公开(公告)号：US08581094B2

公开(公告)日：2013-11-12

申请号：US11857208

申请日：2007-09-18

申请人： Rajen M. Patel ,  Shaofu Wu ,  Mark T. Bernius ,  Mohamed Esseghir ,  Robert L. McGee ,  Michael H. Mazor ,  John Naumovitz

发明人： Rajen M. Patel ,  Shaofu Wu ,  Mark T. Bernius ,  Mohamed Esseghir ,  Robert L. McGee ,  Michael H. Mazor ,  John Naumovitz

IPC分类号： H02N6/00 ,  H01L31/042 ,  H01L31/00

CPC分类号： H01L31/0481 ,  B32B17/10018 ,  B32B17/10678 ,  B32B2457/12 ,  C08L51/06 ,  H01L31/18 ,  Y02E10/50 ,  C08L2666/02 ,  C08L2666/04

摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer with at least one of (a) a density of less than about 0.90 g/cc, (b) a 2% secant modulus of less than about 150 megaPascal (mPa) as measured by ASTM D-882-02), (c) a melt point of less than about 95 C, (d) an α-olefin content of at least about 15 and less than about 50 wt % based on the weight of the polymer, (e) a Tg of less than about −35 C, and (f) a SCBDI of at least about 50, (2) optionally, free radical initiator, e.g., a peroxide or azo compound, or a photoinitiator, e.g., benzophenone, and (3) optionally, a co-agent. Typically, the polyolefin copolymer is an ethylene/α-olefin copolymer. Optionally, the polymeric material can further comprise a vinyl silane and/or a scorch inhibitor, and the copolymer can remain uncrosslinked or be crosslinked.

摘要翻译： 一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料，所述聚合材料包含（1）聚烯烃共聚物， （a）小于约0.90g / cc的密度，（b）通过ASTM D-882-02测量的小于约150兆帕（mPa）的2％割线模量中的至少一个），（c） 熔点低于约95℃，（d）基于聚合物重量，至少约15-小于约50重量％的α-烯烃含量，（e）小于约-35℃的Tg， 和（f）至少约50的SCBDI，（2）任选的自由基引发剂，例如过氧化物或偶氮化合物，或光引发剂，例如二苯甲酮，和（3）任选的助剂。 通常，聚烯烃共聚物是乙烯/α-烯烃共聚物。 任选地，聚合物材料还可以包含乙烯基硅烷和/或焦烧抑制剂，并且共聚物可保持未交联或交联。

公开(公告)号：US20130269776A1

公开(公告)日：2013-10-17

申请号：US13994315

申请日：2011-11-08

申请人： Shaofu Wu ,  Lih-Long Chu ,  John D. Weaver ,  John A. Naumovitz ,  Richard C. Abel

发明人： Shaofu Wu ,  Lih-Long Chu ,  John D. Weaver ,  John A. Naumovitz ,  Richard C. Abel

IPC分类号： H01L31/048 ,  H01L31/18

CPC分类号： H01L31/1876 ,  B32B17/10018 ,  B32B2323/04 ,  B32B2457/12 ,  C08F255/02 ,  C08J5/18 ,  C08J2351/06 ,  H01L31/0481 ,  Y02E10/50 ,  C08F230/08

摘要： Disclosure are films based on alkoxysilane-containing polyolefin resins with reduced melt strength, photovoltaic cell laminate structures and methods for their preparation. In the disclosed alkoxysilane-containing polyolefin resin films according to the invention, reduced melt strength is provided by, among other things, using optimized silane:initiator ratios and is shown to reduce detrimental film shrinkage and provide improved photovoltaic laminate structures.

摘要翻译： 披露是基于具有降低的熔体强度的含烷氧基硅烷的聚烯烃树脂的膜，光伏电池层压结构及其制备方法。 在所公开的本发明的含烷氧基硅烷的聚烯烃树脂膜中，除了别的以外，使用优化的硅烷：引发剂比率提供降低的熔体强度，并且显示出减少有害的膜收缩并提供改进的光伏层压结构。

公开(公告)号：US20130206224A1

公开(公告)日：2013-08-15

申请号：US13701060

申请日：2011-06-06

申请人： John A. Naumovitz ,  Rajen M. Patel ,  Shaofu Wu ,  Debra H. Niemann

发明人： John A. Naumovitz ,  Rajen M. Patel ,  Shaofu Wu ,  Debra H. Niemann

IPC分类号： H05K1/03 ,  H01L31/048

CPC分类号： H05K1/0353 ,  B32B17/10018 ,  B32B17/1055 ,  B32B17/10697 ,  C08F210/16 ,  C08L23/08 ,  H01L31/0481 ,  Y02E10/50 ,  C08L2666/24 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/26

摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm3; total unsaturation of not more than 125 per 100,000 carbons; and; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/Mn), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145° C.) and 1H-NMR (125° C.), (2) a graft polymer to enhance the adhesion, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.

摘要翻译： 一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）乙烯互聚物，其包含 总聚合物密度不大于0.905g / cm3; 总不饱和度不超过125 / 100,000个碳; 和; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 和总数（1000 / Mn）的乙烯基/ 1000个碳的总数，其中通过凝胶渗透色谱（145℃）和1 H-NMR（125°）测量乙烯基-3含量和乙烯基测量值 （3）任选的自由基引发剂或光引发剂，其量为至少约0.05重量％，基于共聚物的重量，和（3）任选地， 基于共聚物的重量，至少约0.05重量％的量的助剂。

公开(公告)号：US20130167926A1

公开(公告)日：2013-07-04

申请号：US13821272

申请日：2011-09-02

申请人： Debra H. Niemann ,  John A. Naumovitz ,  Rajen M. Patel ,  Shaofu Wu

发明人： Debra H. Niemann ,  John A. Naumovitz ,  Rajen M. Patel ,  Shaofu Wu

IPC分类号： H01L31/048

CPC分类号： H01L31/0481 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/1055 ,  B32B2457/12 ,  Y02E10/50

摘要： An electronic device module such as a solar cell is described. The electronic device module is made using a polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising a tapered block copolymer comprising an A block, and a B block.

摘要翻译： 描述了诸如太阳能电池的电子设备模块。 电子器件模块使用与电子器件的至少一个表面紧密接触的聚合物材料制成，聚合物材料包含包含A嵌段和B嵌段的渐缩嵌段共聚物。

公开(公告)号：US20110290317A1

公开(公告)日：2011-12-01

申请号：US13116520

申请日：2011-05-26

申请人： John Naumovitz ,  Rajen M. Patel ,  Shaofu Wu ,  Debra H. Niemann

发明人： John Naumovitz ,  Rajen M. Patel ,  Shaofu Wu ,  Debra H. Niemann

IPC分类号： H01L31/0216

CPC分类号： C08L23/08 ,  B32B17/10018 ,  B32B17/1055 ,  C08L2205/02 ,  H01L31/0481 ,  Y02E10/50 ,  C08L2666/06

摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene-based polymer composition characterized by a Comonomer Distribution Constant greater than about 45, more preferably greater than 50, most preferably greater than 95, and as high as 400, preferably as high as 200, wherein the composition has less than 120 total unsaturation unit/1,000,000C, preferably the ethylene-based polymer compositions comprise up to about 3 long chain branches/1000 carbons, more preferably from about 0.01 to about 3 long chain branches/1000 carbons; the ethylene-based polymer composition can have a ZSVR of at least 2; the ethylene-based polymer compositions can be further characterized by comprising less than 20 vinylidene unsaturation unit/1,000,000C; the ethylene-based polymer compositions can have a bimodal molecular weight distribution (MWD) or a multi-modal MWD; the ethylene-based polymer compositions can have a comonomer distribution profile comprising a mono or bimodal distribution from 35° C. to 120° C., excluding purge; the ethylene-based polymer compositions can comprise a single DSC melting peak; the ethylene-based polymer compositions can comprise a weight average molecular weight (Mw) from about 17,000 to about 220,000, (2) optionally, a vinyl silane, (3) optionally, a free radical initiator, e.g., a peroxide or azo compound, or a photoinitiator, e.g., benzophenone, and (4) optionally, a co-agent.

摘要翻译： 一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料，所述聚合物材料包括（1）基于乙烯的 聚合物组合物的特征在于共聚单体分布常数大于约45，更优选大于50，最优选大于95，高达400，优选高达200，其中组合物具有小于120总不饱和单元/ 1,000,000C 优选地，基于乙烯的聚合物组合物包含最多约3个长链分支/ 1000个碳，更优选约0.01至约3个长支链/ 1000个碳; 基于乙烯的聚合物组合物可以具有至少2的ZSVR; 基于乙烯的聚合物组合物可以进一步表征为包含少于20个亚乙烯基不饱和单元/ 1,000,000C; 乙烯基聚合物组合物可以具有双峰分子量分布（MWD）或多模态MWD; 乙烯基聚合物组合物可以具有包含35℃至120℃的单峰或双峰分布的共聚单体分布分布，不包括吹扫; 基于乙烯的聚合物组合物可以包含单个DSC熔融峰; 基于乙烯的聚合物组合物可包含约17,000至约220,000的重均分子量（Mw），（2）任选的乙烯基硅烷，（3）任选的自由基引发剂，例如过氧化物或偶氮化合物， 或光引发剂，例如二苯甲酮，和（4）任选的助剂。

公开(公告)号：US20110146792A1

公开(公告)日：2011-06-23

申请号：US12963172

申请日：2010-12-08

申请人： Shaofu Wu ,  Peter S. Martin ,  Xuming Chen ,  Michelle L. Boven ,  Weijun Zhou ,  Valentina A. Kuznetsova

发明人： Shaofu Wu ,  Peter S. Martin ,  Xuming Chen ,  Michelle L. Boven ,  Weijun Zhou ,  Valentina A. Kuznetsova

IPC分类号： H01L31/0203 ,  B32B17/06 ,  B32B27/28 ,  B32B7/02 ,  B05D7/24

CPC分类号： B32B27/32 ,  B32B17/064 ,  B32B2457/12 ,  Y10T428/24967 ,  Y10T428/26 ,  Y10T428/266 ,  Y10T428/31507 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31573 ,  Y10T428/31598 ,  Y10T428/31645

摘要： The present invention generally relates to composite laminates and uses thereof in articles in need of protection from mechanical damage and water or oxygen based degradation.

摘要翻译： 本发明一般涉及复合层合物及其在需要防止机械损伤和水或氧气降解的制品中的用途。

公开(公告)号：US07439276B2

公开(公告)日：2008-10-21

申请号：US10566612

申请日：2004-08-25

申请人： Gary M. Strandburg ,  Mark W. VanSumeren ,  Shaofu Wu ,  Luther E. Stockton ,  David R. Speth ,  Brad M. Moncla ,  Matthew J. Kalinowski

发明人： Gary M. Strandburg ,  Mark W. VanSumeren ,  Shaofu Wu ,  Luther E. Stockton ,  David R. Speth ,  Brad M. Moncla ,  Matthew J. Kalinowski

IPC分类号： C08L47/00

CPC分类号： C08J9/30 ,  A61L15/425 ,  C08J2205/05 ,  C08J2207/12 ,  C08J2300/14 ,  C08J2323/02 ,  C08J2323/16

摘要： Aqueous-based, dispersed olefin polymers, froths, durable, open-cell foam compositions, structures and articles derived from same; methods for preparation of such froths and foams; and use of the dry durable foams in various applications are disclosed. Further described is use of the foams and structures and articles made of same in absorption, filtration, insulation, cushioning and backing applications, and in particular for odor removal, hygiene and medical applications due to, among other properties, good absorption capabilities, softness and/or flexibility of the foams and their recyclable nature.

摘要翻译： 基于水的，分散的烯烃聚合物，泡沫，耐用的开孔泡沫组合物，由其衍生的结构和制品; 制备这种泡沫和泡沫的方法; 并且公开了在各种应用中使用干燥耐久泡沫。 进一步描述的是在吸收，过滤，绝缘，缓冲和背衬应用中使用由它们制成的泡沫和结构物以及特别是除臭，卫生和医疗应用的泡沫和结构物以及由此产生的良好的吸收能力，柔软度和 /或泡沫的灵活性及其可回收性质。

公开(公告)号：US20080115825A1

公开(公告)日：2008-05-22

申请号：US11857195

申请日：2007-09-18

申请人： Rajen M. Patel ,  Shaofu Wu ,  Mark T. Bernius ,  Mohamed Esseghir ,  Robert L. McGee ,  Michael H. Mazor ,  John Naumovitz

发明人： Rajen M. Patel ,  Shaofu Wu ,  Mark T. Bernius ,  Mohamed Esseghir ,  Robert L. McGee ,  Michael H. Mazor ,  John Naumovitz

IPC分类号： H01L31/00

CPC分类号： C08F210/02 ,  B32B17/10018 ,  B32B17/10678 ,  B32B17/10697 ,  H01L31/048 ,  H01L31/0481 ,  Y02E10/50

摘要： An electronic device module comprises: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising an ethylene multi-block copolymer. Typically, the polyolefin material is an ethylene multi-block copolymer with a density of less than about 0.90 grams per cubic centimeter (g/cc). The polymeric material can fully encapsulate the electronic device, or it can be laminated to one face surface of the device. Optionally, the polymeric material can further comprise a scorch inhibitor, and the copolymer can remain uncrosslinked or it can be crosslinked.

摘要翻译： 电子设备模块包括：A.至少一个电子设备，例如太阳能电池和B.与电子设备的至少一个表面紧密接触的聚合材料，聚合物材料包含乙烯多嵌段共聚物。 通常，聚烯烃材料是密度小于约0.90克/立方厘米（g / cc）的乙烯多嵌段共聚物。 聚合物材料可以完全封装电子器件，或者它可以层压到器件的一个表面。 任选地，聚合物材料还可以包含焦烧抑制剂，并且该共聚物可以保持未交联或可以交联。

公开(公告)号：US06239217B1

公开(公告)日：2001-05-29

申请号：US09400567

申请日：1999-09-21

申请人： David H. Bank ,  John M. Warakomski ,  Shaofu Wu ,  Kalyan Sehanobish

发明人： David H. Bank ,  John M. Warakomski ,  Shaofu Wu ,  Kalyan Sehanobish

IPC分类号： C08L5300

CPC分类号： C08L25/06 ,  C08L23/16 ,  C08L53/02 ,  C08L91/00 ,  C08L2666/02

摘要： A composition of matter comprising: A) from 25 to 90 parts by weight of a syndiotactic, vinylaromatic polymer, B) from 5 to 30 parts by weight of an oil extended, elastomeric polyolefin; C) from 1 to 10 parts by weight of a compatibilizer comprising a styrene containing block copolymer or a hydrogenated derivative thereof; D) from 0 to 25 parts by weight of a domain forming rubbery polymer comprising a styrene/conjugated diene triblock copolymer or a hydrogenated derivative thereof; E) from 0 to 5 parts by weight of a nucleator for the syndiotactic, vinylaromatic thermoplastic resin, F) from 0 to 60 parts by weight of a reinforcing agent, and G) from 0 to 90 parts by weight of a polyarylene ether or polar group modified polyarylene ether.

摘要翻译： 一种物质组合物，其包含：A）25至90重量份的间同立构乙烯基芳族聚合物，B）5至30重量份的延油弹性体聚烯烃; C）1至10重量份的 包含苯乙烯嵌段共聚物或其氢化衍生物的增容剂; D）0-25重量份包含苯乙烯/共轭二烯三嵌段共聚物或其氢化衍生物的区域形成橡胶状聚合物; E）0至5份 间同立构乙烯基芳族热塑性树脂的成核剂的重量，F）0至60重量份的增强剂，和G）0至90重量份的聚亚芳基醚或极性基团改性的聚亚芳基醚。