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公开(公告)号：US20110190813A1
公开(公告)日：2011-08-04
申请号：US12673400
申请日：2008-08-14
申请人： Alan George Brownlee , Christopher Malcolm Elvin , Jerome Anthony Werkmeister , John Alan Maurice Ramshaw , Charles Mark Lindall
发明人： Alan George Brownlee , Christopher Malcolm Elvin , Jerome Anthony Werkmeister , John Alan Maurice Ramshaw , Charles Mark Lindall
IPC分类号： A61B17/08 , C07K14/00 , C07K14/75 , C07K14/78 , C07K14/435 , C07K1/00 , C07K14/765
CPC分类号： A61L24/10 , A61L24/001 , A61L24/0026 , A61L24/102 , A61L24/106 , A61L24/108 , A61L26/0028 , A61L26/0061 , A61L26/0076 , A61L27/22 , A61L27/50 , C08H1/00 , C09J189/00
摘要： A method of crosslinking a protein or peptide for use as a biomaterial, the method comprising the step of irradiating a photoactivatable metal-ligand complex and an electron acceptor in the presence of the protein or peptide, thereby initiating a crosslinking reaction to form a 3-dimensional matrix of the biomaterial.
摘要翻译： 交联用作生物材料的蛋白质或肽的方法，所述方法包括在蛋白质或肽存在下照射可光活化的金属 - 配体复合物和电子受体的步骤，由此引发交联反应以形成3- 生物材料的三维矩阵。
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公开(公告)号：US08232222B2
公开(公告)日：2012-07-31
申请号：US10537651
申请日：2003-12-01
CPC分类号： B01J31/223 , B01J31/0201 , B01J31/0212 , B01J31/04 , B01J2231/49 , B01J2531/31 , B01J2531/38 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08G63/84 , C08G63/85
摘要： A catalyst composition comprises the reaction product of an alkoxide or condensed alkoxide of a metal M, selected from titanium, zirconium, hafnium, aluminum, or a lanthanide, an alcohol containing at least two hydroxyl groups, a 2-hydroxy carboxylic acid and a base, wherein the ratio of equivalents of base to —COOH acid equivalents of said 2-hydroxy carboxylic acid is in the range 0.0033-0.2:1. The composition is useful as a catalyst for esterification reactions, especially for the production of polyesters such as polyethylene terephthalate, polytrimethylene terephthalate and polybutylene terephthalate.
摘要翻译： 催化剂组合物包含选自钛，锆，铪，铝或镧系金属的金属M的醇盐或稠合醇盐的反应产物，含有至少两个羟基的醇，2-羟基羧酸和碱 其中所述2-羟基羧酸的碱与-COOH酸当量的当量比在0.0033-0.2:1的范围内。 该组合物可用作酯化反应的催化剂，特别是用于生产聚对苯二甲酸乙二醇酯，聚对苯二甲酸丙二醇酯和聚对苯二甲酸丁二醇酯等聚酯。
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公开(公告)号：US09216235B2
公开(公告)日：2015-12-22
申请号：US12673400
申请日：2008-08-14
申请人： Alan George Brownlee , Christopher Malcolm Elvin , Jerome Anthony Werkmeister , John Alan Maurice Ramshaw , Charles Mark Lindall
发明人： Alan George Brownlee , Christopher Malcolm Elvin , Jerome Anthony Werkmeister , John Alan Maurice Ramshaw , Charles Mark Lindall
CPC分类号： A61L24/10 , A61L24/001 , A61L24/0026 , A61L24/102 , A61L24/106 , A61L24/108 , A61L26/0028 , A61L26/0061 , A61L26/0076 , A61L27/22 , A61L27/50 , C08H1/00 , C09J189/00
摘要： A method of crosslinking a protein or peptide for use as a biomaterial, the method comprising the step of irradiating a photoactivatable metal-ligand complex and an electron acceptor in the presence of the protein or peptide, thereby initiating a crosslinking reaction to form a 3-dimensional matrix of the biomaterial.
摘要翻译： 交联用作生物材料的蛋白质或肽的方法，所述方法包括在蛋白质或肽存在下照射可光活化的金属 - 配体复合物和电子受体的步骤，由此引发交联反应以形成3- 生物材料的三维矩阵。
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公开(公告)号：US07767612B2
公开(公告)日：2010-08-03
申请号：US10432510
申请日：2001-11-21
申请人： Andrew Martin Bellamy , Charles Mark Lindall , Calum Harry McIntosh , Martin Graham Partridge , John Armstrong Young , Steven Charles Davies
发明人： Andrew Martin Bellamy , Charles Mark Lindall , Calum Harry McIntosh , Martin Graham Partridge , John Armstrong Young , Steven Charles Davies
CPC分类号： B01J31/26 , B01J31/0212 , B01J31/0239 , B01J31/04 , B01J31/122 , B01J31/223 , B01J2231/14 , B01J2231/49 , B01J2531/31 , B01J2531/42 , B01J2531/46 , B01J2531/48 , B01J2531/52 , C08G63/183 , C08G63/80 , C08G63/85 , C08G63/87 , D01F6/62 , D04H1/42
摘要： A catalyst composition for producing polyesters comprises: a) an organometallic compound obtained by reacting an orthoester or condensed orthoester of titanium, zirconium or aluminum, an alcohol containing at least two hydroxyl groups, a 2-hydroxy carboxylic acid and a base; and b) at least one compound comprising germanium, antimony or tin. Polyesters obtained by esterification reaction in the presence of the catalyst compositions according to the present invention exhibit improved melt properties and are particularly suitable for production of textile and commercial fibers, films and rigid packaging.
摘要翻译： 用于制备聚酯的催化剂组合物包括：a）通过钛，锆或铝的原酸酯或缩合原酸酯，含有至少两个羟基的醇，2-羟基羧酸和碱反应而获得的有机金属化合物; 和b）至少一种包含锗，锑或锡的化合物。 在根据本发明的催化剂组合物的存在下通过酯化反应获得的聚酯表现出改进的熔体性质，并且特别适用于生产纺织品和商业纤维，膜和刚性包装。
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公开(公告)号：US08455387B2
公开(公告)日：2013-06-04
申请号：US13544773
申请日：2012-07-09
CPC分类号： B01J31/223 , B01J31/0201 , B01J31/0212 , B01J31/04 , B01J2231/49 , B01J2531/31 , B01J2531/38 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08G63/84 , C08G63/85
摘要： A catalyst composition comprises the reaction product of an alkoxide or condensed alkoxide of a metal M, selected from titanium, zirconium, hafnium, aluminum, or a lanthanide, an alcohol containing at least two hydroxyl groups, a 2-hydroxy carboxylic acid and a base, wherein the molar ratio of base to 2-hydroxy carboxylic acid is in the range 0.01-0.79:1. The composition is useful as a catalyst for esterification reactions, especially for the production of polyesters such as polyethylene terephthalate, polytrimethylene terephthalate and polybutylene terephthalate.
摘要翻译： 催化剂组合物包含选自钛，锆，铪，铝或镧系金属的金属M的醇盐或稠合醇盐的反应产物，含有至少两个羟基的醇，2-羟基羧酸和碱 其中碱与2-羟基羧酸的摩尔比在0.01-0.79:1的范围内。 该组合物可用作酯化反应的催化剂，特别是用于生产聚对苯二甲酸乙二醇酯，聚对苯二甲酸丙二醇酯和聚对苯二甲酸丁二醇酯等聚酯。
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公开(公告)号：US20120271030A1
公开(公告)日：2012-10-25
申请号：US13544773
申请日：2012-07-09
IPC分类号： C08F4/16 , C08G63/183 , C07C69/704
CPC分类号： B01J31/223 , B01J31/0201 , B01J31/0212 , B01J31/04 , B01J2231/49 , B01J2531/31 , B01J2531/38 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08G63/84 , C08G63/85
摘要： A catalyst composition comprises the reaction product of an alkoxide or condensed alkoxide of a metal M, selected from titanium, zirconium, hafnium, aluminium, or a lanthanide, an alcohol containing at least two hydroxyl groups, a 2-hydroxy carboxylic acid and a base, wherein the molar ratio of base to 2-hydroxy carboxylic acid is in the range 0.01-0.79:1. The composition is useful as a catalyst for esterification reactions, especially for the production of polyesters such as polyethylene terephthalate, polytrimethylene terephthalate and polybutylene terephthalate.
摘要翻译： 催化剂组合物包含选自钛，锆，铪，铝或镧系金属的金属M的醇盐或稠合醇盐的反应产物，含有至少两个羟基的醇，2-羟基羧酸和碱 其中碱与2-羟基羧酸的摩尔比在0.01-0.79:1的范围内。 该组合物可用作酯化反应的催化剂，特别是用于生产聚对苯二甲酸乙二醇酯，聚对苯二甲酸亚丙酯和聚对苯二甲酸丁二醇酯等聚酯。
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