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41.发明授权Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary amino compounds 失效从具有严格位阻的仲氨基化合物的气态混合物中选择性除去硫化氢的方法
公开(公告)号：US4405581A
公开(公告)日：1983-09-20
申请号：US339901
申请日：1982-01-18
CPC分类号： B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a severely sterically hindered secondary amino compound having a cumulative .sup.- E.sub.s value (Taft's steric hindrance constant) greater than about 1.75 whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气体混合物与包含具有大于约1.75的累积-E值（塔夫脱空位阻抗常数）的严重空间位阻的仲氨基化合物的吸收剂溶液接触来实现从含有H 2 S和CO 2的常规气态混合物中选择性除去H 2 S气体。 从而从混合物中选择性地吸收H2S。
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42.发明授权Process for selective removal of H.sub.2 S from mixtures containing H.sub.2 .sub.2 with tertiary amino azabicyclic alcohols 失效从含有H 2 S和CO 2的混合物中选择性除去H 2 S与叔氨基氮杂双环醇的方法
公开(公告)号：US4405580A
公开(公告)日：1983-09-20
申请号：US339898
申请日：1982-01-18
CPC分类号： B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a tertiary amino azabicyclic alcohol whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气态混合物与包含叔氨基氮杂二醇的吸收剂溶液接触，从而从混合物中选择性吸收H 2 S，可以将H2S气体从含有H 2 S和CO 2的常规气态混合物中选择性地除去。
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43.发明授权Non-sterically hindered-sterically hindered amine co-promoted acid gas scrubbing solution and process for using same 失效非位阻位阻胺共同促进的酸性气体洗涤溶液及其使用方法
公开(公告)号：US4405577A
公开(公告)日：1983-09-20
申请号：US321103
申请日：1981-11-13
申请人： Guido Sartori , David W. Savage
发明人： Guido Sartori , David W. Savage
CPC分类号： B01D53/1493 , Y02C10/06
摘要： The present invention relates to an alkaline promoter system comprising specific mixtures of nonsterically hindered amino compounds and sterically hindered amino acids and their use in acid gas scrubbing processes. The preferred promoter system comprises a mixture of (i) diethanol amine or 1,6-hexanediamine and (ii) N-secondary butyl glycine or pipecolinic acid.
摘要翻译： 本发明涉及包含非阻碍氨基化合物和空间位阻氨基酸的特定混合物的碱性助催化剂体系及其在酸性气体洗涤方法中的用途。 优选的助催化剂体系包含（i）二乙醇胺或1,6-己二胺和（ii）N-仲丁基甘氨酸或哌啶酸的混合物。
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公开(公告)号：US4094957A
公开(公告)日：1978-06-13
申请号：US750520
申请日：1976-12-14
申请人： Guido Sartori , David W. Savage
发明人： Guido Sartori , David W. Savage
CPC分类号： B01D53/1493
摘要： Acidic components are removed from gaseous mixtures by contacting the gaseous mixture with an aqueous solution comprising (1) a basic salt and (2) an activator for said basic salt comprising at least one sterically hindered amine and an aminoacid which is a cosolvent for the sterically hindered amines. The aminoacid serves to prevent phase separation of the aqueous solution at high temperatures and low fractional conversions during the contacting.
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