摘要:
The invention provides a propylene polymer composition well balanced and excellent in transparency, flexibility, heat resistance, scratch resistance and rubber elasticity, and a medical tube made from the propylene polymer composition. The propylene polymer composition satisfies all the following properties (A), (B), (C) and (D): (A) the composition shows a loss tangent (tan δ) peak at a temperature in the range of −20 to 25° C. according to dynamic viscoelasticity measurement (10 rad/s) in a torsion mode, and the peak is 0.5 or above; (B) the storage elastic modulus G′ at 20° C. from the dynamic viscoelasticity measurement is in the range of 1.0×107 to 4.9×108 dyn/cm2; (C) the penetration temperature (° C.) determined in accordance with JIS K 7196 is in the range of 60 to 160° C.; and (D) the composition has a permanent set of not more than 30% as determined after the composition fixed between chucks 30 mm apart is 100% strained at a stress rate of 30 mm/min, maintained for 10 minutes and released for 10 minutes. The medical tube is made from the propylene polymer composition.
摘要:
The present invention provides a propylene polymer composition having excellent transparency, flexibility, heat resistance, scratch resistance and rubber elasticity with a good balance. The propylene polymer composition comprises 1 to 40 parts by weight of isotactic polypropylene (i) and 60 to 99 parts by weight of a propylene/ethylene/α-olefin copolymer (ii) which contains 45 to 89% by mol of a propylene component, 10 to 25% by mol of an ethylene component, and optionally, 0 to 30% by mol of constituent units (a) derived from an α-olefin of 4 to 20 carbon atoms.
摘要:
Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyolefin resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronicmicroscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyolefin resin (a) forms a disperse phase. The thermoplastic resin structure gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.
摘要:
An ethylene/.alpha.-olefin copolymer obtained by copolymerizing ethylene with an .alpha.-olefin of 3 to 20 carbon atoms in the presence of a catalyst for olefin polymerization comprising an organoaluminum oxy-compound (a) and at least two kinds of transition metal compounds (b). This ethylene/.alpha.-olefin copolymer has high melt tension and high flowability. A graft modified ethylene/.alpha.-olefin copolymer obtained by graft polymerizing the above-mentioned ethylene/.alpha.-olefin copolymer with a polar monomer. An ethylene copolymer composition comprising the above-mentioned graft modified ethylene/.alpha.-olefin copolymer and polyolefin. The ethylene/.alpha.-olefin copolymer of the invention is excellent in moldability. From this copolymer, a film having high transparency and high mechanical strength can be produced. The graft modified ethylene/.alpha.-olefin copolymer of the invention is excellent in heat stability and moldability. From this copolymer, a film having high transparency and good adhesion to highly polar materials can be produced. The ethylene copolymer composition of the invention is excellent in heat stability and moldability. From this composition, a film having high transparency and good adhesion to highly polar materials can be produced.
摘要:
A graft-modified ethylene/.alpha.-olefin copolymer composition is prepared by graft copolymerizing an ethylene/.alpha.-olefin copolymer. The ethylene/.alpha.-olefin copolymer composition includes first and second ethylene/.alpha.-olefin copolymers. The copolymers are each prepared in the presence of a polymerization catalyst containing (a) an organoaluminum oxy compound and (b) for the first ethylene/.alpha.-olefin copolymer at least two kinds, and for the second ethylene/.alpha.-olefin copolymer one kind, of compounds of Group IV transition metals of the periodic table containing a ligand having a cyclopentadienyl skeleton. The ethylene/.alpha.-olefin copolymer composition may be blended with a polyolefin by mechanical or solution blending. The copolymer compositions have excellent moldability and heat stability properties and forms films having high transparency and mechanical strength.
摘要:
An ethylene/.alpha.-olefin copolymer composition containing a first and second ethylene/.alpha.-olefin copolymer is disclosed. The first ethylene/.alpha.-olefin copolymer is prepared in the prsence of a polymerization catalyst containing an organoaluminum oxy compound and at least two kinds of metallocene compounds (b) and the second ethylene/.alpha.-olefin copolymer, which differs from the first in at least one physical property, is prepared in the presence of a polymerization catalyst containing an organoaluminum oxy compound and a metallocene compound (b'). The ethylene/.alpha.-olefin copolymer composition has excellent moldability and heat stability properties and forms films having high transparency and mechanical strength.
摘要:
An information recording medium formed by adhering, with an adhesive composition, two disk substrates to each other, at least one of the two disk substrates having a recording layer on at least one surface of a transparent resin substrate thereof and the adhesive composition comprising(1) the following components:(A) an .alpha.-olefin polymer,(B) an ethylene/(meth)acrylate copolymer,(C) a styrene-type polymer, and(D) a tackifier provided that at least one of the components (A) to (D) is modified with an unsaturated carboxylic acid or a derivative thereof, or(2) the following components:(A) an .alpha.-olefin polymer,(C) a styrene-type polymer,(D) a tackifier, and(E) fine filler particles.
摘要:
Optical recording media disclosed herein comprise a substrate and a recording layer formed thereon, wherein the recording layer is irradiated with beam of energy to form thereon bits corresponding to given pieces of information and thereby record the pieces of information. The recording layer comprises Te and Cr, the proportion of Cr contained in said recording layer being 0.1-10 atom % based on the total atoms constituting the recording layer. Processes for preparing the optical recording media disclosed above comprise forming the recording layer comprising Te and Cr on the substrate and then subjecting the thus formed recording layer to heat treatment. Oxidation resistance of said recording layer is improved and accordingly the optical recording medium comprising this recording layer can be expected to prolong its duration of life. This recording layer has excellent recording sensitivity, because the content of Cr in said recording layer is present to 0.1-10 atom %, which is lower than the Cr content in conventional recording layers. According to the process for preparing the optical recording media disclosed above, the resulting optical recording medium further improves in recording sensitivity, notwithstanding that the optical recording medium obtained is improved in durability. Moreover, it becomes possible to enlarge the recording margin.
摘要:
Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyolefin resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronicmicroscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyolefin resin (a) forms a disperse phase. The thermoplastic resin structure gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.
摘要:
Provided is a thermoplastic resin structure formed of a resin composition that comprises substantially (a) from 5 to 80% by volume of a polyolefin resin and (b) from 20 to 95% by volume of a polyphenylene sulfide resin, which is characterized in that, in morphology therein seen through electronicmicroscopy, the polyphenylene sulfide resin (b) forms a matrix phase (continuous phase) and the polyolefin resin (a) forms a disperse phase. The thermoplastic resin structure gives plastic containers, tubes and their Attached parts having good barrier properties, strength, durability and workability.