Process For Producing Unsaturated Aldehyde And/or Unsaturated Carboxylic Acid
    1.
    发明申请
    Process For Producing Unsaturated Aldehyde And/or Unsaturated Carboxylic Acid 有权
    生产不饱和醛和/或不饱和羧酸的方法

    公开(公告)号:US20130310604A1

    公开(公告)日:2013-11-21

    申请号:US13982808

    申请日:2012-01-16

    Abstract: There is provided a process for producing aerolein, acrylic acid, methacrolein, methacrylic acid in a safe and steady manner and in high yields, which avoids a phenomenon of occurrence of an abnormal reaction attributable to the fact that the temperature at a raw material gas outlet side becomes considerably higher than the temperature at a raw material gas inlet side, with regard to the temperature of a catalyst packed in a reaction tube at vapor-phase catalytic oxidation of propylene, isobutylene, or the like.In the process of using a reaction tube on which a plurality of catalyst layers formed in a raw material gas flow direction, a catalyst and a catalyst packing schedule are designed so that a relation between the raw material conversion rate at which the yield of the objective product becomes maximum and the raw material conversion rate at which a high and low correlation between maximum temperature of the catalyst layer present closest to a reaction gas inlet side Zin and maximum temperature of the catalyst layer present closest to a reaction gas outlet side Zout is reversed satisfies a specific condition of 0.5≦Cmax−Ccrs≦5, in which Cmax: a raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: a raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate is changed, a high and low correlation between Tin and Tout is reversed.

    Abstract translation: 提供了以安全稳定的方式和高产率生产气溶胶,丙烯酸,甲基丙烯醛,甲基丙烯酸的方法,避免了由于原料气体出口处的温度导致的异常反应的发生现象 相对于在丙烯,异丁烯等的气相催化氧化反应管中填充的催化剂的温度,原料气体入口侧的温度显着高于原料气体入口侧的温度。 在使用在原料气体流动方向上形成有多个催化剂层的反应管的过程中,设计催化剂和催化剂填充进度,使得目的物的产率的原料转化率之间的关系 产物变得最大,并且最接近反应气体入口侧的催化剂层的最高温度和最接近反应气体出口侧的催化剂层的最高温度之间的高低相关性的原料转化率反转 满足0.5 @ Cmax-Ccrs @ 5的特定条件,其中Cmax:目标产物的产率变为最大的原料转化率; Ccrs:将催化剂层Zin的最高温度设为Tin时的原料转化率,将催化剂层Zout的最高温度设为Tout,将原料转化率变更为高,低相关 Tin和Tout之间是相反的。

    PROCESS FOR PRODUCING AMINO ACID N-CARBOXYANHYDRIDE
    7.
    发明申请
    PROCESS FOR PRODUCING AMINO ACID N-CARBOXYANHYDRIDE 有权
    制备氨基酸N-羧酸的方法

    公开(公告)号:US20070015932A1

    公开(公告)日:2007-01-18

    申请号:US11457035

    申请日:2006-07-12

    CPC classification number: C07C269/04 C07C271/44 C07C271/54

    Abstract: The present invention provides a process for producing an amino acid N-carboxyanhydride, which comprises reacting an amino acid or a derivative thereof with a compound represented by the following formula (1): wherein R1 and R2 represent the same or different electron-withdrawing substituents and each independently are an optionally substituted acyl group, an optionally substituted alkyloxycarbonyl group, an optionally substituted perfluoroalkyl group, an optionally substituted perchloroalkyl group, a cyano group, a halogen atom, or a nitro group; and a and b are the same or different and each are an integer of 1-5.

    Abstract translation: 本发明提供一种氨基酸N-羧酸酐的制备方法,其包括使氨基酸或其衍生物与下式(1)表示的化合物反应:其中R 1和R 2, SUP> 2表示相同或不同的吸电子取代基,并且各自独立地为任选取代的酰基,任选取代的烷氧基羰基,任选取代的全氟烷基,任选取代的全氯烷基,氰基,卤素 原子或硝基; a和b相同或不同,为1-5的整数。

    Aqueous ink composition
    8.
    发明授权
    Aqueous ink composition 有权
    水性油墨组合物

    公开(公告)号:US06666913B2

    公开(公告)日:2003-12-23

    申请号:US09948177

    申请日:2001-09-05

    CPC classification number: C09D11/037

    Abstract: The main object is to provide a water-based ink composition which is not only superior in hiding power but also has satisfactory writing properties. This invention relates to a water-based ink composition comprising a powder consisting of inorganic particles comprising at least one of aluminum oxide, titanium dioxide and boron nitride and water.

    Abstract translation: 主要目的在于提供一种水硬性油墨组合物,其不仅具有优异的遮盖力,而且具有良好的书写性能。 本发明涉及包含由包含氧化铝,二氧化钛和氮化硼和水中的至少一种的无机颗粒组成的粉末的水性油墨组合物。

    Process for producing unsaturated aldehyde and/or unsaturated carboxylic acid
    9.
    发明授权
    Process for producing unsaturated aldehyde and/or unsaturated carboxylic acid 有权
    不饱和醛和/或不饱和羧酸的制备方法

    公开(公告)号:US08969618B2

    公开(公告)日:2015-03-03

    申请号:US13982808

    申请日:2012-01-16

    Abstract: A catalyst and a catalyst packing schedule are designed so that a relation between the raw material conversion rate at which the yield of the objective product becomes maximum and the raw material conversion rate at which a high and low correlation between maximum temperature of the catalyst layer present closest to a reaction gas inlet side Zin and maximum temperature of the catalyst layer present closest to a reaction gas outlet side Zout is reversed satisfies a specific condition of 0.5≦Cmax−Ccrs≦5, in which Cmax: a raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: a raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate is changed, a high and low correlation between Tin and Tout is reversed.

    Abstract translation: 设计催化剂和催化剂填充进度,使得目标产物的产率变得最大的原料转化率与存在催化剂层的最高温度之间的高低相关性的原料转化率之间的关系 最接近反应气体入口侧的Zin和最接近反应气体出口侧的催化剂层的最高温度Zout反过来满足特定条件为0.5& NlE; Cmax-Ccrs≦̸ 5,其中Cmax:原料转化率 目标产品的产量变得最大; Ccrs:将催化剂层Zin的最高温度设为Tin时的原料转化率,将催化剂层Zout的最高温度设为Tout,将原料转化率变更为高,低相关 Tin和Tout之间是相反的。

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