公开(公告)号：US09847545B2

公开(公告)日：2017-12-19

申请号：US14639082

申请日：2015-03-04

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae Lim ,  Hee Lak Lee ,  Hyeong Cheol Shin ,  Choong Hwan Lee ,  Byung Sub Kim

IPC分类号： H01M8/12 ,  H01M8/1253 ,  H01M8/126 ,  H01M8/124

CPC分类号： H01M8/1253 ,  H01M8/126 ,  H01M2008/1293 ,  H01M2300/0077 ,  Y02E60/525 ,  Y02P70/56

摘要： Disclosed are a highly ionic conductive zirconia electrolyte and a high-efficiency solid oxide fuel cell using the same. The highly ionic conductive zirconia electrolyte is configured such that a scandia (Sc2O3) stabilized zirconia (ZrO2) electrolyte is simultaneously doped with cerium oxide (CeO2) and at least one oxide of gadolinium oxide (Gd2O3), samarium oxide (Sm2O3), and ytterbium oxide (Yb2O3) so that an ionic conductivity drop rate is mitigated.

公开(公告)号：US20170062855A1

公开(公告)日：2017-03-02

申请号：US15066246

申请日：2016-03-10

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae LIM ,  Hee Lak Lee ,  Hyeong Cheol Shin ,  Choong Hwan Lee ,  Byung Sub Kim ,  Jae Hwa Choi ,  Su Jeong Lee

IPC分类号： H01M8/126 ,  H01M4/90 ,  H01M8/1253

CPC分类号： H01M8/126 ,  H01M4/9033 ,  H01M8/1253 ,  H01M2008/1293 ,  H01M2300/0077 ,  Y02E60/525 ,  Y02P70/56

摘要： Disclosed is a ceria electrolyte for a solid oxide fuel cell, which is a ceria (CeO2) electrolyte configured such that either gadolinium (Gd) or samarium (Sm) is co-doped with ytterbium (Yb) and bismuth (Bi), wherein Bi is doped in an amount of 0.5 to 5 mol %, thus exhibiting low-temperature sintering properties.

摘要翻译： 公开了一种用于固体氧化物燃料电池的二氧化铈电解质，其是配置为使钆（Gd）或钐（Sm）与镱（Yb）和铋（Bi）共掺杂的二氧化铈（CeO 2）电解质，其中Bi 掺杂量为0.5〜5摩尔％，因此显示出低温烧结性能。

公开(公告)号：US10581102B2

公开(公告)日：2020-03-03

申请号：US15989835

申请日：2018-05-25

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae Lim ,  Hee Lak Lee ,  Hyeong Cheol Shin ,  Choong Hwan Lee ,  Byung Sub Kim ,  Jae Hwa Choi ,  Su Jeong Lee

IPC分类号： H01M8/126 ,  H01M8/1253 ,  H01M4/90 ,  H01M8/124

摘要： Disclosed is a ceria electrolyte for a solid oxide fuel cell, which is a ceria (CeO2) electrolyte configured such that either gadolinium (Gd) or samarium (Sm) is co-doped with ytterbium (Yb) and bismuth (Bi), wherein Bi is doped in an amount of 0.5 to 5 mol %, thus exhibiting low-temperature sintering properties.

公开(公告)号：US10008731B2

公开(公告)日：2018-06-26

申请号：US15066246

申请日：2016-03-10

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae Lim ,  Hee Lak Lee ,  Hyeong Cheol Shin ,  Choong Hwan Lee ,  Byung Sub Kim ,  Jae Hwa Choi ,  Su Jeong Lee

IPC分类号： H01M8/12 ,  H01M4/90 ,  H01M8/126 ,  H01M8/1253 ,  H01M8/124

CPC分类号： H01M8/126 ,  H01M4/9033 ,  H01M8/1253 ,  H01M2008/1293 ,  H01M2300/0077 ,  Y02E60/525 ,  Y02P70/56

摘要： Disclosed is a ceria electrolyte for a solid oxide fuel cell, which is a ceria (CeO2) electrolyte configured such that either gadolinium (Gd) or samarium (Sm) is co-doped with ytterbium (Yb) and bismuth (Bi), wherein Bi is doped in an amount of 0.5 to 5 mol %, thus exhibiting low-temperature sintering properties.

公开(公告)号：US20170373337A1

公开(公告)日：2017-12-28

申请号：US15222454

申请日：2016-07-28

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae LIM ,  Hee Lak LEE ,  Hyeong Cheol SHIN

IPC分类号： H01M8/1253 ,  H01M8/124

CPC分类号： H01M8/1253 ,  C04B35/486 ,  C04B2235/3224 ,  C04B2235/3229 ,  C04B2235/6567 ,  C04B2235/762 ,  H01M2008/1293 ,  H01M2300/0077 ,  Y02E60/525 ,  Y02P70/56

摘要： Disclosed is a scandia-stabilized zirconia electrolyte for a solid oxide fuel cell, which is configured such that at least one oxide selected from among gadolinium oxide (Gd2O3) and samarium oxide (Sm2O3) is co-doped with ytterbium oxide (Yb2O3) to thus improve stability in a reducing atmosphere. The scandia-stabilized zirconia electrolyte of the invention can be stabilized into a cubic crystal structure at room temperature while retaining the inherently high oxygen ionic conductivity of a scandia-stabilized zirconia electrolyte (11ScSZ), and can also ensure stability in a reducing atmosphere by solving the problem with a conventional ceria (CeO2)-doped scandia-stabilized zirconia in which the ionic conductivity continuously deteriorates in a reducing atmosphere.

公开(公告)号：US10218024B2

公开(公告)日：2019-02-26

申请号：US15222454

申请日：2016-07-28

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae Lim ,  Hee Lak Lee ,  Hyeong Cheol Shin

IPC分类号： H01M8/12 ,  C04B35/48 ,  H01M8/1253 ,  C04B35/486 ,  H01M8/124

摘要： Disclosed is a scandia-stabilized zirconia electrolyte for a solid oxide fuel cell, which is configured such that at least one oxide selected from among gadolinium oxide (Gd2O3) and samarium oxide (Sm2O3) is co-doped with ytterbium oxide (Yb2O3) to thus improve stability in a reducing atmosphere. The scandia-stabilized zirconia electrolyte of the invention can be stabilized into a cubic crystal structure at room temperature while retaining the inherently high oxygen ionic conductivity of a scandia-stabilized zirconia electrolyte (11ScSZ), and can also ensure stability in a reducing atmosphere by solving the problem with a conventional ceria (CeO2)-doped scandia-stabilized zirconia in which the ionic conductivity continuously deteriorates in a reducing atmosphere.

公开(公告)号：US20180309148A1

公开(公告)日：2018-10-25

申请号：US15989835

申请日：2018-05-25

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae Lim ,  Hee Lak Lee ,  Hyeong Cheol Shin ,  Choong Hwan Lee ,  Byung Sub Kim ,  Jae Hwa Choi ,  Su Jeong Lee

IPC分类号： H01M8/126 ,  H01M4/90 ,  H01M8/1253

CPC分类号： H01M8/126 ,  H01M4/9033 ,  H01M8/1253 ,  H01M2008/1293 ,  H01M2300/0077 ,  Y02E60/525 ,  Y02P70/56

摘要： Disclosed is a ceria electrolyte for a solid oxide fuel cell, which is a ceria (CeO2) electrolyte configured such that either gadolinium (Gd) or samarium (Sm) is co-doped with ytterbium (Yb) and bismuth (Bi), wherein Bi is doped in an amount of 0.5 to 5 mol %, thus exhibiting low-temperature sintering properties.

公开(公告)号：US20150255821A1

公开(公告)日：2015-09-10

申请号：US14639082

申请日：2015-03-04

申请人： KCERACELL CO., LTD.

发明人： Kyoung Tae LIM ,  Hee Lak LEE ,  Hyeong Cheol SHIN ,  Choong Hwan LEE ,  Byung Sub KIM

IPC分类号： H01M8/12

CPC分类号： H01M8/1253 ,  H01M8/126 ,  H01M2008/1293 ,  H01M2300/0077 ,  Y02E60/525 ,  Y02P70/56

摘要： Disclosed are a highly ionic conductive zirconia electrolyte and a high-efficiency solid oxide fuel cell using the same. The highly ionic conductive zirconia electrolyte is configured such that a scandia (Sc2O3) stabilized zirconia (ZrO2) electrolyte is simultaneously doped with cerium oxide (CeO2) and at least one oxide of gadolinium oxide (Gd2O3), samarium oxide (Sm2O3), and ytterbium oxide (Sm2O3) so that an ionic conductivity drop rate is mitigated.

摘要翻译： 公开了高离子导电氧化锆电解质和使用其的高效固体氧化物燃料电池。 高离子导电氧化锆电解质被配置为使得Scandia（Sc 2 O 3）稳定化的氧化锆（ZrO 2）电解质同时掺杂有氧化铈（CeO 2）和至少一种氧化钆（Gd 2 O 3），氧化钐（Sm 2 O 3）和镱 氧化物（Sm2O3），从而减轻离子电导率降低速率。