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81.发明授权Catalyst systems comprising a calcined chromium catalyst and a non-transition metal cyclopentadienyl cocatalyst 有权包含煅烧铬催化剂和非过渡金属环戊二烯基助催化剂的催化剂体系公开(公告)号：US06977235B2
公开(公告)日：2005-12-20
申请号：US10829550
申请日：2004-04-22
申请人： Max P. McDaniel , Elizabeth A. Benham , Steven J. Secora , Michael D. Jensen , Kathy S. Collins
发明人： Max P. McDaniel , Elizabeth A. Benham , Steven J. Secora , Michael D. Jensen , Kathy S. Collins
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F4/69 , C08F4/24 , C08F2500/12 , C08F2500/07 , C08F2500/13 , C08F2500/04
摘要： According to an embodiment, catalyst systems for polymerizing olefins include a catalyst comprising chromium and a cocatalyst comprising a substituted or unsubstituted non-transition metal cyclopentadienyl compound (Cp). The catalyst also comprises an inorganic oxide support. In an embodiment, methods of preparing a catalyst comprise contacting a support with chromium and with a non-transition metal Cp compound. In one embodiment, the support may be contacted with a solution comprising the non-transition metal Cp compound prior to entry into a reaction zone. In another embodiment, the activated catalyst and non-transition metal Cp compound may be added separately to the reaction zone.
摘要翻译： 根据一个实施方案，用于聚合烯烃的催化剂体系包括含有铬的催化剂和包含取代或未取代的非过渡金属环戊二烯基化合物（Cp）的助催化剂。 催化剂还包含无机氧化物载体。 在一个实施方案中，制备催化剂的方法包括使载体与铬和非过渡金属Cp化合物接触。 在一个实施方案中，载体可以在进入反应区之前与包含非过渡金属Cp化合物的溶液接触。 在另一个实施方案中，活化的催化剂和非过渡金属Cp化合物可以分开加入到反应区中。
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公开(公告)号：US06300271B1
公开(公告)日：2001-10-09
申请号：US09080619
申请日：1998-05-18
申请人： Max P. McDaniel , Elizabeth A. Benham , Shirley J. Martin , Kathy S. Collins , James L. Smith , Gil R. Hawley , Christopher E. Wittner , Michael D. Jensen
发明人： Max P. McDaniel , Elizabeth A. Benham , Shirley J. Martin , Kathy S. Collins , James L. Smith , Gil R. Hawley , Christopher E. Wittner , Michael D. Jensen
IPC分类号： B01J3100
CPC分类号： B01J31/143 , B01J21/04 , B01J21/08 , B01J21/12 , B01J27/053 , B01J27/125 , B01J31/1608 , B01J31/2295 , B01J31/38 , B01J35/10 , B01J37/0207 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F110/02 , C08F4/65916 , C08F2500/12 , C08F2500/03
摘要： This invention provides a compositions that are useful for polymerizing at least one monomer into at least one polymer.
摘要翻译： 本发明提供可用于将至少一种单体聚合成至少一种聚合物的组合物。
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公开(公告)号：US6107230A
公开(公告)日：2000-08-22
申请号：US80629
申请日：1998-05-18
申请人： Max P. McDaniel , Kathy S. Collins , Marvin M. Johnson , James L. Smith , Elizabeth A. Benham , Gil R. Hawley , Christopher E. Wittner , Michael D. Jensen
发明人： Max P. McDaniel , Kathy S. Collins , Marvin M. Johnson , James L. Smith , Elizabeth A. Benham , Gil R. Hawley , Christopher E. Wittner , Michael D. Jensen
IPC分类号： C08F4/02 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , B01J31/00
CPC分类号： C08F10/00 , C08F110/02 , C08F4/65912 , C08F4/65922
摘要： This invention provides compositions for polymerizing at least one monomer to produce a polymer. The compositions are produced by a process comprising contacting at least one organometal compound, at least one organoaluminum compound, and at least one treated solid oxide compound. The treated solid oxide compound is produced by a process comprising contacting at least one solid oxide compound with at least one electron-withdrawing anion source compound and at least one metal salt compound.
摘要翻译： 本发明提供用于聚合至少一种单体以制备聚合物的组合物。 通过包括使至少一种有机金属化合物，至少一种有机铝化合物和至少一种经处理的固体氧化物化合物接触的方法制备组合物。 经处理的固体氧化物化合物是通过使至少一种固体氧化物化合物与至少一种吸电子阴离子源化合物和至少一种金属盐化合物接触的方法制备的。
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公开(公告)号：US08318873B2
公开(公告)日：2012-11-27
申请号：US13020334
申请日：2011-02-03
CPC分类号： B01J31/2295 , B01J31/143 , B01J2531/0263 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12
摘要： Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
摘要翻译： 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。
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85.发明授权Polymerization catalysts and process for producing bimodal polymers in a single reactor 有权聚合催化剂和在单个反应器中生产双峰聚合物的方法公开(公告)号：US07521572B2
公开(公告)日：2009-04-21
申请号：US11705695
申请日：2007-02-12
CPC分类号： B01J31/2295 , B01J31/143 , B01J2531/0263 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12
摘要： Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
摘要翻译： 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。
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公开(公告)号：US07910763B2
公开(公告)日：2011-03-22
申请号：US12357007
申请日：2009-01-21
CPC分类号： B01J31/2295 , B01J31/143 , B01J2531/0263 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12
摘要： Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
摘要翻译： 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。
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公开(公告)号：US20110190460A1
公开(公告)日：2011-08-04
申请号：US13020334
申请日：2011-02-03
CPC分类号： B01J31/2295 , B01J31/143 , B01J2531/0263 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12
摘要： Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
摘要翻译： 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。
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公开(公告)号：US20090198078A1
公开(公告)日：2009-08-06
申请号：US12357007
申请日：2009-01-21
IPC分类号： C07F7/00
CPC分类号： B01J31/2295 , B01J31/143 , B01J2531/0263 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12
摘要： Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
摘要翻译： 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。
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89.发明授权Polymerization catalysts and process for producing bimodal polymers in a single reactor 有权聚合催化剂和在单个反应器中生产双峰聚合物的方法公开(公告)号：US07226886B2
公开(公告)日：2007-06-05
申请号：US11208077
申请日：2005-09-15
CPC分类号： B01J31/2295 , B01J31/143 , B01J2531/0263 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65904 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12
摘要： Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.
摘要翻译： 提供了包含第一茂金属化合物，第二茂金属化合物，活化剂 - 载体和有机铝化合物的催化剂组合物。 还提供了用于制备用于制备聚烯烃的环戊二烯基络合物的改进方法。
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公开(公告)号：US08673806B2
公开(公告)日：2014-03-18
申请号：US13143003
申请日：2010-01-07
IPC分类号： B01J21/00
CPC分类号： B01J35/023 , B01J21/04 , B01J21/12 , B01J23/26 , B01J35/002 , B01J35/008 , B01J35/1019 , B01J35/1047 , B01J35/1061 , B01J37/0221 , C08F10/00 , C08F4/025 , C08F4/24
摘要： The invention concerns catalysts comprising (i) a cladded catalyst support comprising (a) a core which comprises alumina particles and (b) about 1 to about 40 weight percent silica cladding, based on the weight of the cladded catalyst support, on the surface of the core; the catalyst support having a BET surface area of greater than 20 m2/g and a porosity of at least about 0.2 cc/g; and (ii) 0.1 to 10 weight percent, based on the weight of the catalyst, of catalytically active transition metal on the surface of the cladded catalyst support; wherein the catalyst support has a normalized sulfur uptake (NSU) of up to 25 ?g/m2. The invention also concerns the production and use of such catalysts.
摘要翻译： 本发明涉及催化剂，其包括（i）包覆的催化剂载体，其包含（a）包含氧化铝颗粒的芯和（b）基于包覆催化剂载体的重量的约1至约40重量％的二氧化硅包层， 核心; 所述催化剂载体具有大于20m 2 / g的BET表面积和至少约0.2cc / g的孔隙率; 和（ii）基于催化剂重量的0.1至10重量％的催化活性过渡金属在包覆的催化剂载体的表面上; 其中催化剂载体具有高达25g / m 2的归一化硫吸收（NSU）。 本发明还涉及这种催化剂的生产和使用。
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