Electroplating zinc or cadmium and additive composition therefor
    33.
    发明授权
    Electroplating zinc or cadmium and additive composition therefor 失效
    电镀锌或镉及其添加剂组成

    公开(公告)号:US4062739A

    公开(公告)日:1977-12-13

    申请号:US687455

    申请日:1976-05-18

    IPC分类号: C25D3/24 C25D3/28

    CPC分类号: C25D3/28 C25D3/24

    摘要: Zinc and cadmium are electrodeposited in the presence of the more or less complex mixture present after reacting (a) a compound containing a pyridine nucleus, especially a 3-substituted pyridine and (b) a compound containing an oxirane ring such as an alkylene or arylene oxide, and yield a bright electrodeposit.

    摘要翻译: 在(a)含有吡啶核的化合物,特别是3-取代的吡啶和(b)含有环氧乙烷环的化合物如亚烷基或亚芳基存在下,存在的或多或少的复合混合物存在时,将锌和镉电沉积 氧化,并产生明亮的电沉积。

    Method for electroplating bright zinc
    34.
    发明授权
    Method for electroplating bright zinc 失效
    电镀亮锌的方法

    公开(公告)号:US3974045A

    公开(公告)日:1976-08-10

    申请号:US526950

    申请日:1974-11-25

    IPC分类号: C25D3/22 C25D3/24

    CPC分类号: C25D3/24 C25D3/22 Y10S524/901

    摘要: A brightener additive for zinc electroplating baths, which comprises: a water-soluble polymer prepared by the reaction of an epihalohydrin with a nitrogen heterocyclic compound such as the compounds of imidazole, pyrrole, cyclic amine of the formula: ##EQU1## and piperazine in the presence of a nitrogen compound such as the compounds of aliphatic amines, hexamethylenetetramine and ammonia.

    摘要翻译: 一种用于锌电镀浴的增白剂添加剂,其包括:通过表卤代醇与氮杂环化合物如咪唑,吡咯,下式的化合物(CH2)nNH和哌嗪的化合物反应制备的水溶性聚合物 氮化合物的存在,例如脂族胺,六亚甲基四胺和氨的化合物。

    Process for the production of complex mixtures of N-benzyl-dihydro-nicotinic acid dimers and metal salts thereof and derivatives thereof
    36.
    发明授权
    Process for the production of complex mixtures of N-benzyl-dihydro-nicotinic acid dimers and metal salts thereof and derivatives thereof 失效
    制备N-苄基 - 二氢 - 烟酸二聚体及其金属盐及其衍生物的复合混合物的方法

    公开(公告)号:US3928365A

    公开(公告)日:1975-12-23

    申请号:US38974773

    申请日:1973-08-20

    IPC分类号: C25D3/24 C07D213/55

    CPC分类号: C25D3/24

    摘要: There is disclosed the preparation of novel compositions comprising complex mixtures of salts of di-(1-benzyl-3-carboxyl1,2-dihydropyridyl-2) ethers, the salts of the corresponding sulfides and polysulfides and the position isomers and other products resulting from the reaction between a 1-benzyl-3carboxy-pyridinium halide and an alkali metal, or ammonium, hydroxide, sulfide or polysulfide. These complex mixtures are particularly suitable for use as brightening agents for the alkaline cyanide zinc plating baths employed for the electrodeposition of zinc, as sequestrants and as stabilizers for plastics and rubbers.

    摘要翻译: 公开了包含二(1-苄基-3-羧基-1,2-二氢吡啶基-2)醚的盐的复合混合物,相应硫化物和多硫化物的盐和位置异构体和其它产物的新型组合物的制备 由1-苄基-3-羧基 - 吡啶鎓卤化物与碱金属或铵,氢氧化物,硫化物或多硫化物之间的反应产生。 这些复合混合物特别适合用作用于电沉积锌的碱性氰化物锌电镀浴的增白剂,作为多价螯合剂和用作塑料和橡胶的稳定剂。

    Alkaline zinc electroplating bath
    37.
    发明授权
    Alkaline zinc electroplating bath 失效
    碱性锌电镀浴

    公开(公告)号:US3915815A

    公开(公告)日:1975-10-28

    申请号:US41575773

    申请日:1973-11-14

    申请人: KOCH REINHARD

    发明人: KOCH REINHARD

    IPC分类号: C25D3/24

    CPC分类号: C25D3/24 Y10S524/901

    摘要: The alkaline zinc electroplating bath of the present invention contains as brightening agent the reaction product of A. POLYETHYLENE IMINE OR POLYPROPYLENE IMINE WITH B. AN AROMATIC ALDEHYDE, C. AMMONIA AND/OR ETHYLENEDIAMINE, OR DIETHYLENE TRIAMINE AND D. EPICHLOROHYDRIN. Due to the addition of said reaction product its cyanide content can be considerably reduced without impairing the brightness of the zinc deposit.

    摘要翻译: 本发明的碱性锌电镀浴含有作为增亮剂的A.聚乙烯亚胺或聚丙烯亚胺与B.A芳香醛,C.AMMONIA和/或乙烯二胺,或二乙烯三胺和D.HPICHLOROHYDRIN的反应产物。

    Zinc plating baths
    38.
    发明授权
    Zinc plating baths 失效
    镀锌浴

    公开(公告)号:US3883405A

    公开(公告)日:1975-05-13

    申请号:US27018572

    申请日:1972-07-10

    IPC分类号: C25D3/24 C23B5/10 C23B5/46

    CPC分类号: C25D3/24

    摘要: A brightening composition for the lustrous deposit of zinc from alkaline cyanide solutions contains the condensation products formed by reaction of dialdehydes with polyamine salts. The polyamines of the polyamine salts have at least two terminal amine groups on an aliphatic chain. The salt is formed by neutralizing a water soluble acid with the water soluble polyamine. Reaction of the polyamine salt with the dialdehyde produces the novel condensation products.

    摘要翻译: 用于从碱性氰化物溶液中有光泽地沉积锌的增亮组合物含有通过二醛与多胺盐反应形成的缩合产物。 多胺盐的多胺在脂族链上具有至少两个末端胺基。 盐是通过用水溶性多胺中和水溶性酸形成的。 多胺盐与二醛的反应产生新的缩合产物。

    Cyanide zinc electroplating
    39.
    发明授权
    Cyanide zinc electroplating 失效
    氰化锌电镀

    公开(公告)号:US3769183A

    公开(公告)日:1973-10-30

    申请号:US3769183D

    申请日:1971-06-18

    申请人: DU PONT

    发明人: ADELMAN R

    IPC分类号: C25D3/24 C23B5/10

    CPC分类号: C25D3/24

    摘要: Aqueous alkaline cyanide zinc electroplating baths and processes are provided in which polyvinyl alcohol or a vinyl alcohol copolymer degraded with periodic acid or an alkali metal periodate is used as a brightener, particularly to give improved plating characteristics at low applied currents. Enhanced zinc plates are obtained when the degraded polyvinyl alcohol is used with other brightening additives, particularly a pyridinium compound having at least one polar substituent.

    摘要翻译: 提供了一种碱性氰化锌锌电镀浴和其中使用用高碘酸或碱金属高碘酸盐降解的聚乙烯醇或乙烯醇共聚物作为增白剂的方法,特别是在低施加电流下提供改善的电镀特性。 当降解的聚乙烯醇与其它增亮剂,特别是具有至少一个极性取代基的吡啶鎓化合物一起使用时,可获得增强的锌板。