Process for producing anode material for solid oxide fuel cell
    1.
    发明授权
    Process for producing anode material for solid oxide fuel cell 有权
    固体氧化物燃料电池用阳极材料的制造方法

    公开(公告)号:US09570754B2

    公开(公告)日:2017-02-14

    申请号:US14607734

    申请日:2015-01-28

    摘要: To provide an NiO-GDC composite powder or NiO-SDC composite powder having a uniform composition, which is suitable as an anode material for a solid oxide fuel cell.A process for producing an anode material for a solid oxide fuel cell, made of a composite powder comprising a composite oxide containing cerium element and gadolinium or samarium element, and oxygen element, and an oxide containing nickel element and oxygen element, which comprises a dissolving step of mixing raw material compounds containing metal elements constituting the above composite powder, at least one organic acid selected from the group consisting of maleic acid, lactic acid and malic acid, and a solvent to obtain a metal elements-containing solution, and a drying/sintering step of drying and sintering the metal elements-containing solution.

    摘要翻译: 一种固体氧化物型燃料电池用负极材料的制造方法,其特征在于,包含含有铈元素,钆或钐元素的复合氧化物,氧元素和含有镍元素和氧元素的氧化物的复合粉末, 混合含有构成上述复合粉末的金属元素的原料化合物,至少一种选自马来酸,乳酸和苹果酸的有机酸和溶剂以获得含金属元素的溶液的步骤,以及干燥 干燥和烧结含金属元素溶液的烧结步骤。

    Fluorine-containing compound, fluorine-containing surfactant and compositions containing same
    3.
    发明授权
    Fluorine-containing compound, fluorine-containing surfactant and compositions containing same 有权
    含氟化合物,含氟表面活性剂和含有它们的组合物

    公开(公告)号:US08563769B2

    公开(公告)日:2013-10-22

    申请号:US13388195

    申请日:2010-07-26

    摘要: A fluorine-containing compound exhibiting excellent surface tension-reducing ability despite the absence of perfluoroalkyl group having a chain length of 8 or more which had been the cause of the PFOS and PFOA problems and use of a fluorine material with low environmental load is provided. Also provided are a fluorine-containing surfactant and a composition thereof, an aqueous resin emulsion and a floor polish composition containing such surfactant. The fluorine-containing compound is represented by the following formula (1): Rf1—CpH2p—CH(OH)—CqH2q—NR—CrH2r—(O)n—SO3M (1) wherein Rf1 is a C1-6 perfluoroalkyl group, p, q, and r are independently an integer of 1 to 6, M is a cationic atom or atomic group, n is 0 or 1, R is hydrogen atom, a C1-12 alkyl group, or a group represented by the following formula (2): Rf2—CsH2s—CH(OH)—CtH2t—  (2) wherein Rf2 is a C1-6 perfluoroalkyl group, and s and t are independently an integer of 1 to 6.

    摘要翻译: 提供了尽管不具有全氟烷基的链长为8或更大的全氟烷基,其具有优异的表面张力降低能力的含氟化合物,这是PFOS和PFOA问题的原因,以及使用环境负荷低的氟材料。 还提供了含氟表面活性剂及其组合物,水性树脂乳液和含有这种表面活性剂的地板油漆组合物。 含氟化合物由下式(1)表示:Rf1-CpH2p-CH(OH)-CqH2q-NR-CrH2r-(O)n-SO3M(1)其中Rf1为C1-6全氟烷基,p ,q和r分别为1〜6的整数,M为阳离子性原子或原子团,n为0或1,R为氢原子,碳原子数为1〜12的烷基或下述式 2):Rf2-CsH2s-CH(OH)-CtH2t-(2)其中Rf2为C1-6全氟烷基,s和t独立地为1〜6的整数。

    FLUOROALKYL GROUP-CONTAINING N-SUBSTITUTED (METH)ACRYLAMIDE COMPOUND, POLYMER THEREOF , AND USE THEREOF
    4.
    发明申请
    FLUOROALKYL GROUP-CONTAINING N-SUBSTITUTED (METH)ACRYLAMIDE COMPOUND, POLYMER THEREOF , AND USE THEREOF 有权
    含有氟取代基的N-取代(甲基)丙烯酰胺化合物,其聚合物及其用途

    公开(公告)号:US20120149860A1

    公开(公告)日:2012-06-14

    申请号:US13391120

    申请日:2010-08-17

    摘要: A compound represented by the following formula (a): CH2═CR1—CONJ-CKR2—(CH2)n—COO-Q1-Rf1  (a) is provided. This compound is capable of forming a polymer having an oil repellency equivalent to polymers containing a polyfluoroalkyl group containing at least 8 carbon atoms, although the polyfluoroalkyl group contains up to 6 carbon atoms. In the formula, R1 is hydrogen atom or methyl group, R2 is hydrogen atom or a group represented by —(CH2)m—COO-Q2-Rf2 (r), n and m are independently an integer of 0 to 4, Rf1 and Rf2 are independently a polyfluoroalkyl group or a polyfluoroether group containing 1 to 6 carbon atoms, Q1 and Q2 are independently single bond or a divalent linkage group, J is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms, K is hydrogen atom or an alkyl group containing 1 to 3 carbon atoms, and j and k are independently single bond or an alkylene group containing 1 to 3 carbon atoms with the proviso that j and k are not simultaneously single bond.

    摘要翻译: 提供由下式(a)表示的化合物:CH2 = CR1-CONJ-CKR2-(CH2)n-COO-Q1-Rf1(a)。 尽管多氟烷基含有最多6个碳原子,但是该化合物能够形成斥油性等同于含有至少8个碳原子的多氟烷基的聚合物的聚合物。 式中,R 1为氢原子或甲基,R 2为氢原子或 - (CH 2)m -COO-Q 2 -R f 2(r)表示的基团,n和m分别为0〜4的整数,Rf 1及 Rf2独立地为含有1〜6个碳原子的多氟烷基或多氟醚基,Q1和Q2独立地为单键或二价连接基团,J为氢原子或含有1〜3个碳原子的烷基,K为氢原子或 含有1〜3个碳原子的烷基,j和k独立地为单键或含有1〜3个碳原子的亚烷基,条件是j和k不同时为单键。

    PROCESS FOR PRODUCTION OF CATHODE ACTIVE MATERIAL FOR LITHIUN ION SECONDARY BATTERY
    6.
    发明申请
    PROCESS FOR PRODUCTION OF CATHODE ACTIVE MATERIAL FOR LITHIUN ION SECONDARY BATTERY 有权
    用于生产用于锂离子二次电池的阴极活性材料的方法

    公开(公告)号:US20110033749A1

    公开(公告)日:2011-02-10

    申请号:US12606224

    申请日:2009-10-27

    摘要: To provide a process for producing a surface modified lithium-containing composite oxide, which is excellent in discharge capacity, volume capacity density, safety, durability for charge and discharge cycles and an excellent rate property, at a low production cost. The present invention is characterized in that a process for producing a surface modified lithium-containing composite oxide, wherein a lithium titanium composite oxide is contained in the surface layer of particles of a lithium-containing composite oxide represented by the formula: LipNxMyOzFa, where N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, Sn, alkaline earth metal elements and transition metal elements other than Co, Mn and Ni, 0.9≦p≦1.3, 0.9≦x≦2.0, 0≦y≦0.1, 1.9≦z≦4.2, and 0≦a≦0.05, which comprises impregnating a solution having a lithium source and a titanium source dissolved therein, followed by heat treatment at a determined temperature, to obtain the surface modified lithium-containing composite oxide, wherein the titanium contained in the surface layer is from 0.01 to 1.95 mol %.

    摘要翻译: 为了提供一种生产成本低的放电容量,容量容量密度,安全性,充放电循环的耐久性和优异的速率特性的表面改性的含锂复合氧化物的方法。 本发明的特征在于一种表面改性的含锂复合氧化物的制造方法,其中,在下式表示的锂复合氧化物的表面层中含有锂钛复合氧化物,式中,N表示下式:LipNxMyOzFa,其中N 是选自Co,Mn和Ni中的至少一种元素,M是选自Al,Sn,碱土金属元素和Co,Mn和Ni以外的过渡金属元素中的至少一种元素,0.9 其中包括浸渍溶解有锂源和钛源的溶液,其中包括溶解在其中的锂源和溶解有钛源的溶液,随后 通过在确定的温度下进行热处理,得到表面改性的含锂复合氧化物,其中表面层中所含的钛为0.01〜1.95摩尔%。

    POSITIVE ELECTRODE ACTIVE SUBSTANCE FOR LITHIUM SECONDARY BATTERY AND PROCESS FOR PRODUCING THE SAME
    7.
    发明申请
    POSITIVE ELECTRODE ACTIVE SUBSTANCE FOR LITHIUM SECONDARY BATTERY AND PROCESS FOR PRODUCING THE SAME 失效
    用于锂二次电池的正极电极活性物质及其制造方法

    公开(公告)号:US20100294985A1

    公开(公告)日:2010-11-25

    申请号:US12849435

    申请日:2010-08-03

    IPC分类号: H01M4/525

    摘要: A positive electrode active material for a lithium secondary battery containing a lithium-cobalt composite oxide, which has a large volume capacity density, has a high safety and is excellent in charge and discharge cyclic durability, and its production process, are provided.A lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co or an alkaline earth metal element, 0.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1 and 0≦a≦0.02) and comprising a mixture containing substantially spherical hard first particles of lithium-cobalt composite oxide having such a sharp particle size distribution that the volume basis cumulative size D10 is at least 50% of the average particle size D50, and the volume basis cumulative size D90 is at most 150% of the average particle size D50, and second particles of lithium-cobalt composite oxide filling the space among the first particles, in a mass ratio of first particles/second particles of from 1/2 to 9/1, and process for producing the same.

    摘要翻译: 提供了具有大体积容量密度的含有锂钴复合氧化物的锂二次电池用正极活性物质,其安全性高,充放电循环耐久性优异,其制造方法。 由式LipCoxMyOzFa表示的锂钴复合氧化物(其中M是除Co以外的过渡金属元素或碱土金属元素,0.9≦̸ p≦̸ 1.1,0.980≦̸ x≦̸ 1.000,0和nlE; y≦̸ 0.02,1.9 并且包括含有基本上球形的硬质的第一第一颗粒的锂 - 钴复合氧化物的混合物,所述锂 - 钴复合氧化物具有这样的尖锐的粒度分布,其体积基础累积尺寸D10处于(例如,n + 1) 平均粒径D50的至少50%,体积基础累积尺寸D90为平均粒径D50的150%以下,以及以第一粒子的质量比填充第一粒子之间的空间的第二粒子的锂钴复合氧化物 的1/2至9/1的第一颗粒/第二颗粒及其制备方法。

    NOVEL AMINO GROUP-CONTAINING HETEROCYCLIC DERIVATIVES AND SENSITIZING DYES FOR PHOTOELECTRIC CONVERSION CONTAINING THE HETEROCYCLIC DERIVATIVES
    10.
    发明申请
    NOVEL AMINO GROUP-CONTAINING HETEROCYCLIC DERIVATIVES AND SENSITIZING DYES FOR PHOTOELECTRIC CONVERSION CONTAINING THE HETEROCYCLIC DERIVATIVES 有权
    含有杂环衍生物的光电转化剂的新型含氨基的杂环衍生物和敏化剂

    公开(公告)号:US20090025781A1

    公开(公告)日:2009-01-29

    申请号:US11914344

    申请日:2006-04-28

    摘要: It is intended to provide novel amino group-containing heterocyclic derivatives, which have a broad absorption zone in the visible region and are suitable for sensitizing dyes for photoelectric conversion having a high photoelectric conversion efficiency, and photoelectric conversion materials, photoelectric conversion electrodes and photoelectric conversion cells using the same. Namely, a heterocyclic derivative represented by the following general formula (I) and containing an amino group at the terminus: wherein R1, R2, R4 and R5 independently represent each a hydrogen atom or a monovalent organic group optionally having one or more substituent; R3 represents an anchor group capable of binding to an inorganic porous material showing semiconductor characteristics; X represents a divalent aromatic hydrocarbon group or a combination of two or more aromatic hydrocarbons being divalent or higher; Y represents a divalent aromatic heterocyclic group having a sulfur atom; Z represents a divalent aromatic heterocyclic group, a divalent aromatic hydrocarbon group, a divalent unsaturated hydrocarbon group or a combination thereof; and m is an integer of from 1 to 3.

    摘要翻译: 旨在提供新颖的含氨基的杂环衍生物,其在可见光区域具有宽的吸收区,适用于具有高光电转换效率的光敏转化用染料,以及光电转换材料,光电转换电极和光电转换 细胞使用相同。 即,由以下通式(I)表示并在末端含有氨基的杂环衍生物:其中R 1,R 2,R 4和R 5各自独立地表示氢原子或任选具有一个或多个取代基的一价有机基团; R3表示能够结合显示半导体特性的无机多孔材料的锚定基团; X表示二价芳族烃基或两种以上芳族烃的组合,为二价以上; Y表示具有硫原子的二价芳族杂环基; Z表示二价芳族杂环基,二价芳族烃基,二价不饱和烃基或其组合; m为1〜3的整数。