摘要:
A RUBBER LATEX OF SULFONATED BUTYL RUBBER CONTAINING >0.5 MOLE PERCENT SO3H IS PREPARED BY FORMING AN EMULSION OF A SOLUTION OF SULFONATED BUTYL RUBBER IN A SUITABLE SOLVENT USING NON-IONIC EMULSIFIERS AND THEREAFTER STRIPPING OFF THE SOLVENT TO LEAVE A LATEX OF SULFONATED BUTYL RUBBER DISPERSED IN WATER. PRIOR TO STRIPPING THE SOLVENT, THE EMULSIFIERS ARE REMOVED FROM THE SYSTEM BY CENTRIFUGATION, THE SULFONATED BUTYL RUBBER BEING SELF-EMULSIFIABLE, ONCE IT HAS BEEN DISPERSED. PLASTICIZERS ARE ADDED TO THE LATEX TO PREVENT CRACKING OF FILMS PREPARED THEREFROM.
摘要:
LOW MOLECUAR WEIGHT BUTYL-TYPE COPOLYMERS HAVING NARROW MOLECULAR WEIGHT DISTRIBUTIONS ARE PREPARED BY CONTACTING A HIGHER MOLECULAR WEIGHT BUTYL-TYPE COPOLYMER, E.G., A BUTYL RUBBER, WITH A CATALYST COMPOSITION COMPRISING A TRANSITION METAL SALT, AN ORGANOMETALLIC COMPOUND OF A METAL OF GROUP I-A, II-A, II-B, OR III-A OF THE PERIODIC TABLE, A PROTON DONOR, AND HYDROGEN. THE CATALYST COMPOSITION PREFERABLY COMPRISES A HALIDE OF TUNGSTEN, MOLYBDENUM, OR RHENIUM, AN ALKYL ALUMINUM HALIDE, A LOWER ALKANOL, AND HYDROGEN.
摘要:
An improved process for separating a volatile organic diluent from a low density olefin polymer in solution of suspension comprises vaporizing the diluent with steam and water at an elevated temperature and separating a slurry of polymer and water; discharging a vapor stream containing a small amount of polymer particles into a cyclone vessel; withdrawing the vapors substantially free of polymer and recovering the diluent; and removing the separated particles from the cyclone with a flow of water at a downward velocity exceeding the rise velocity of the particles through the water to prevent agglomeration of the particles.
摘要:
Functional surface coating compositions, prepared by blending a mixture of a fluorine containing phosphate material and a nonfluorine containing material in aqueous medium, impart solvent, grease and oil resistance to cellulosic materials.
摘要:
AN UMPROVED POLYCHLOROPRENE LATEX, USEFUL FOR MAKING POLYISOCYANATE-MODIFIED FOAMS, COMPRISES THE PRODUCT PRODUCED BY HEATING A FRESHLY PREPARED POLYCHLOROPRENE LATEX, HAVING A PH HIGHER THAN 11, AT A TEMPERATURE IN THE RANGE OF 60 TO 90* C. UNTIL THE PH IS LOWERED TO THE RANGE OF 9.5 TO 10. IN A PREFERRED EMBODIMENT THE HEATING IS CARRIED OUT ON A LATEX CONTAINING ABOUT 50% SOLIDS AND THE LATEX IS SUBSEQUENTLY CREAMED TO ABOUT 60% SOLIDS.
摘要:
The preparation of a high solids, low viscosity rubber latex by blending a fast reaction latex of small particles with a slow reaction latex of large particles, before concentration, and preferably before stripping for removal of unreacted monomers, stripping and concentrating the blend to about 50 percent solids, freezing the concentrate after acidifying to a pH of about 8.3, and then thawing and concentrating the frozen blend to a solids content above 60 percent.
摘要:
RECOVERY OF POLYMERS FROM SOLUTIONS THEREOF IN A HYDROCARBON SOLVENT BY A STEAM STRIPPING PROCESS IN WHICH WATER CONTAINING MAGNESIUM OR CALCIUM IONS IS EMPLOYED TO INCREASE EFFECTIVENESS OF DISPERSING AGENTS EMPLOYED TO PREVENT AGGLOMERATION OF POLYMERS. THE HARD WATER IS
INTRODUCED INTO THE SYSTEM AT A LOCATION TO ACCOMPLISH THE ABOVE OBJECT AND TO PROVIDE ADDITIONAL PROCESSING ADVANTAGES.