公开(公告)号：US20050159510A1

公开(公告)日：2005-07-21

申请号：US10934904

申请日：2004-09-03

申请人： Sonja Smolak ,  Franz Stelzer ,  Norbert Moszner ,  Volker Rheinberger

发明人： Sonja Smolak ,  Franz Stelzer ,  Norbert Moszner ,  Volker Rheinberger

IPC分类号： A61K6/02 ,  A61K6/027 ,  A61K6/083 ,  A61K6/087 ,  C08G61/00 ,  C08G61/08 ,  C08K9/04 ,  C08K9/12 ,  C08L65/00 ,  C08K9/00

CPC分类号： A61K6/083 ,  C08G61/08 ,  C08L101/005

摘要： The invention relates to compositions, polymerizable by ring-opening metathesis, which contain (a) at least one monomer and/or oligomer which is polymerizable by ring-opening metathesis polymerization, (b) at least one filler and (c) at least one initiator for the ring-opening metathesis polymerization. The compositions are characterized in that the initiator is chemically or physically bound to the filler.

摘要翻译： 本发明涉及通过开环复分解可聚合的组合物，其含有（a）至少一种通过开环易位聚合可聚合的单体和/或低聚物，（b）至少一种填料和（c）至少一种 引发剂用于开环易位聚合。 组合物的特征在于引发剂与填料化学或物理结合。

公开(公告)号：US06713555B2

公开(公告)日：2004-03-30

申请号：US10260069

申请日：2002-09-27

申请人： Norbert Moszner ,  Sabine Stein ,  Thomas Völkel ,  Volker Rheinberger

发明人： Norbert Moszner ,  Sabine Stein ,  Thomas Völkel ,  Volker Rheinberger

IPC分类号： C08L8308

CPC分类号： C07F7/1804

摘要： Methylene dithiepane silanes according to Formula I in which R1 is a saturated or unsaturated aliphatic or alicyclic hydrocarbon radical with 1 to 10 carbon atoms, which can be interrupted by one or more oxygen and/or sulphur atoms and can contain one or more ester, carbonyl, amide and/or urethane groups, or is an aromatic or heteroaromatic hydrocarbon radical with 6 to 18 carbon atoms, the hydrocarbon radicals being able to be substituted or unsubstituted; R2 has one of the meanings given for R1 or is absent; R3 has one of the meanings given for R1 or is absent; R4 is equal to —(CHR6)n—, —Y—CO—NH—(CHR6)n—, —Y—CO—NH—R5—, —(CHR6)n—S—R5—, —S—R5—, —CO—O—R5— or is absent, with n being equal to 1 to 4, R6 is hydrogen, C1 to C10 alkyl or C6 to C10 aryl, R5 has one of the meanings given for R1 and Y stands for an O or S atom or is absent; with R5 and R6 being able to be substituted or unsubstituted; X is a hydrolyzable group; a, b, c and x each independently of each other being 1, 2 or 3; and the sum of a+x=2 to 4. The silanes are particularly suitable for the preparation of dental materials.

摘要翻译： 具有式Iin的亚甲基二噻吩烷硅烷，其中R 1是具有1至10个碳原子的饱和或不饱和脂族或脂环族烃基，其可被一个或多个氧和/或硫原子间隔并且可含有一个或多个酯 ，羰基，酰胺和/或氨基甲酸酯基团，或是具有6至18个碳原子的芳族或杂芳族烃基，所述烃基能够被取代或未取代; R 2具有R 1给出的含义之一或不存在; R 3具有R 1给出的含义之一或不存在; R 4等于 - （CHR 6）n - ， - O-CO-NH-（CHR 6）n-，-Y-CO-NH-R 5 - ， - （CHR < 6））nSR 5 - ， - SR 5 - ， - CO-OR 5 - 或不存在，n等于1至4，R 6是氢，C 1至C 10烷基或C 6 对于C 10芳基，R 5具有对R 1给出的含义之一，Y表示O或S原子或不存在; 其中R 5和R 6能够被取代或未取代; X是可水解基团; a，b，c和x各自独立地为1,2或3; 并且a + x = 2至4的总和。硅烷特别适用于制备牙科材料。

公开(公告)号：US06569917B1

公开(公告)日：2003-05-27

申请号：US09488489

申请日：2000-01-20

申请人： Norbert Moszner ,  Thomas Völkel ,  Sabine Stein ,  Volkner Rheinberger

发明人： Norbert Moszner ,  Thomas Völkel ,  Sabine Stein ,  Volkner Rheinberger

IPC分类号： A16F200

CPC分类号： A61K6/0023 ,  A61K6/083 ,  A61K6/093 ,  C08L51/085 ,  C08L83/12

摘要： The invention relates to dental materials which contain at least one polysiloxane based on one or several silanes according to formula (I) [(Wq—R6—Z)p—R3]mY—R2—SiXnR13−n  Formula (I) in which X stands for a halogen atom, a hydroxyl, alkoxy and/or acyloxy group; n is equal to 1 to 3, R1 stands for an alkyl, alkenyl, aryl, alkylaryl, arylalkyl group; R2 stands for an alkylene group; R3 stands for a p-time substituted, straight, branched or cyclic, saturated or unsaturated, aromatic or aliphatic organic radical with 2 to 40 carbon atoms and optionally 1 to 6 heteroatoms; R6 stands for a q-times substituted, straight, branched or cyclic organic radical with 1 to 20 carbon atoms or is absent; p is equal to 1 to 6; q is equal to 1 to 6; Y stands for —NR4—, N or —(C═O)—NH—; m is equal to 2 for Y═N and equal to 1 for Y═—NR4—, or —(C═O)—NH—; R4 stands for an alkyl or aryl group; Z stands for O, S, —(C═O)—O—, —(C═O)—NH—, —O—(C═O)—NH— or is absent; W stands for CH2═CR5—(C═O)—O—; and R5 stands for a hydrogen atom or an alkyl group and optionally one or several further hydrolytically condensable compounds of silicon, aluminium, zirconium, titanium, boron, tin, vanadium and/or phosphorus.

摘要翻译： 本发明涉及含有至少一种基于一种或几种根据式（I）的硅烷的聚硅氧烷的牙科材料，其中X代表卤素原子，羟基，烷氧基和/或酰氧基; n等于1至3，R1代表烷基，烯基，芳基，烷基芳基，芳基烷基; R2表示亚烷基; R3表示具有2至40个碳原子和任选1至6个杂原子的p时间取代的，直链，支链或环状饱和或不饱和的芳族或脂族有机基团; R6代表具有1至20个碳原子的q次取代的，直链，支链或环状的有机基团或不存在; p等于1至6; q等于1至6; Y代表-NR4-，N或 - （C = O）-NH-; 对于Y = N，m等于2，Y = -NR4-等于1，或 - （C = O）-NH-; R4代表烷基或芳基; Z代表O，S， - （C = O）-O-， - （C = O）-NH-，-O-（C = O）-NH-或不存在; W代表CH 2 = CR 5 - （C = O）-O-; R5代表氢原子或烷基，以及任选的一种或几种其它可水解缩合的硅，铝，锆，钛，硼，锡，钒和/或磷的化合物。

公开(公告)号：US6136887A

公开(公告)日：2000-10-24

申请号：US266509

申请日：1999-03-11

申请人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Voelkel ,  Urs Karl Fischer

发明人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Voelkel ,  Urs Karl Fischer

IPC分类号： A61K6/00 ,  A61K6/083 ,  C07C69/743 ,  C08F22/10

CPC分类号： A61K6/0023 ,  A61K6/083 ,  C07C69/743 ,  C08F22/105

摘要： The invention relates to vinylcyclopropane derivatives according to the formula ##STR1## in which A is --[--Y--CO--C(.dbd.CH.sub.2)R.sup.4 ].sub.m or --C(.dbd.CH.sub.2)CO--O--C.sub.1-4 -alkyl, U and X, independently of each other, stand for CO, COO or CONH; Y and Z stand for O or NH or are absent, but Y and Z cannot be absent at the same time; n, m stand for a whole number from 0 to 4, but n and m are not 0 at the same time; R.sup.1 is H, CH.sub.3 or Cl; R.sup.2, R.sup.3 stand for H, a C.sub.1 - to C.sub.10 -alkyl or alkylene radical, which can be interrupted by O, S or NH, for a C.sub.6 - to C.sub.14 -aryl or arylene, C.sub.7 - to C.sub.14 -alkylaryl or alkylarylene or a C.sub.5 - to C.sub.8 -cycloalkyl or cycloalkylene radical; and R.sup.4 is H or a C.sub.1 - to C.sub.10 -alkyl radical, and to processes for their production. The compounds are suitable in particular for the production of adhesives, cements, composites and mouldings.

摘要翻译： 本发明涉及下式的乙烯基环丙烷衍生物，其中A为 - [ - Y-CO-C（= CH2）R4] m或-C（= CH2）CO-O-C1-4烷基，U和X， 独立于代表CO，COO或CONH; Y和Z代表O或NH或不存在，但Y和Z不能同时不存在; n，m表示从0到4的整数，但n和m不同时为0; R1是H，CH3或Cl; R2，R3代表H，C 1至C 10 - 烷基或亚烷基，其可被O，S或NH中断，用于C 6至C 14 - 芳基或亚芳基，C 7至C 14 - 烷基芳基或烷基亚芳基或 C5至C8-环烷基或环亚烷基; 并且R4是H或C1-至C10-烷基，并且用于其制备。 该化合物特别适用于粘合剂，水泥，复合材料和模制品的生产。

公开(公告)号：US07585901B2

公开(公告)日：2009-09-08

申请号：US11752652

申请日：2007-05-23

申请人： Norbert Moszner ,  Armin de Meijere ,  Frank Zeuner ,  Urs Karl Fischer

发明人： Norbert Moszner ,  Armin de Meijere ,  Frank Zeuner ,  Urs Karl Fischer

IPC分类号： A61K6/083 ,  A61C5/00 ,  C08F232/08

CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  A61K6/09 ,  C07C69/608 ,  C07C69/675 ,  C07C69/716 ,  C07C271/28 ,  C07C2602/18 ,  C07D307/93 ,  C07D311/94 ,  C07D335/04 ,  C08L33/00 ,  C08L75/16

摘要： Bicyclic cyclopropane derivatives of the general Formula (I) in which n+m is 0 to 8; r is 1 to 4; R1 is absent or is a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 arylene or C7-C20 alkylenearylene radical; R2 is for r=1 a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C4-C12 radical, a C6-C14 aryl or a C7-C20 alkylaryl radical; is for r>1 an r-times substituted aliphatic C1 to C20 radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, an aromatic C6-C14 radical or aliphatic-aromatic C7-C20 radical; X is absent or is —CO—O—, —CO—NH— or —O—CO—NH—, and Y is CH2, O or S which is suitable in particular for the preparation of dental materials.

摘要翻译： 通式（I）的双环环丙​​烷衍生物，其中n + m为0至8; r为1〜4; R1不存在或是可被O或S间隔的C 1 -C 20亚烷基，脂环族C 4 -C 12基团，双环C 4 -C 12基团，C 6 -C 14亚芳基或C 7 -C 20亚烷基亚芳基基团; R2为r = 1，可被O或S间隔的C1-C20烷基，脂环族C 4 -C 12基，双环C 4 -C 12基，C 6 -C 14芳基或C 7 -C 20烷基芳基; 对于r> 1，可以被O或S间隔的r-次取代的脂族C1至C20基团，脂环族C 4 -C 12基团，芳族C 6 -C 14基团或脂族 - 芳族C 7 -C 20基团; X不存在或是-CO-O-，-CO-NH-或-O-CO-NH-，Y是CH2，O或S，其特别适用于制备牙科材料。

公开(公告)号：US20080058443A1

公开(公告)日：2008-03-06

申请号：US11897228

申请日：2007-08-29

申请人： Norbert Moszner ,  Helmut Ritter ,  Urs-Karl Fischer ,  Monir Tabatabai ,  Matthias Schaub ,  Andreas Utterodt

发明人： Norbert Moszner ,  Helmut Ritter ,  Urs-Karl Fischer ,  Monir Tabatabai ,  Matthias Schaub ,  Andreas Utterodt

IPC分类号： A61K6/08

CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  A61K6/087 ,  C08F222/1006 ,  C08L61/14 ,  C08L33/04

摘要： The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.

摘要翻译： 本发明涉及由杯形[n]芳烃组成的牙科用材料，以及其在牙科领域中用于粘合剂，复合材料，粘合剂和涂层材料的用途。 这些材料包括：（a）0.5至90重量％的至少一种根据式（I）的可聚合杯[n]芳烃，（b）0.01至5重量％的引发剂，（c）0至90重量％ 的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合，（d）0至85重量％的填料，（e）0.01至5重量％的添加剂和 （f）0〜70重量％的溶剂。

公开(公告)号：US07101942B2

公开(公告)日：2006-09-05

申请号：US10053460

申请日：2002-01-18

申请人： Norbert Moszner ,  Thomas Völkel ,  Volker Rheinberger ,  Ulrich Schubert

发明人： Norbert Moszner ,  Thomas Völkel ,  Volker Rheinberger ,  Ulrich Schubert

IPC分类号： C08F30/04

CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00

摘要： Dental material containing a cluster according to the general formula [(M1)a(M2)bOc(OH)d(OR)e(L-Sp-Z)f] (I) in which M1, M2, independently of each other, stand in each case for a metal atom of the IIIrd or Vth main groups or the Ist to VIIIth sub-groups of the periodic table; R is an alkyl group with 1 to 6 carbon atoms; L is a co-ordinating group with 2 to 6 complexing centres; Sp is a spacer group or is absent; Z is a polymerizable group; c is a number from 1 to 30; d, e, independently of each other, are in each case a number from 1 to 30; f is a number from 2 to 30, any charge of the cluster (I) present being equalized by counterions.

摘要翻译： 含有根据通式[（M 1））的簇的牙科材料[（M 2））B O （OH）n（OR）e（L-Sp-Z）F（ⅰ）在（ⅰ）中 其中M 1，M 2，2彼此独立地代表IIIrd或Vth主族或第I至VIII族的金属原子 周期表; R是具有1至6个碳原子的烷基; L是一个有2到6个络心中心的协调小组; Sp是间隔基团或不存在; Z是可聚合基团; c是从1到30的数字; d，e彼此独立地在每种情况下为1至30的数; f是从2到30的数字，存在的群集（I）的任何费用由抵抗衡平衡。

公开(公告)号：US06653375B2

公开(公告)日：2003-11-25

申请号：US09236787

申请日：1999-01-25

申请人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Völkel ,  Urs Karl Fischer

发明人： Norbert Moszner ,  Volker Rheinberger ,  Thomas Völkel ,  Urs Karl Fischer

IPC分类号： A61K6083

CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/09 ,  C07C271/20 ,  C08L75/16

摘要： The invention relates to urethane di(meth)acrylate derivatives of 1-3-bis(1-isocyanato-1-methylethyl)benzene according to Formula (I) in which R is hydrogen or a straight-chained C1-C8 alkyl radical; X and Y independently of each other stand for R1 being a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; R2 hydrogen, a C1- to C5-alkyl or a substituted or unsubstituted C6- to C12-aryl radical; R3 hydrogen or a methyl radical; R4 a C1- to C8-alkylene radical which can be broken by oxygen atoms, or a phenylene radical; R5 hydrogen or a methyl radical; R6 a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; Z being —CO— or a chemical bond and W standing for oxygen, sulphur or NR7, R7 being hydrogen or a straight-chained C1- to C6-alkyl radical. The substances are suitable in particular for the production of dental materials.

摘要翻译： 本发明涉及式（I）的1,3-双（1-异氰酸基-1-甲基乙基）苯的氨基甲酸酯二（甲基）丙烯酸酯衍生物，其中R为氢或直链C1-C8烷基; X和Y彼此独立地代表R 1是取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; R 2为氢，C 1至C 5 - 烷基或取代或未取代的C 6至C 12 - 芳基; R 3氢或甲基; R 4可以被氧原子断裂的C1-至C8-亚烷基或亚苯基; R 5氢或甲基; R 6取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; Z是-CO-或化学键，W代表氧，硫或NR 7，R 7是氢或直链C 1至C 6烷基。 这些物质特别适用于生产牙科材料。

公开(公告)号：US06172131B2

公开(公告)日：2001-01-09

申请号：US09169066

申请日：1998-10-09

申请人： Norbert Moszner ,  Frank Zeuner ,  Volker Rheinberger

发明人： Norbert Moszner ,  Frank Zeuner ,  Volker Rheinberger

IPC分类号： A61K6083

CPC分类号： C08F30/02 ,  A61K6/083 ,  A61K6/0023 ,  C08L33/10 ,  C08L33/08

摘要： Hydrolysis-stable and polymerizable acrylphosphonic acids are described which are particularly suitable as a component of dental adhesives owing to their adhesion-promoting properties.

摘要翻译： 描述了水解稳定和可聚合的丙烯酸膦酸，其特别适合作为牙科粘合剂的组分，这是由于其粘合促进性质。

公开(公告)号：US6034151A

公开(公告)日：2000-03-07

申请号：US47592

申请日：1998-03-25

申请人： Norbert Moszner ,  Thomas Voelkel ,  Frank Zeuner ,  Sabine Stein ,  Volker Rheinberger

发明人： Norbert Moszner ,  Thomas Voelkel ,  Frank Zeuner ,  Sabine Stein ,  Volker Rheinberger

IPC分类号： A61K6/093 ,  C07F7/18 ,  C08G77/22 ,  C08G77/58

CPC分类号： A61K6/093 ,  C07F7/1836 ,  C07F7/184 ,  C08G77/22 ,  C08G77/58 ,  Y10S522/908

摘要： Polymerizable and hydrolyzable vinylcyclopropane silanes and in particular silicic acid condensates which can be prepared therefrom are described, which exhibit only a low volume shrinkage on polymerization and produce polymers with high mechanical strength and therefore can be used above all as dental material or a constituent thereof.

摘要翻译： 描述了可聚合和可水解的乙烯基环丙烷硅烷，特别是可由其制备的硅酸缩合物，其在聚合时仅显示低体积收缩率并且产生具有高机械强度的聚合物，因此可以首先被用作牙科材料或其组分。