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    Processes for Producing Levosandal and Levosandol
    42.
    发明申请
    Processes for Producing Levosandal and Levosandol 审中-公开
    产生左旋糖和左旋糖酐的方法

    公开(公告)号：US20100312018A1

    公开(公告)日：2010-12-09

    申请号：US12753279

    申请日：2010-04-02

    申请人： Avelino Corma Canos ,  Sara Iborra Chornet ,  Alexandra Velty

    发明人： Avelino Corma Canos ,  Sara Iborra Chornet ,  Alexandra Velty

    IPC分类号： C07C45/74 ,  C07C29/159

    CPC分类号： C07C29/14 ,  C07C45/74 ,  C07C2601/10 ,  C07C33/12 ,  C07C47/225

    摘要： The present invention relates to processes for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal and 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol using heterogeneous bifunctional catalysts with a good yield. There is provided a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal by the cross-aldol condensation between campholenic aldehyde and butanal using bifunctional heterogeneous catalysts in the presence of controlled amounts of an aliphatic alcohol; and a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol useful as perfume, starting from 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal through a MPV reduction using an acid-base bifunctional heterogeneous catalyst. Both process can be coupled in a cascade process which involves the cross-aldol condensation between campholenic aldehyde and butanal followed by the Meerwein-Ponndorf-Verley (MPV) reduction in the presence of a secondary alcohol using the same heterogeneous bifunctional catalyst for obtaining (2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol).

    摘要翻译： 本发明涉及2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛和2-乙基-4-（2,2,3-三甲基 -3-环戊烯-1-基）-2-丁烯-1-醇，使用异构双官能催化剂，产率很高。 提供了一种通过使用双功能非均相催化剂在camp醛和丁醛之间的交换醛醇缩合产生2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛的方法 存在受控量的脂族醇; 和用作香料的2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇的制备方法，由2-乙基-4-（2 ，2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛，通过使用酸碱双功能多相催化剂的MPV还原。 这两种方法可以在级联方法中偶合，其涉及在醛醇和丁醛之间的交叉醛醇缩合，随后在仲醇存在下使用相同的异构双功能催化剂还原Meerwein-Ponndorf-Verley（MPV）以获得（2 - 乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇）。

    METHOD AND CATALYSTS FOR THE EPOXIDATION OF OLEFINIC COMPOUNDS IN THE PRESENCE OF OXYGEN
    43.
    发明申请
    METHOD AND CATALYSTS FOR THE EPOXIDATION OF OLEFINIC COMPOUNDS IN THE PRESENCE OF OXYGEN 审中-公开
    氧气存在下氧化烯烃的方法和催化剂

    公开(公告)号：US20090234145A1

    公开(公告)日：2009-09-17

    申请号：US11911836

    申请日：2006-04-06

    申请人： Avelino Corma Canos ,  Marcelo Eduardo Domine

    发明人： Avelino Corma Canos ,  Marcelo Eduardo Domine

    IPC分类号： C07D301/04

    CPC分类号： B01J29/0325 ,  B01J21/063 ,  B01J23/66 ,  B01J29/89 ,  B01J31/0274 ,  B01J35/006 ,  B01J2229/18 ,  B01J2229/32 ,  C07D301/10 ,  C07D303/04

    摘要： The invention relates to a method for the epoxidation of an olefinic compound, which is characterised in that it comprises an oxidation reaction of at least one olefinic compound containing one or more double bonds C═C with oxygen in the presence of one or more reaction initiating agents, at least one catalyst containing at least one metal that is selected from a noble metal, a transition metal and mixtures of same, and at least one hydrocarbon that is selected from one or more branched alkanes, one or more alkyl cyclic or cyclic hydrocarbons, one or more alkyl aromatic or aromatic compounds and mixtures of same.

    摘要翻译： 本发明涉及一种烯烃化合物的环氧化方法，其特征在于它包含在一种或多种反应引发剂存在下至少一种含有一个或多个双键CC与氧的烯属化合物的氧化反应， 至少一种含有至少一种选自贵金属，过渡金属及其混合物的金属的催化剂和至少一种选自一种或多种支链烷烃，一种或多种烷基环状或环状烃的烃，一种 或更多烷基芳族或芳族化合物及其混合物。

    Microporous crystalline zeolite material, zeolite ITQ-28, production method thereof and use of same
    47.
    发明申请
    Microporous crystalline zeolite material, zeolite ITQ-28, production method thereof and use of same 失效
    微孔结晶沸石材料，沸石ITQ-28，其制备方法及用途

    公开(公告)号：US20060286029A1

    公开(公告)日：2006-12-21

    申请号：US11392473

    申请日：2006-03-29

    申请人： Avelino Corma Canos ,  Maria Sabater Picot ,  Susana Valencia Valencia

    发明人： Avelino Corma Canos ,  Maria Sabater Picot ,  Susana Valencia Valencia

    IPC分类号： C01B39/48

    CPC分类号： C01B37/005 ,  B01J29/035 ,  B01J29/70 ,  B01J29/87 ,  B01J29/89 ,  C01B37/02 ,  C01B39/065 ,  C01B39/48

    摘要： The invention relates to a microporous crystalline zeolite material, zeolite ITQ-28, the production method thereof and the use of same. More specifically, the invention relates to a microporous crystalline zeolite material, ITQ-28, which, in the calcined state and in the absence of defects in the crystalline lattice thereof, manifested by the presence of silanols, is characterised by having empirical formula x (M1/nXO2): y YO2: SiO2, wherein: M is selected from H+, at least one inorganic cation with charge +n, preferably alkalines or alkaline earths, and a mixture of both; X is at least one chemical element in oxidation state +3, preferably Al, Ga, B, Fe, Cr or mixtures thereof; Y is at least a chemical element in oxidation state +4, which is different from Si, preferably Ge, Ti, Sn, V or mixtures of same; x has a value of between 0 and 0.2 inclusive; and y has a value of between 0 and 0.1 inclusive. The invention is further characterised in that the material as it is synthesised has an x-ray diffraction pattern with at least values of angle 2θ (degrees) and the relative intensities given in table 1. The invention also relates to the method of preparing said material and to the use thereof in the conversion of organic compounds.

    摘要翻译： 本发明涉及微孔结晶沸石材料，沸石ITQ-28，其制备方法及其用途。 更具体地说，本发明涉及一种微孔结晶沸石材料ITQ-28，其在煅烧状态中并且在其不存在其晶格缺陷的情况下，通过硅烷醇的存在而表现出来，其特征在于具有经验式x（ M 1 / n 2 XO 2）：y Y 2 O 2 SiO 2其中：M选自H 至少一种带电荷的无机阳离子，优选碱金属或碱土金属，以及二者的混合物; X是氧化态+3，优选Al，Ga，B，Fe，Cr或其混合物中的至少一种化学元素; Y至少是氧化态+4的化学元素，其不同于Si，优选Ge，Ti，Sn，V或其混合物; x的值在0和0.2之间; y的值在0和0.1之间。 本发明的特征还在于其合成的材料具有x射线衍射图，其至少具有角度2θ（度）和表1中给出的相对强度。本发明还涉及制备所述材料的方法 以及其在有机化合物的转化中的用途。

    Process and catalysts for deep desulphurization of fuels
    48.
    发明申请
    Process and catalysts for deep desulphurization of fuels 审中-公开
    燃料深度脱硫的工艺和催化剂

    公开(公告)号：US20060154814A1

    公开(公告)日：2006-07-13

    申请号：US10528813

    申请日：2003-09-26

    申请人： Laura Zanibelli ,  Giuseppe Bellussi ,  Avelino Corma Canos ,  Marcelo Domine ,  Maria Gagliardi

    发明人： Laura Zanibelli ,  Giuseppe Bellussi ,  Avelino Corma Canos ,  Marcelo Domine ,  Maria Gagliardi

    IPC分类号： B01J21/08 ,  B01J21/12 ,  B01J21/14

    CPC分类号： B01J21/063 ,  B01J21/06 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  C10G27/12 ,  C10G67/12

    摘要： The present invention concerns a process for oxidative desulphurization of hydrotreated hydrocarbon mixtures which boil within the range of 180° to 360° C., containing less than 350 ppm of sulphur as thiophenic compounds, said process comprising the steps of a) putting these mixtures in contact, in the presence of an organic peroxide, with a catalytic composition comprising a completely amorphous micro and/or mesoporous mixed oxide containing an oxide matrix selected from silica, alumina, ceria, magnesia and mixtures of thereof, wherein one or more oxidative metal oxides selected from transition metal oxides and group IVA metal oxides are uniformly dispersed, and b) separating the obtained corresponding sulphur oxygenated products from the hydrocarbon mixture.

    摘要翻译： 本发明涉及一种加氢处理的烃混合物的氧化脱硫方法，其在180℃至360℃的范围内沸腾，含有少于350ppm的硫作为噻吩化合物，所述方法包括以下步骤：a）将这些混合物置于 在有机过氧化物的存在下与包含含有选自二氧化硅，氧化铝，二氧化铈，氧化镁及其混合物的氧化物基质的完全无定形微孔和/或介孔混合氧化物的催化组合物接触，其中一种或多种氧化性金属氧化物 选自过渡金属氧化物和IVA族金属氧化物均匀分散，b）从烃混合物中分离得到的相应硫氧化产物。

    Structure material of the zeolite type with ultralarge pores and a lattice comprised of silicone and titanium oxides: its synthesis and utilization for the selective oxidation of organic products
    50.
    发明授权
    Structure material of the zeolite type with ultralarge pores and a lattice comprised of silicone and titanium oxides: its synthesis and utilization for the selective oxidation of organic products 失效
    具有超细孔的沸石型结构材料和由硅氧烷和氧化钛组成的晶格：其合成和利用有机产物的选择性氧化

    公开(公告)号：US5783167A

    公开(公告)日：1998-07-21

    申请号：US413867

    申请日：1995-02-15

    申请人： Avelino Corma Canos ,  Teresa Navarro Villalba ,  Joaquin Perez Pariente

    发明人： Avelino Corma Canos ,  Teresa Navarro Villalba ,  Joaquin Perez Pariente

    IPC分类号： B01J29/89 ,  C01B39/00 ,  C07D301/12 ,  C01B33/20 ,  B01J29/04

    CPC分类号： C01B39/00 ,  B01J29/89 ,  C07D301/12

    摘要： The invention relates to a material comprised of silicotitanates having a crystalline structure similar to MCM-41 zeolites, said material being characterized in that it contains in its lattice atoms of titanium and channels in its porous structure whose average sizes exceed 10 .ANG., making possible its utilization in catalytic reactions wherein are involved large organic molecules, such as the oxidation of olefins to epoxides and glycols, alcohols to cetones, thio-ethers to sulfoxides and sulfones, and phenol to catechol and hydroquinone, and if Al is introduced into the structure it is then possible to prepare bifunctional catalysts "oxidant-acid/base." In order to obtain such product, and aqueous solution is used which contains the ion NR.sub.1 N.sub.2 N.sub.3 N.sub.4.sup.+ as well as another aqueous solution which contains tetramethyl ammonium hydroxide and a silica source (e.g. aerosil.RTM.. After homogenization, more silica is added, as is the Ti source �e.g. Ti(C.sub.2 OH.sub.5).sub.4 !. The resultant gel is heated in an autoclave at a temperature between 80.degree. and 200.degree. C. It is used for catalytic oxidation.

    摘要翻译： 本发明涉及由具有类似于MCM-41沸石的结晶结构的硅钛酸盐组成的材料，所述材料的特征在于其平均尺寸超过10 ANGSTROM的钛及其多孔结构中的通道的晶格原子含有其多孔结构，使其成为可能 在催化反应中的应用，其中涉及大的有机分子，例如将烯烃氧化成环氧化物和二醇，醇类，酮类，硫代醚类，亚砜类和砜类，以及苯酚类，以及邻苯二酚和对苯二酚。 然后可以制备双功能催化剂“氧化剂 - 酸/碱”。 为了获得这样的产物，使用含有离子NR1N2N3N4 +的水溶液以及含有四甲基氢氧化铵和二氧化硅源（例如aerosil TM）的另一种水溶液，均化后加入更多的二氧化硅，Ti源 [例如Ti（C 2 O 5）4]。所得凝胶在高压釜中在80〜200℃的温度下加热。用于催化氧化。