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公开(公告)号：US6107524A
公开(公告)日：2000-08-22
申请号：US101692
申请日：1998-07-15
IPC分类号： B01J31/22 , B01J31/16 , B01J31/18 , B01J31/40 , C07B61/00 , C07C27/22 , C07C29/16 , C07C31/125 , C07C45/50 , C07C45/80 , C07C47/02
CPC分类号： C07C45/80 , B01J31/1815 , B01J31/4046 , C07C29/16 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/1658 , Y02P20/584
摘要： A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of from 50 to 1000 bar and at a temperature of from 50.degree. to 180.degree. C. using a rhodium catalyst that is dissolved in a homogeneous reaction medium and by extraction of the rhodium catalyst, in whicha) the hydroformylation is carried out in the presence of a rhodium complex, which exhibits, as ligand, a polydentate, organic nitrogen compound that is free from phosphorus and capable of forming complexes with Group VIII metals, which additionally contains at least one tertiary nitrogen radical that is capable of being protonized by a weak acid,b) the effluent of the hydroformylation stage is subjected to extraction with an aqueous solution of a distillable acid optionally following separation or partial separation of aldehydes and alcohols,(c) the aqueous acid extract is subjected to thermal treatment in the presence of an organic solvent or solvent mixture, which is inert under the hydroformylation conditions, with distillation of the aqueous acid, by means of which treatment the complex is deprotonized and transferred to the organic phase, and(d) the organic phase containing the catalyst complex is recycled to the hydroformylation stage.
摘要翻译： PCT No.PCT / EP97 / 00372 Sec。 371日期：1998年7月15日 102（e）1998年7月15日PCT PCT 1997年1月28日PCT公布。 公开号WO97 / 28113 日期：1997年8月7日一种通过加氢甲酰化含有多于3个碳原子的烯烃制备醛或醛和醇的方法，该方法包括加氢甲酰化阶段，其中烯烃在50至1000巴的压力和温度下加氢甲酰化 使用溶解在均匀的反应介质中并通过萃取铑催化剂的铑催化剂，其中a）在铑配合物的存在下进行加氢甲酰化，其表现出作为 配体，多齿，有机氮化合物，其不含磷并能够与VIII族金属形成络合物，其另外含有至少一个能够被弱酸质子化的叔氮基团，b）加氢甲酰化的流出物 任选在醛和醇的分离或部分分离后，用可蒸馏的酸的水溶液萃取阶段，（c ）酸性水提取物在有机溶剂或溶剂混合物存在下进行热处理，所述有机溶剂或溶剂混合物在加氢甲酰化条件下是惰性的，同时蒸馏酸水溶液，通过该处理将络合物去质子化并转移到有机溶剂 相，和（d）含有催化剂络合物的有机相再循环到加氢甲酰化阶段。
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公开(公告)号：US5689010A
公开(公告)日：1997-11-18
申请号：US638592
申请日：1996-04-29
IPC分类号： B01J31/22 , C07B61/00 , C07C45/50 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/02 , C07C47/21 , C07C45/49
摘要： Aldehydes with a higher number of carbon atoms and high selection are prepared by reacting olefins, in particular from petrochemical refinery products, by a hydroformylation with aldol condensation using a mixed catalyst of rhodium-carbonyl-phosphines and Mannich catalyst.
摘要翻译： 通过使用铑 - 羰基膦和Mannich催化剂的混合催化剂通过使醛醇缩合的加氢甲酰化反应，使烯烃，特别是石油化学品炼油产物反应，制备具有较高碳原子数和高选择性的醛。
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43.发明授权Process for preparing di-, tri- and polyamines by homogeneously catalyzed alcohol amination 有权通过均匀催化的醇胺化制备二 - ，三 - 和多胺的方法公开(公告)号：US08912361B2
公开(公告)日：2014-12-16
申请号：US13415466
申请日：2012-03-08
申请人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
发明人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
IPC分类号： C07C213/02 , C07C209/16 , C07D307/52 , C07D207/20 , C07D295/027 , C07D205/04 , C07D211/06 , C07D207/02 , C07D223/04
CPC分类号： C07C213/02 , C07C209/16 , C07C2601/14 , C07D205/04 , C07D207/02 , C07D207/20 , C07D211/06 , C07D223/04 , C07D295/027 , C07D307/52 , C07C217/08 , C07C215/08 , C07C211/09 , C07C211/10 , C07C211/18 , C07C215/20 , C07C211/12
摘要： Process for preparing primary amines which have at least one functional group of the formula (—CH2—NH2) and at least one further primary amino group by alcohol amination of starting materials having at least one functional group of the formula (—CH2—OH) and at least one further functional group (—X), where (—X) is selected from among hydroxyl groups and primary amino groups, by means of ammonia with elimination of water, wherein the reaction is carried out homogeneously catalyzed in the presence of at least one complex catalyst comprising at least one element selected from groups 8, 9 and 10 of the Periodic Table and also at least one donor ligand.
摘要翻译： 具有至少一个式（-CH 2 -NH 2）官能团和至少一个另外的伯氨基的伯胺的方法，其通过具有至少一个式（-CH 2 -OH）官能团的原料醇醇胺化， 和至少一个另外的官能团（-X），其中（-X）选自羟基和伯氨基，通过氨除去水，其中反应在存在下进行均匀催化 至少一种复合催化剂，其包含至少一种选自元素周期表第8,9和10族的元素，以及至少一种供体配体。
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公开(公告)号：US08697834B2
公开(公告)日：2014-04-15
申请号：US13116649
申请日：2011-05-26
申请人： Thomas Schaub , Boris Buschhaus , Johann-Peter Melder , Rocco Paciello , Stephan Hüffer , Helmut Witteler
发明人： Thomas Schaub , Boris Buschhaus , Johann-Peter Melder , Rocco Paciello , Stephan Hüffer , Helmut Witteler
CPC分类号： C07C209/16 , C07C213/02 , C08G73/0213 , C07C211/14 , C07C215/14
摘要： The invention relates to a process for the preparation of polyalkylenepolyamines by catalyzed alcohol amination, in which(i) aliphatic aminoalcohols are reacted with one another or(ii) aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a catalyst.
摘要翻译： 本发明涉及通过催化醇胺化制备聚亚烷基多胺的方法，其中（i）脂肪族氨基醇彼此反应，或（ii）脂族二胺或多胺与脂族二元醇或多元醇反应，在 存在催化剂。
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45.发明授权公开(公告)号：US08637709B2
公开(公告)日：2014-01-28
申请号：US13415174
申请日：2012-03-08
申请人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
发明人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
IPC分类号： C07C209/16 , C07C209/18
CPC分类号： C07C213/02 , C07C215/08 , C07C217/08
摘要： Preparing a primary amine by alcohol amination of alcohol with ammonia and elimination of water includes reacting, in a homogeneously catalyzed reaction, a mixture of alcohol, ammonia, nonpolar solvent, and catalyst, in a liquid phase, to obtain a product mixture. The process then includes phase separating the product mixture into a polar product phase and a nonpolar product phase, and separating off the nonpolar product phase. At least some of the nonpolar phase returns to the homogenously catalyzed reaction. The process further includes separating off amination product from the polar product phase. At least some of the catalyst is in the nonpolar phase, and the catalyst accumulates in the nonpolar phase.
摘要翻译： 通过醇与醇的氨基化反应制备伯胺并除去水包括在均相催化的反应中，将醇，氨，非极性溶剂和催化剂的混合物在液相中反应，得到产物混合物。 然后，该方法包括将产物混合物相分离成极性产物相和非极性产物相，并将非极性产物相分离。 至少一些非极性相返回均匀催化反应。 该方法还包括从极性产物相分离胺化产物。 至少一些催化剂处于非极性相，并且催化剂积聚在非极性相中。
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46.发明申请PROCESS FOR PREPARING FORMIC ACID BY REACTING CARBON DIOXIDE WITH HYDROGEN 审中-公开通过用氢气反应二氧化碳制备形式酸的方法公开(公告)号：US20120157711A1
公开(公告)日：2012-06-21
申请号：US13330974
申请日：2011-12-20
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Petra Deckert , Peter Bassler
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Petra Deckert , Peter Bassler
IPC分类号： C07C53/02
摘要： The present invention relates to a process for preparing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where a tertiary amine having a boiling point which is at least 5° C. higher than that of formic acid is used and a reaction mixture comprising the polar solvent, the formic acid/amine adducts, the tertiary amine and the catalyst is formed in the reaction in the hydrogenation reactor (I) and is discharged from the reactor as output (3).
摘要翻译： 本发明涉及一种通过使二氧化碳（1）与氢（2）在氢化反应器（I）中在含有周期表第8,9或10族元素的催化剂存在下反应来制备甲酸的方法 ，每分子含有至少12个碳原子的叔胺和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中第三 使用沸点比甲酸高至少5℃的胺，并且在反应中形成包含极性溶剂，甲酸/胺加合物，叔胺和催化剂的反应混合物 氢化反应器（I），并作为输出（3）从反应器排出。
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公开(公告)号：US20120071690A1
公开(公告)日：2012-03-22
申请号：US13234549
申请日：2011-09-16
IPC分类号： C07C231/10
CPC分类号： C07C231/02 , C07C233/03
摘要： A process is proposed for production of formamides by reaction of carbon dioxide with hydrogen in a hydrogenation reactor I in the presence of a catalyst comprising an element from group 8, 9 or 10 of the periodic table, a tertiary amine comprising at least 6 carbon atoms per molecule, and also a polar solvent, to form formic acid-amine adducts as intermediates, which are subsequently reacted with ammonia or amines in a reactor to obtain a two-phase liquid reaction effluent from which the liquid phase enriched with the formamides is distillatively separated to recover the formamide.
摘要翻译： 提出了在含有元素周期表第8,9或10族的元素的催化剂存在下，在氢化反应器I中使二氧化碳与氢气反应制备甲酰胺的方法，包含至少6个碳原子的叔胺 每分子以及极性溶剂，以形成作为中间体的甲酸 - 胺加合物，随后在反应器中与氨或胺反应以获得两相液体反应流出物，富含甲酰胺的液相从中蒸馏出 分离以回收甲酰胺。
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48.发明申请PROCESS FOR PREPARING FORMIC ACID BY REACTION OF CARBON DIOXIDE WITH HYDROGEN 有权通过用氢气反应二氧化碳制备形式酸的方法公开(公告)号：US20110319658A1
公开(公告)日：2011-12-29
申请号：US13172123
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/15
CPC分类号： C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols and also water, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, with work-up of the output (3) from the hydrogenation reactor (I) in a plurality of process steps, where a tertiary amine-comprising stream (13) from the work-up is used as selective solvent for the catalyst, is proposed.
摘要翻译： 在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法， 每分子含有至少12个碳原子，以及包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇和极性溶剂的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，具有后处理 提出了在多个工艺步骤中，来自加氢反应器（I）的输出物（3）的来自后处理的含叔胺的物流（13）用作催化剂的选择性溶剂。
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公开(公告)号：US20110045560A1
公开(公告)日：2011-02-24
申请号：US12906654
申请日：2010-10-18
IPC分类号： C12P7/04
CPC分类号： C12P7/04 , C07B2200/07 , C07C29/14 , C07C29/141 , C07C29/172 , C12C11/02 , C07C33/025 , C07C31/125
摘要： A process for preparing optically active 2-methylalkan-1-ol of the general formula (III) comprising the following steps: carbonyl-selective reduction of 2-methylalk-2-en-1-al of the general formula (I) to 2-methylalk-2-en-1-ol of the general formula (II), (ii) enantioselective hydrogenation of 2-methylalk-2-en-1-ol to the general formula (iii), (iii) increasing the optical yield of the optically active 2-methylalkan-1-ol (III) obtained in step (ii) by a lipase-catalyzed acylation reaction, where the radical R means C1-C10-alkyl.
摘要翻译： 一种制备通式（III）的光学活性2-甲基链烷-1-醇的方法，包括以下步骤：将通式（I）的2-甲基烯-2-烯-1-醇羰基选择性还原为2 （II）的2-甲基-2-烯-1-醇，（ii）2-甲基烯-2-烯-1-醇与通式（iii）的对映选择性氢化，（iii）提高光学收率 的通过脂肪酶催化酰化反应在步骤（ii）中获得的光学活性2-甲基烷-1-醇（III），其中基团R表示C 1 -C 10 - 烷基。
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公开(公告)号：US20100152494A1
公开(公告)日：2010-06-17
申请号：US12597025
申请日：2008-04-17
CPC分类号： C07C29/172 , C07B53/00 , C07B2200/07 , C07C29/56 , C07C45/62 , C07C2601/14 , C07C35/12 , C07C35/17 , C07C47/21
摘要： The present invention relates to a process for preparing optically active carbonyl compounds by asymmetrically hydrogenating α,β-unsaturated carbonyl compounds in the presence of optically active transition metal catalysts which are soluble in the reaction mixture and have at least one carbon monoxide ligand, the optically active catalyst which has at least one carbon monoxide ligand and is to be used in each case being prepared by pretreating a catalyst precursor with a gas mixture comprising carbon monoxide and hydrogen and the asymmetric hydrogenation being performed in the presence of carbon monoxide supplied additionally to the reaction mixture.
摘要翻译： 本发明涉及一种通过在光学活性的过渡金属催化剂的存在下不对称氢化α，β-不饱和羰基化合物来制备光学活性的羰基化合物的方法，其可溶于反应混合物并具有至少一种一氧化碳配体， 具有至少一种一氧化碳配体并且在每种情况下使用的光学活性催化剂通过用包含一氧化碳和氢气的气体混合物预处理催化剂前体而制备，并且在另外提供的一氧化碳的存在下进行不对称氢化 反应混合物。
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