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    Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof
    2.
    发明授权
    Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof 失效
    含硫热裂解石油残渣加氢甲酰化的方法及其新产物

    公开(公告)号：US4922028A

    公开(公告)日：1990-05-01

    申请号：US323070

    申请日：1989-03-10

    申请人： Alexis A. Oswald ,  Ram N. Bhatia ,  Edmund J. Mozeleski ,  Alexandr P. Glivicky ,  Barry G. Brueggeman ,  John R. Hooton ,  Charles M. Smith ,  Chang S. Hsu

    发明人： Alexis A. Oswald ,  Ram N. Bhatia ,  Edmund J. Mozeleski ,  Alexandr P. Glivicky ,  Barry G. Brueggeman ,  John R. Hooton ,  Charles M. Smith ,  Chang S. Hsu

    IPC分类号： C07C29/16 ,  C07C45/50

    CPC分类号： C07C29/16 ,  C07C45/50

    摘要： A catalytic process for the hydroformylation of olefinic, sulfur containing thermally cracked petroleum streams to produce aldehydes and/or alcohols is disclosed. The catalysts are homogeneous transition metal carbonyl complexes. Especially preferred catalysts for low and medium pressure hydroformylation are cobalt and rhodium carbonyl hydride complexes in which some of the carbonyl ligands have been replaced by trivalent phosphorus ligands. In a preferred high pressure hydroformylation, the sulfur-containing naphtha and gas oil distillate feeds are produced from vacuum residue by high temperature thermal cracking. Such feeds contain more than 20% olefins with 1-n-olefins as the single major types. These olefin components are hydroformylated in the presence of a cobalt carbonyl complex to produce a novel type of semilinear aldehyde and/or alcohol product containing an average of less than one alkyl branch per molecule. The alcohols are converted to dialkyl phthalates and other esters having a unique balance of plasticizer properties. They are also useful for producing novel surfactants, particularly ethoxylated derivatives.For the preparation of products containing minimal concentrations of sulfur compounds, narrow distillate fractions of thermally cracked residua are preferred. In the C.sub.6 to C.sub.11 carbon range, single carbon fractions of sharply reduced aromatic hydrocarbon and thiophenic sulfur content can be obtained. These fractions of increased linear olefin content can be advantageously used as hydroformylation feeds in the derivation of low sulfur containing alcohols and related products of increased linearity.

    摘要翻译： 公开了一种用于烯烃，含硫热裂解石油气流加氢甲酰化以产生醛和/或醇的催化方法。 催化剂是均匀的过渡金属羰基络合物。 用于低和中压加氢甲酰化的特别优选的催化剂是钴和铑羰基氢化物络合物，其中一些羰基配体已被三价磷配体取代。 在优选的高压加氢甲酰化反应中，通过高温热裂解从减压渣中产生含硫的石脑油和粗柴油馏分。 这样的进料含有超过20％的烯烃，其中1-正烯烃作为单一主要类型。 这些烯烃组分在羰基钴络合物的存在下被加氢甲酰化，以产生每分子平均含有少于一个烷基支链的新型半线性醛和/或醇产物。 醇被转化为邻苯二甲酸二烷基酯和具有独特平衡的增塑剂性质的其它酯。 它们也可用于生产新型表面活性剂，特别是乙氧基化衍生物。 对于含有最少浓度的硫化合物的产品的制备，优选热裂化残渣的窄馏分馏分。 在C6至C11碳范围内，可以获得芳香烃锐减的单碳馏分和噻吩硫含量。 增加的线性烯烃含量的这些馏分可以有利地用作促进含低级含硫醇和增加线性的相关产物的加氢甲酰化进料。

    Free radical adducts of fullerenes with hydrocarbons and polymers
    4.
    发明授权
    Free radical adducts of fullerenes with hydrocarbons and polymers 失效
    富勒烯与碳氢化合物和聚合物的自由基加成物

    公开(公告)号：US5462680A

    公开(公告)日：1995-10-31

    申请号：US229510

    申请日：1994-04-19

    申请人： Stanley J. Brois ,  Abhimanyu O. Patil ,  Wolfgang W. Schulz ,  Chang S. Hsu ,  Richard T. Garner

    发明人： Stanley J. Brois ,  Abhimanyu O. Patil ,  Wolfgang W. Schulz ,  Chang S. Hsu ,  Richard T. Garner

    IPC分类号： B01D71/00 ,  C08F8/00 ,  C10M127/00 ,  C10M143/00

    CPC分类号： C10M143/00 ,  B01D71/00 ,  C08F8/00 ,  C08F8/32 ,  C10M127/00 ,  C08F2810/20 ,  C10M2203/02 ,  C10M2203/022 ,  C10M2203/024 ,  C10M2203/04 ,  C10M2203/06 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2205/022 ,  C10N2220/02 ,  Y10S977/738

    摘要： This invention relates to novel compositions of matter comprising free radical adducts of a fullerene with one or more saturated hydrocarbons having a number average molecular weight ranging from about 200 to about ten million. Attachment of saturated hydrocarbons to as many as fourteen sites on the fullerene surface can be achieved via free radical initiated reactions. Fullerenes also add to saturated hydrocarbons with functional groups selected from the group consisting of hydroxy, carboxy, and carboalkoxy radicals in the presence of a free radical initiator. Said radical adducts of substantially saturated hydrocarbons with fullerenes react further with alkylamines and polyamines to produce new compositions. The radical adducts, and their aminated derivatives are useful as dispersants and viscosity modifiers in lubricants. In the presence of free radical initiators, said fullerenes can also crosslink substantially saturated polymers having number average molecular weight ranging from about 50,000 to about 500,000. The crosslinked polymers, are useful as new membranes and composites.

    摘要翻译： 本发明涉及包含富勒烯与一种或多种数均分子量为约200至约1000万的饱和烃的自由基加成物的新物质组合物。 通过自由基引发的反应可以将饱和烃连接到富勒烯表面上多达14个位点。 在自由基引发剂的存在下，富勒烯还加入选自羟基，羧基和烷氧羰基的官能团的饱和烃。 基本上饱和的烃与富勒烯的自由基加成物与烷基胺和多胺进一步反应以产生新的组合物。 自由基加合物及其胺化衍生物可用作润滑剂中的分散剂和粘度调节剂。 在存在自由基引发剂的情况下，所述富勒烯还可交联数均分子量范围为约50,000至约500,000的基本上饱和的聚合物。 交联聚合物可用作新膜和复合材料。

    Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof
    6.
    发明授权
    Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof 失效
    含硫热裂解石油残渣加氢甲酰化的方法及其新产物

    公开(公告)号：US5030774A

    公开(公告)日：1991-07-09

    申请号：US461137

    申请日：1990-01-04

    申请人： Alexis A. Oswald ,  Ram N. Bhatia ,  Edmund J. Mozeleski ,  Alexandr P. Glivicky ,  Barry G. Brueggeman ,  John R. Hooton ,  Charles M. Smith ,  Chang S. Hsu

    发明人： Alexis A. Oswald ,  Ram N. Bhatia ,  Edmund J. Mozeleski ,  Alexandr P. Glivicky ,  Barry G. Brueggeman ,  John R. Hooton ,  Charles M. Smith ,  Chang S. Hsu

    IPC分类号： C07C29/16 ,  C07C45/50

    CPC分类号： C07C29/16 ,  C07C45/50

    摘要： A catalytic process for the hydroformylation of olefinic, sulfur containing thermally cracked petroleum streams to produce aldehydes and/or alcohols is disclosed. The catalysts are homogeneous transition metal carbonyl complexes. Especially preferred catalysts for low and medium pressure hydroformylation are cobalt and rhodium carbonyl hydride complexes in which some of the carbonyl ligands have been replaced by trivalent phosphorus ligands. In a preferred high pressure hydroformylation, the sulfur-containing naphtha and gas oil distillate feeds are proudced from vacuum residue by high temperature thermal cracking. Such feeds contain more than 20% olefins with 1-n-olefins as the single major types. These olefin components are hydroformylated in the presence of a cobalt cabonyl complex to produce a novel type of semilinear aldehyde and/or alcohol product containing an average of less than one alkyl branch per molecule. The alcohols are converted to dialkyl phthalates and other esters having a unique balance of plasticizer properties. They are also useful for producing novel surfactants, particularly ethoxylated derivatives.For the preparation of products containing minimal concentrations of sulfur compounds, narrow distillate fractions of thermally cracked residua are preferred. In the C.sub.6 to C.sub.11 carbon range, single carbon fractions of sharply reduced aromatic hydrocarbon and thiophenic sulfur content can be obtained. These fractions of increased linear olefin content can be advantageously used as hydroformylation feeds in the derivation of low sulfur containing alcohols and related products of increased linearity.

    摘要翻译： 公开了一种用于烯烃，含硫热裂解石油气流加氢甲酰化以产生醛和/或醇的催化方法。 催化剂是均匀的过渡金属羰基络合物。 用于低和中压加氢甲酰化的特别优选的催化剂是钴和铑羰基氢化物络合物，其中一些羰基配体已被三价磷配体取代。 在优选的高压加氢甲酰化中，含硫石脑油和粗柴油馏出物通过高温热裂解从真空残渣中骄傲。 这样的进料含有超过20％的烯烃，其中1-正烯烃作为单一主要类型。 这些烯烃组分在钴内酰胺基配合物的存在下被加氢甲酰化，以产生每分子平均含有小于一个烷基支链的新型的半线性醛和/或醇产物。 醇被转化为邻苯二甲酸二烷基酯和具有独特平衡的增塑剂性质的其它酯。 它们也可用于生产新型表面活性剂，特别是乙氧基化衍生物。 对于含有最少浓度的硫化合物的产品的制备，优选热裂化残渣的窄馏分馏分。 在C6至C11碳范围内，可以获得芳香烃锐减的单碳馏分和噻吩硫含量。 增加的线性烯烃含量的这些馏分可以有利地用作促进含低级含硫醇和增加线性的相关产物的加氢甲酰化进料。