Additive components for liquid crystalline materials
    7.
    发明授权
    Additive components for liquid crystalline materials 有权
    用于液晶材料的添加剂组分

    公开(公告)号:US08105662B2

    公开(公告)日:2012-01-31

    申请号:US10581716

    申请日:2004-11-25

    摘要: The present invention relates to mesogenic, cross-linkable mixtures comprising (i) a cross-linkable liquid crystalline host compound comprising at least one cross-linkable liquid crystalline compound, and (ii) at least one chiral or achiral rod shaped additive component, wherein said additive component has a rigid core and comprises at least two fused or linked, optionally substituted, non-aromatic, aromatic, carbocyclic or heterocyclic groups, and also comprises at least one optionally substituted alkyl residue, and at least one polymerizable group and wherein the additive component has a transition temperature to the isotropic state of 40° C. or lower. The invention also relates to the novel chiral or achiral rod-shaped additive compounds used for the preparation of these mixtures, to mixtures according to the invention in form of an elastomer, polymer gel, polymer network or polymer film, to polymer networks and liquid crystalline polymer films prepared from these mixtures and to optical or electrooptical components comprising polymer networks and liquid crystalline polymer films prepared from such mixtures. Further, the invention relates to the use of the chiral or achiral rod shaped compounds as components of a cross-linkable liquid crystalline mixture in the production of orientated liquid crystalline polymers, to liquid crystalline mixtures comprising these compounds, to liquid crystalline polymers and liquid crystalline polymer networks prepared from such liquid crystalline mixtures, and to liquid crystalline devices comprising these compounds.

    摘要翻译: 本发明涉及介晶的可交联的混合物,其包含(i)包含至少一个可交联的液晶化合物的可交联的液晶宿主化合物和(ii)至少一种手性或非手性的棒状添加剂组分,其中 所述添加剂组分具有刚性核并且包含至少两个稠合或连接的,任选取代的非芳族,芳族,碳环或杂环基团,并且还包含至少一个任选取代的烷基残基和至少一个可聚合基团,并且其中 添加剂成分的转变温度为各向同性状态为40℃以下。 本发明还涉及用于制备这些混合物的新颖的手性或非手性棒状添加剂化合物,本发明的混合物以弹性体,聚合物凝胶,聚合物网络或聚合物膜的形式,与聚合物网络和液晶 由这些混合物制备的聚合物膜和包含由这些混合物制备的聚合物网络和液晶聚合物膜的光学或电光组分。 此外,本发明涉及手性或非手性棒状化合物在制备定向液晶聚合物中的可交联液晶混合物的组分,包含这些化合物的液晶混合物,液晶聚合物和液晶 由这种液晶混合物制备的聚合物网络,以及包含这些化合物的液晶装置。

    PATTERNABLE LIQUID CRYSTAL POLYMER COMPRISING THIO-ETHER UNITS
    10.
    发明申请
    PATTERNABLE LIQUID CRYSTAL POLYMER COMPRISING THIO-ETHER UNITS 有权
    包含THIO-ETHER单位的方形液晶聚合物

    公开(公告)号:US20100059709A1

    公开(公告)日:2010-03-11

    申请号:US12515918

    申请日:2007-12-11

    IPC分类号: C08G75/02 C09K19/38

    摘要: The present invention relates to a photo-polymerized, patterned or unpatterned liquid crystal polymer, especially a liquid crystal polymer film or a liquid crystal polymer network, comprising thio-ether units of formula (I) * covalent bond, which links the unit of formula (I) to the residue of the polymer wherein LC1 is selected from the group of liquid crystal residues, X1 is selected from the group of aliphatic organic residues, and n1 is an integer ≧0 and m1 is an integer ≧0; with the proviso that if n1 is 0, then m1 is >0, and if m1 is 0, then n1>0; which is prepared in an atmosphere containing oxygen, preferably with an amount of 0.1≦oxygen 50%, more preferably 1≦oxygen≦25%, most preferably in air; with the proviso that polymer dispersed liquid crystals are excluded. Further, this invention relates to a composition used for the preparation of that photo-polymerized liquid crystal polymer of the invention, to processes of the preparation of that liquid crystal polymer and to its use.

    摘要翻译: 本发明涉及光聚合,图案化或未图案化的液晶聚合物,特别是液晶聚合物膜或液晶聚合物网络,其包含式(I)*共价键的硫醚单元,其将式 (I)所示的聚合物残基,其中LC1选自液晶残基,X1选自脂族有机残基,n1为整数≥0,m1为整数≥0; 条件是如果n1为0,则m1> 0,如果m1为0,则n1> 0; 其在含有氧气的气氛中制备,优选为0.1< NlE;氧气50%,更优选1& NlE;氧气& 25%,最优选在空气中; 条件是排除聚合物分散的液晶。 此外,本发明涉及用于制备本发明的光聚合液晶聚合物的组合物,该液晶聚合物的制备方法及其用途。