Massive bodies containing free halogen source for producing highly converted solutions of chlorine dioxide
    51.
    发明授权
    Massive bodies containing free halogen source for producing highly converted solutions of chlorine dioxide 有权
    含有游离卤素源的大量物质用于生产高度转化的二氧化氯溶液

    公开(公告)号:US07182883B2

    公开(公告)日:2007-02-27

    申请号:US10744481

    申请日:2003-12-23

    IPC分类号: C01B11/10 C01B11/06 C01B11/02

    摘要: A massive body, e.g., a tablet, for producing a solution of chlorine dioxide when the massive body is added to liquid water. The massive body comprises a metal chlorite such as sodium chlorite, an acid source such as sodium bisulfate and a source of free halogen such as the sodium salt of dichloroisocyanuric acid or a hydrate thereof. The concentration of free halogen in the solution will be: (a) less than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.25:1 by weight; or (b) equal to or greater than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.50:1 by weight.

    摘要翻译: 当块体被添加到液态水中时,用于产生二氧化氯溶液的大块体例如片剂。 大块体包括金属亚氯酸盐如亚氯酸钠,酸源如硫酸氢钠和游离卤素源如二氯异氰尿酸钠盐或其水合物。 溶液中游离卤素的浓度将是:(a)小于所述溶液中二氧化氯浓度的重量,二氧化氯浓度与二氧化氯和亚氯酸盐阴离子的浓度之比 所述溶液的重量至少为0.25:1; 或(b)等于或大于所述溶液中二氧化氯浓度的重量,并且二氧化氯浓度与所述溶液中二氧化氯和亚氯酸盐阴离子的浓度之和的比例为至少0.50: 1重量。

    Catalyst for selective oxidation of unsaturated hydrocarbons and methods
of making and using the same
    54.
    发明授权
    Catalyst for selective oxidation of unsaturated hydrocarbons and methods of making and using the same 失效
    用于不饱和烃的选择性氧化的催化剂及其制备和使用方法

    公开(公告)号:US5948683A

    公开(公告)日:1999-09-07

    申请号:US953871

    申请日:1997-10-18

    摘要: A selective catalytic material is used to catalyze selective oxidation of unsaturated hydrocarbons, e.g., olefins, in the presence of carbon monoxide. The catalytic material comprises phosphated ceria containing from 0.1 to 20, preferably from 1 to 5, percent by weight phosphate component (calculated as elemental phosphorus). The phosphated ceria may be made by mixing particles of ceria and a solution containing phosphates to disperse the desired amount of phosphate component on the ceria and calcining the particles after separation of them from the solution. The resulting selective catalytic material is contacted under oxidizing conditions with a gas stream containing an oxidant, e.g., air, carbon monoxide and one or more unsaturated hydrocarbons. The selective catalytic material (24a) may be disposed on a sensor (24) disposed within a conduit (18) downstream of a conventional treatment catalyst (16) to evaluate the performance of the latter by measuring the extent of unsaturated hydrocarbon oxidation catalyzed by the selective catalytic material (24a) in the treated gas.

    摘要翻译: 选择性催化材料用于在一氧化碳存在下催化不饱和烃如烯烃的选择性氧化。 催化材料包含含有0.1至20,优选1至5重量百分比的磷酸盐组分(以元素磷计算)的磷酸化二氧化铈。 磷酸化二氧化铈可以通过混合二氧化铈的颗粒和含有磷酸盐的溶液以将所需量的磷酸盐组分分散在二氧化铈上并在将颗粒从溶液中分离之后进行煅烧来制备。 所得到的选择性催化材料在氧化条件下与含有氧化剂如空气,一氧化碳和一种或多种不饱和烃的气流接触。 选择性催化材料(24a)可以设置在设置在常规处理催化剂(16)下游的导管(18)内的传感器(24)上,以评估后者的性能,通过测量由 处理气体中的选择性催化材料(24a)。

    Highly porous amorphous titania and titania/silica phases
    55.
    发明授权
    Highly porous amorphous titania and titania/silica phases 失效
    高度多孔的无定形二氧化钛和二氧化钛/二氧化硅相

    公开(公告)号:US5162283A

    公开(公告)日:1992-11-10

    申请号:US644151

    申请日:1991-01-22

    申请人: Ahmad Moini

    发明人: Ahmad Moini

    IPC分类号: B01J21/06 B01J21/08 B01J37/03

    摘要: There is provided a highly porous amorphous titania or titania/silica material. The material may be prepared by gelling a reaction mixture comprising hydrolyzable titanium and optionally, hydrolyzable silicon compounds, such as titanium diisopropoxide (2,4-pentanedionate) and tetraethylorthosilicate, a nonaqueous solvent, such as ethanol, and water, followed by drying the gel. The titania or titania/silica material may be used as a catalyst, a catalyst support or a sorbent.

    摘要翻译: 提供了高度多孔的无定形二氧化钛或二氧化钛/二氧化硅材料。 可以通过将包含可水解的钛和任选的可水解的硅化合物如二异丙氧基钛(2,4-戊二酮)和原硅酸四乙酯,非水溶剂如乙醇和水的反应混合物凝胶化,然后将凝胶 。 二氧化钛或二氧化钛/二氧化硅材料可以用作催化剂,催化剂载体或吸附剂。

    Dried metal oxide and clay particle compositions and method for the
preparation thereof
    56.
    发明授权
    Dried metal oxide and clay particle compositions and method for the preparation thereof 失效
    干金属氧化物和粘土颗粒组合物及其制备方法

    公开(公告)号:US4981825A

    公开(公告)日:1991-01-01

    申请号:US406094

    申请日:1989-09-12

    IPC分类号: B01J21/16

    CPC分类号: B01J21/16

    摘要: Dried compositions of inorganic metal oxide and clay particles wherein the oxide particles are substantially segregated from each other by the clay particles are described. The compositions have a high surface area and are useful for catalytic gaseous reactions and removal of impurities from gas.

    摘要翻译: 描述了其中氧化物颗粒通过粘土颗粒彼此基本分离的无机金属氧化物和粘土颗粒的干组合物。 该组合物具有高的表面积,可用于催化气体反应和从气体中除去杂质。

    Massive bodies containing free halogen source for producing highly converted solutions of chlorine dioxide
    58.
    发明授权
    Massive bodies containing free halogen source for producing highly converted solutions of chlorine dioxide 有权
    含有游离卤素源的大量物质用于生产高度转化的二氧化氯溶液

    公开(公告)号:US08262929B2

    公开(公告)日:2012-09-11

    申请号:US13041393

    申请日:2011-03-05

    IPC分类号: C01B11/10 C01B11/06 C01B11/02

    摘要: A massive body, e.g., a tablet, for producing a thickened solution of chlorine dioxide when the massive body is added to liquid water is disclosed. The massive body comprises a metal chlorite, an acid source and a thickener (incorporated directly into the massive body or added as a component separate from the massive body) and optionally a source of free halogen. The concentration of free chlorine in the solution will be: (a) less than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.25:1 by weight; or (b) equal to or greater than the concentration of chlorine dioxide in said solution on a weight basis and the ratio of the concentration of chlorine dioxide to the sum of the concentrations of chlorine dioxide and chlorite anion in said solution is at least 0.50:1 by weight.

    摘要翻译: 公开了一种大块体,例如片剂,当将大体积添加到液体水中时,用于生产二氧化氯增稠溶液。 大块体包括金属亚氯酸盐,酸源和增稠剂(直接掺入到块状体中或作为与块体分离的组分加入)和任选的游离卤素源。 溶液中游离氯的浓度为:(a)小于所述溶液中二氧化氯浓度的重量,二氧化氯浓度与二氧化氯和亚氯酸根阴离子的浓度之比 所述溶液的重量至少为0.25:1; 或(b)等于或大于所述溶液中二氧化氯浓度的重量,并且二氧化氯浓度与所述溶液中二氧化氯和亚氯酸盐阴离子的浓度之和的比例为至少0.50: 1重量。