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公开(公告)号：US09751042B2
公开(公告)日：2017-09-05
申请号：US14801380
申请日：2015-07-16
Applicant: New Jersey Institute of Technology
Inventor： Kamalesh K. Sirkar
CPC classification number: B01D53/1475 , B01D53/1425 , B01D53/1493 , B01D53/229 , B01D2053/224 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20489 , B01D2252/30 , B01D2257/504 , B01D2258/0283 , B01D2325/38 , Y02A50/2342 , Y02C10/04 , Y02C10/06 , Y02C10/10
Abstract: The present disclosure provides improved systems, assemblies and methods to remove and recover CO2 from emissions. More particularly, the present disclosure provides improved membrane contactors configured to remove CO2 from flue gas by temperature swing absorption. In exemplary embodiments, the present disclosure provides a novel hollow fiber membrane contactor that integrates absorption and stripping using a nonvolatile reactive absorbent (e.g., 80% polyamidoamine (PAMAM) dendrimer generation 0, and 20% of an ionic liquid (IL)). Equilibrium CO2 absorption in the nonvolatile viscous mixed absorbent is as high as 6.37 mmolCO2/g absorbent in the presence of moisture at 50° C. A novel membrane contactor is provided for CO2 absorption and stripping via a process identified as temperature swing membrane absorption (TSMAB). The contactor integrates non-dispersive gas absorption and hot water-based CO2 stripping in one device/assembly containing two sets of commingled hollow fibers.
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公开(公告)号：US09555363B2
公开(公告)日：2017-01-31
申请号：US14967609
申请日：2015-12-14
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor： Masatoshi Hodotsuka , Satoshi Saito , Mitsuru Udatsu
CPC classification number: B01D53/1425 , B01D53/1475 , B01D53/18 , B01D2252/2021 , B01D2252/2026 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20442 , B01D2252/20447 , B01D2252/20484 , B01D2252/20494 , Y02A50/2342 , Y02C10/04 , Y02C10/06
Abstract: An absorber of a carbon dioxide capture system according to an embodiment includes: a release region for releasing carbon dioxide from an absorbing liquid supplied from a stripper; and a second gas-liquid contact unit to which carbon dioxide released in the release region is supplied together with exhaust gas discharged from a first gas-liquid contact unit. The absorbing liquid having released the carbon dioxide therefrom in the release region is supplied to the second gas-liquid contact unit by an absorbing liquid supply device. The absorbing liquid having passed through the second gas-liquid contact unit is guided to the first gas-liquid contact unit while bypassing the release region. The second gas-liquid contact unit brings the exhaust gas and the absorbing gas into contact with each other so as to cause the carbon dioxide contained in the exhaust gas to be absorbed in the absorbing liquid.
Abstract translation: 根据一个实施方案的二氧化碳捕获系统的吸收器包括：释放区域，用于从从汽提塔供应的吸收液体中释放二氧化碳; 以及与从第一气液接触单元排出的排气一起供给在释放区域中释放的二氧化碳的第二气液接触单元。 在释放区域中释放出二氧化碳的吸收液体通过吸收液体供给装置供给到第二气液接触单元。 已经通过第二气液接触单元的吸收液被引导到第一气液接触单元，同时绕过释放区。 第二气液接触单元使废气和吸收气体彼此接触，以使废气中所含的二氧化碳被吸收在吸收液中。
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公开(公告)号：US20160045857A1
公开(公告)日：2016-02-18
申请号：US14925183
申请日：2015-10-28
Applicant: Evonik Degusssa GmbH
Inventor： Jörn Rolker , Matthias Seiler , Ralf Meier , Udo Knippenberg , Rolf Schneider , Muhammad Irfan , Hari Prasad Mangalapally
CPC classification number: B01D53/18 , B01D53/1425 , B01D53/1456 , B01D53/1475 , B01D53/1493 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20442 , B01D2252/20484 , B01D2252/504 , B01D2257/30 , B01D2257/504 , F23J2219/40 , Y02C10/06
Abstract: The invention is directed to a method for separating acid gases from a gas mixture in which the gas mixture is contacted with an absorption medium which comprises water and at least one amine and has a phase-separation temperature in the range from 0 to 130° C. In addition, the invention is directed to a device which can be used for carrying out this method.
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公开(公告)号：US09243200B2
公开(公告)日：2016-01-26
申请号：US14093371
申请日：2013-11-29
Applicant: Almont Emissions Inc.
Inventor： Bryan Campbell
CPC classification number: C10L3/103 , B01D53/1468 , B01D53/1487 , B01D53/18 , B01D53/52 , B01D2252/20415 , B01D2252/20436 , B01D2252/20452 , B01D2252/20457 , B01D2252/20489 , B01D2252/504 , B01D2256/245 , B01D2257/304 , B01D2257/708 , B01D2257/90
Abstract: A compact treatment apparatus and methodology is provided for scavenging at least H2S from an acid gas stream. The vessel is charged with a batch of an aqueous solution of H2S scavenging treatment liquid. Acid gas is discharged from a sparge bar fit with graduated openings, either graduated from small to large or from a few to many and spaced therealong, for distributed discharge into the treatment liquid. The acid gas percolates up through the liquid and into a vessel headspace, the gas being scrubbed of H2S for producing a treated discharge gas. The treatment solution can be an aqueous solution of incorporating one of several active H2S scavenger ingredients including amine-aldehyde compositions or triazines.
Abstract translation: 提供了一种紧凑的处理设备和方法，用于从酸性气流中清除至少H2S。 向容器中加入一批H 2 S清除处理液的水溶液。 酸性气体从配有刻度开口的喷射棒排出，分级开口从小到大或从几个到多个，并且间隔开，用于分配排放到处理液中。 酸性气体通过液体渗透到容器顶部空间中，气体被H 2 S洗涤以产生经处理的放电气体。 处理溶液可以是包含几种活性H 2 S清除剂组分之一的水溶液，包括胺 - 醛组合物或三嗪。
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公开(公告)号：US09221012B2
公开(公告)日：2015-12-29
申请号：US14153548
申请日：2014-01-13
Applicant: General Electric Company
Inventor： Robert James Perry , Michael Joseph O'Brien
CPC classification number: B01D53/62 , B01D47/00 , B01D53/1475 , B01D53/1493 , B01D2252/20415 , B01D2252/205 , B01D2258/0283 , C07F7/0838 , C10K1/16 , C10L3/104 , Y02C10/04 , Y02C10/06 , Y02P20/152
Abstract: In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.
Abstract translation: 根据一个方面，本发明提供含有如本文所述的氨基 - 硅氧烷结构I或III的组合物。 该组合物可用于从工艺流中捕获二氧化碳。 此外，本发明提供了制备氨基 - 硅氧烷组合物的方法。 本发明的另一方面提供了使用本发明的氨基 - 硅氧烷组合物作为与二氧化碳反应形成与二氧化碳的加合物的物质的方法中减少二氧化碳量的方法。
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公开(公告)号：US20150353454A1
公开(公告)日：2015-12-10
申请号：US14760819
申请日：2014-02-06
Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
Inventor： Masaki Iijima
IPC: C07C29/151 , C01B3/38 , C10L1/06 , C07C29/152 , B01D53/14 , C10G3/00
CPC classification number: C07C29/1518 , B01D53/1425 , B01D53/1475 , B01D2252/20415 , B01D2252/20421 , B01D2252/20484 , B01D2258/0283 , B01D2259/65 , C01B3/38 , C01B3/384 , C01B32/50 , C01B2203/0233 , C01B2203/0495 , C01B2203/061 , C01B2203/0811 , C01B2203/0883 , C01B2203/1058 , C01B2203/1241 , C07C29/152 , C07C29/80 , C10G3/49 , C10L1/06 , C10L2200/0492 , C10L2270/023 , C10L2290/06 , C10L2290/12 , C10L2290/42 , Y02C10/06 , Y02P20/129 , Y02P20/152 , Y02P30/20 , C07C31/04
Abstract: A method or system for recovering carbon dioxide is provided with which in a plant for synthesizing methanol from a hydrocarbon gas or synthesizing gasoline therefrom via methanol, the waste heat of a low-temperature reformed gas, which has conventionally been discarded and is difficult to reutilize, can be effectively utilized. In the system for synthesizing methanol or gasoline from a hydrocarbon gas and for recovering carbon dioxide, a reformed gas is produced by steam reforming of the hydrocarbon gas. Since a combustion discharge gas generates when a fuel gas is burned in order to obtain a heat source for the steam reforming, carbon dioxide is recovered from the combustion discharge gas in an absorption tower (40) using an absorption liquid. In a regeneration tower (10), the reformed gas is used first as a heat source for a first reboiler (20A) located at the tower bottom, and the reformed gas having a lowered temperature is then used as a heat source for a second reboiler (20B) located in a middle position to heat the absorption liquid in stages, thereby regenerating the absorption liquid.
Abstract translation: 提供了一种用于回收二氧化碳的方法或系统，其在用于从烃气体合成甲醇或通过甲醇合成汽油的设备中，经常被丢弃并且难以再利用的低温重整气体的废热 ，可以有效利用。 在从烃气合成甲醇或汽油并回收二氧化碳的系统中，通过烃气体的蒸汽重整产生重整气体。 由于当燃料气体燃烧以产生用于蒸汽重整的热源时产生燃烧放电气体，所以使用吸收液体从吸收塔（40）中的燃烧放电气体回收二氧化碳。 在再生塔（10）中，首先将重整气体用作位于塔底的第一再沸器（20A）的热源，然后将具有降低温度的重整气体用作第二再沸器的热源 （20B）位于中间位置以分级地加热吸收液体，从而再生吸收液体。
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公开(公告)号：US09028785B2
公开(公告)日：2015-05-12
申请号：US13228999
申请日：2011-09-09
Applicant: Pavel Kortunov , Lisa S. Baugh , David C. Calabro , Michael Siskin
Inventor： Pavel Kortunov , Lisa S. Baugh , David C. Calabro , Michael Siskin
CPC classification number: B01D53/1493 , B01D53/1475 , B01D53/62 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20478 , B01D2252/2056 , B01D2252/30 , Y02A50/2342 , Y02C10/04 , Y02C10/06
Abstract: A CO2 amine scrubbing process uses an absorbent mixture combination of an amine containing a primary amino group CO2 sorbent in combination with a non-nucleophilic relatively stronger base. The weaker base(s) are nucleophilic and have the ability to react directly with the CO2 in the gas stream while the relatively stronger bases act as non-nucleophilic promoters for the reaction between the CO2 and the weaker base. Two moles of CO2 can be taken up by the primary amine groups in a dicarboxylation reaction, affording the potential for a highly efficient scrubbing process.
Abstract translation: CO 2胺洗涤方法使用含有伯氨基CO 2吸附剂的胺与非亲核相对较强的碱的组合的吸收混合物组合。 较弱的碱是亲核的，并且具有与气流中的CO 2直接反应的能力，而相对较强的碱作为CO 2和较弱碱之间的反应的非亲核促进剂。 在二羧酸化反应中，二元醇可以被伯胺基团吸收，提供高效洗涤过程的潜力。
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公开(公告)号：US20140183038A1
公开(公告)日：2014-07-03
申请号：US14184265
申请日：2014-02-19
Applicant: Liquid Light, Inc.
Inventor： Prasad Lakkaraju , Kyle Teamey
CPC classification number: C25B9/08 , B01D53/1475 , B01D53/965 , B01D2252/103 , B01D2252/20 , B01D2252/2021 , B01D2252/20415 , B01D2252/20463 , B01D2252/30 , C25B3/04 , Y02C10/06 , Y02P20/152
Abstract: Methods and systems for capture of carbon dioxide and electrochemical conversion of the captured carbon dioxide to organic products are disclosed. A method may include, but is not limited to, steps (A) to (C). Step (A) may introduce a solvent to a first compartment of an electrochemical cell. Step (B) may capture carbon dioxide with at least one of guanidine, a guanidine derivative, pyrimidine, or a pyrimidine derivative to form a carbamic zwitterion. Step (C) may apply an electrical potential between an anode and a cathode sufficient for the cathode to reduce the carbamic zwitterion to a product mixture.
Abstract translation: 公开了捕获二氧化碳的方法和系统以及所捕获的二氧化碳对有机产物的电化学转化。 方法可以包括但不限于步骤（A）至（C）。 步骤（A）可以将溶剂引入电化学电池的第一隔室。 步骤（B）可以用胍，胍衍生物，嘧啶或嘧啶衍生物中的至少一种捕获二氧化碳以形成氨基二硫代磷酸酯。 步骤（C）可以在阳极和阴极之间施加足以使阴极减少对产物混合物的氨基二
氧离子的电位。
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公开(公告)号：US08747694B2
公开(公告)日：2014-06-10
申请号：US12817276
申请日：2010-06-17
Applicant: Robert James Perry , Michael Joseph O'Brien
Inventor： Robert James Perry , Michael Joseph O'Brien
IPC: C09K3/00
CPC classification number: B01D53/62 , B01D47/00 , B01D53/1475 , B01D53/1493 , B01D2252/20415 , B01D2252/205 , B01D2258/0283 , C07F7/0838 , C10K1/16 , C10L3/104 , Y02C10/04 , Y02C10/06 , Y02P20/152
Abstract: In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.
Abstract translation: 根据一个方面，本发明提供含有如本文所述的氨基 - 硅氧烷结构I或III的组合物。 该组合物可用于从工艺流中捕获二氧化碳。 此外，本发明提供了制备氨基 - 硅氧烷组合物的方法。 本发明的另一方面提供了使用本发明的氨基 - 硅氧烷组合物作为与二氧化碳反应形成与二氧化碳的加合物的物质的方法中减少二氧化碳量的方法。
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公开(公告)号：US20130327983A1
公开(公告)日：2013-12-12
申请号：US13966404
申请日：2013-08-14
Applicant: NALCO COMPANY
Inventor： Alan M. Blair , Keith N. Garside , William J. Andrews , Kailas B. Sawant
IPC: B01D53/14
CPC classification number: B01D53/1456 , B01D53/1462 , B01D53/1493 , B01D2252/20415 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20447 , B01D2252/20473 , B01D2252/502 , B01D2256/24 , B01D2257/302 , B01D2257/304 , B01D2257/306 , B01D2257/308 , B01D2257/504 , B01D2258/0283 , B01D2258/05 , B01D2258/06 , C12M47/18 , Y02P20/59
Abstract: This invention provides novel compositions comprising substituted polyamines as acid gas scrubbing solutions and methods of using the compositions in an industrial system. The invention relates to the use of such polyamine compounds in industrial processes to remove acidic contaminants from natural and industrial fluid streams, such as natural gas, combustion gas, natural gas, synthesis gas, biogas, and other industrial fluid streams. The compositions and methods of the invention are useful for removal, absorption, or sequestration of acidic contaminants and sulfide contaminants including CO2, H2S, RSH, CS2, COS, and SO2.
Abstract translation: 本发明提供包含取代的多胺作为酸性气体洗涤溶液的新型组合物和在工业系统中使用该组合物的方法。 本发明涉及这种多胺化合物在工业过程中从天然气和工业流体流中除去酸性污染物的用途，例如天然气，燃烧气体，天然气，合成气，沼气和其它工业流体物流。 本发明的组合物和方法可用于除去，吸收或螯合酸性污染物和硫化物污染物，包括CO 2，H 2 S，RSH，CS 2，COS和SO 2。
