Method for end-capping polycarbonate resins and composition for use in same
    71.
    发明授权
    Method for end-capping polycarbonate resins and composition for use in same 有权
    封端聚碳酸酯树脂的方法及其组合物

    公开(公告)号:US06500914B1

    公开(公告)日:2002-12-31

    申请号:US09682724

    申请日:2001-10-10

    IPC分类号: C08G6400

    CPC分类号: C08G64/14 C08G64/42

    摘要: A method for end-capping polycarbonate resins, comprising the step of processing a mixture comprising a polycarbonate having free hydroxyl-end groups and an end-capping reagent in a melt transesterification reaction to produce a polycarbonate resin, wherein the end-capping reagent comprises a mixture of:(a) at least one species of a symmetrical activated aromatic carbonate, and (b) at least one species of a symmetrical non-activated aromatic carbonate, whereby said end-capping reagent reacts with at least some of the free hydroxyl end-groups of the polycarbonate to produce an end-capped polycarbonate resin.

    摘要翻译: 一种封端聚碳酸酯树脂的方法,包括在熔融酯交换反应中处理包含游离羟基端基的聚碳酸酯和封端剂的混合物以制备聚碳酸酯树脂的步骤,其中封端剂包括 混合物:(a)至少一种对称活性芳族碳酸酯,和(b)至少一种对称非活化芳族碳酸酯,其中所述封端剂与至少一些游离羟基末端反应 的聚碳酸酯组,以制备端封聚碳酸酯树脂。

    Solventless preparation of ester-substituted diaryl carbonates
    72.
    发明授权
    Solventless preparation of ester-substituted diaryl carbonates 有权
    酯取代的碳酸二芳基酯的无溶剂制备

    公开(公告)号:US06469192B1

    公开(公告)日:2002-10-22

    申请号:US09911527

    申请日:2001-07-24

    IPC分类号: C07C6996

    CPC分类号: C07C68/02 C07C69/96

    摘要: High yields of ester-substituted diary carbonates such as bis-methyl salicyl carbonate were obtained by the condensation of ester-substituted phenols with phosgene in the presence of a phase transfer catalyst (PTC) and optionally a tertiary amine catalyst in a solvent free reaction system comprising an aqueous phase held at a pH of 8.3 or higher. The optimized conditions of the present invention use an excess of ester-substituted phenol relative to phosgene and high conversion of phosgene to ester-substituted diaryl carbonate is observed. The product ester-substituted diaryl carbonate may be conveniently isolated as a solid by filtration or as a liquid in which the excess ester-substituted phenols serves as solvent. The method represents an attractive route for the manufacture of bis methyl salicyl carbonate and ester-substituted diaryl carbonates generally.

    摘要翻译: 通过在相转移催化剂(PTC)和任选的叔胺催化剂存在下,在无溶剂反应体系中,酯取代的酚与光气的缩合得到高收率的酯取代的二元碳酸酯,例如碳酸双甲基水杨酸酯 包含保持在8.3或更高的pH的水相。 本发明的优化条件相对于光气使用过量的酯取代的苯酚,观察到光气转化为酯取代的碳酸二芳基酯的高转化率。 产物酯取代的碳酸二芳基酯可以通过过滤或作为其中过量的酯取代的酚用作溶剂的液体方便地分离为固体。 该方法通常用于制造碳酸双甲基水杨酸酯和酯取代的二芳基碳酸酯的有吸引力的途径。