Tetrablock copolymer and compositions containing same
    61.
    发明授权
    Tetrablock copolymer and compositions containing same 有权
    四嵌段共聚物和含有它们的组合物

    公开(公告)号:US07001950B2

    公开(公告)日:2006-02-21

    申请号:US10395403

    申请日:2003-03-24

    IPC分类号: C08L53/02

    摘要: Disclosed is a novel tetrablock copolymer having the general configuration of A1-B1-A2-B2, where the A1 and A2 blocks are mono alkenyl arene and the B1 and B2 blocks are blocks of hydrogenated butadiene, having a 1,2-vinyl content of between 25% and 60%. The blocks have well defined molecular weight ranges, resulting in a polymer having a unique set of property advantages. Also disclosed are elastomeric compositions containing the linear hydrogenated block copolymer, a styrene polymer, an ethylene polymer and a tackifying resin. These elastomeric compositions have particular utility in injection molded parts and in extruded parts such as extruded films and fibers.

    摘要翻译: 公开了具有A1-B1-A2-B2的一般构型的新型四嵌段共聚物,其中A1和A2嵌段是单烯基芳烃,B1和B2嵌段是氢化丁二烯的嵌段,其具有1,2-乙烯基含量 在25%至60%之间。 嵌段具有明确的分子量范围,导致聚合物具有独特的一组性能优点。 还公开了包含线性氢化嵌段共聚物,苯乙烯聚合物,乙烯聚合物和增粘树脂的弹性体组合物。 这些弹性体组合物在注模部件和挤出部件如挤压薄膜和纤维中具有特别的用途。

    Modified radial polymers
    62.
    发明授权
    Modified radial polymers 失效
    改性径向聚合物

    公开(公告)号:US5599879A

    公开(公告)日:1997-02-04

    申请号:US248840

    申请日:1994-05-25

    摘要: A super-tough polymeric composition comprising an engineering thermoplastic and a modified radial polymer. The engineering thermoplastic is selected from the group consisting of polyamides, thermoplastic polyesters, polyphenylene ether resins, polyarylene sulfide resins, polysulfone and the like. The modified radial polymer is modified by grafting a compound containing a carboxylic acid or carboxylic acid derivative group. The modified, radial polymer has from about 3 to about 50 arms, as determined using light scattering techniques and the arms will be olefin polymers. The polymer compositions will yield shaped articles which fail ductilely when tested using ASTM procedure D-256 at room temperature and some at -20.degree. F.

    摘要翻译: 包含工程热塑性塑料和改性径向聚合物的超韧性聚合物组合物。 工程热塑性塑料选自聚酰胺,热塑性聚酯,聚苯醚树脂,聚芳硫醚树脂,聚砜等。 通过接枝含有羧酸或羧酸衍生物基团的化合物改性改性的径向聚合物。 修饰的径向聚合物具有约3至约50个臂,如使用光散射技术测定的,臂将为烯烃聚合物。 聚合物组合物将产生成形制品,当在室温下使用ASTM程序D-256进行测试并且在-20°F下测试时,会使其延性失效。

    Polymer production
    64.
    发明授权
    Polymer production 失效
    聚合物生产

    公开(公告)号:US5387649A

    公开(公告)日:1995-02-07

    申请号:US258807

    申请日:1994-06-13

    CPC分类号: C08F293/00 C08F8/42

    摘要: Novel metallated polyolefins are produced by contacting a polyolefin having a vinylidene group in the terminal portion with organoalkali metal compound in the presence of alkali metal t-alkoxide or tertiary amine. The metallated polyolefin is used to initiate the polymerization of polymerizable monomers to produce block copolymers of at least two blocks, at least one of which is saturated polyolefin.

    摘要翻译: 通过在碱金属叔醇盐或叔胺的存在下,将末端部分中具有亚乙烯基的聚烯烃与有机碱金属化合物接触来制备新的金属化聚烯烃。 金属化聚烯烃用于引发可聚合单体的聚合以产生至少两个嵌段的嵌段共聚物,其中至少一个是饱和聚烯烃。

    High impact resistant blends of thermoplastic polyesters and modified
block copolymers
    65.
    发明授权
    High impact resistant blends of thermoplastic polyesters and modified block copolymers 失效
    热塑性聚酯和改性嵌段共聚物的高抗冲击混合物

    公开(公告)号:US4868243A

    公开(公告)日:1989-09-19

    申请号:US152706

    申请日:1988-02-05

    IPC分类号: C08L67/02

    CPC分类号: C08L67/02

    摘要: A suber-toughened multiphase thermoplastic composition is provided by incorporating an effective amount of at least one functionalized, selectively hydrogenated alkenyl arene/conjugated diene block copolymer to which has been grafted an effective amount of carboxyl functional groups primarily in the alkenyl arene blocks thereof with poly (ethylene terephthalate). The carboxyl functional groups are present as carboxylic acids and their salts in an effective salt to acid ratio for super-toughening the composition. Additionally, the block copolymer phase has an effective phase size for super-toughening the composition.

    摘要翻译: 通过加入有效量的至少一种官能化的选择性氢化的烯基芳烃/共轭二烯嵌段共聚物来提供旭格增韧的多相热塑性组合物,其中已经有效量的羧基官能团主要在其烯基芳烃嵌段中与聚 (对苯二甲酸乙二醇酯)。 羧基官能团作为羧酸及其盐以有效的盐与酸的比例存在,用于超级组合物的增韧。 此外,嵌段共聚物相具有用于超增韧组合物的有效相尺寸。

    Block copolymer and method of preparing same
    66.
    发明授权
    Block copolymer and method of preparing same 失效
    嵌段共聚物及其制备方法

    公开(公告)号:US4851474A

    公开(公告)日:1989-07-25

    申请号:US102465

    申请日:1987-09-29

    申请人: Carl L. Willis

    发明人: Carl L. Willis

    IPC分类号: C08G81/02

    CPC分类号: C08G81/027

    摘要: A modified unsaturated polyester useful in preparing molded products having improved impact resistance and surface characteristics is prepared as a block copolymer comprising at least one polyester block and an elastomeric block. The modified unsaturated polyester is prepared by reacting an elastomeric polymer having at least one terminal functional group selected from the group consisting of carboxyl groups, hydroxyl groups and mixtures thereof with either a preformed unsaturated polyester, thereby producing the modified unsaturated polyester directly or with monomer useful in preparing an unsaturated polyester and thereafter growing the unsaturated polyester via condensation of additional monomer. The elastomer is, preferably, a block copolymer comprising at least one polymer block containing predominantly monoalkenyl aromatic hydrocarbon monomer and at least one polymer block containing predominantly conjugated diolefin monomer units. The modified unsaturated polyester is useful in thermosetting resin compositions.

    Olefin polymerization
    67.
    发明授权
    Olefin polymerization 失效
    烯烃聚合

    公开(公告)号:US4451633A

    公开(公告)日:1984-05-29

    申请号:US409744

    申请日:1982-08-19

    摘要: Completely polymerizing olefinic monomer feed, in contact with a coordination catalyst suitable for olefin polymerization, in a mold having the shape of the article, at conditions under which the polymer is produced as a coherent, useful article in the shape of the interior of the mold, and removing the article from the mold. This method permits the production of polyolefin articles which are difficult or impossible to produce from polyolefin powder or pellets by conventional methods, such as articles of polyolefins of such high molecular weight that the polymer would not be processable by a melt process; articles containing extremely high filler loading; articles containing interconnected reinforcement; and articles from molds which require substantial flows through narrow passages.

    摘要翻译: 在适合于烯烃聚合的配位催化剂接触的烯烃单体进料在具有制品形状的模具中,在聚合物生产为模具内部形状的相干有用制品的条件下完全聚合 ,并将物品从模具中取出。 该方法允许生产由聚烯烃粉末或颗粒通过常规方法难以或不可能生产的聚烯烃制品,例如聚合物不能通过熔融方法加工的高分子量聚烯烃制品; 含有极高填料载量的物品; 包含互连钢筋的物品; 和来自模具的物品,其需要大量流动通过狭窄的通道。