公开(公告)号：US20100160570A1

公开(公告)日：2010-06-24

申请号：US12340655

申请日：2008-12-20

申请人： Cyril Chevillard ,  Jay Nguyen

发明人： Cyril Chevillard ,  Jay Nguyen

IPC分类号： C08F10/00

CPC分类号： C08J5/18 ,  B29C47/0004 ,  B29C47/0026 ,  B29C47/009 ,  B29C2791/007 ,  B29K2023/065 ,  C08J2323/04

摘要： Blown films and processes of forming the same are described herein. The processes generally include providing a bimodal ethylene based polymer, blending the bimodal ethylene based polymer with at least about 30 ppm peroxide to form modified polyethylene and forming the modified polyethylene into a blown film.

摘要翻译： 吹塑膜及其形成方法在本文中描述。 方法通常包括提供双峰乙烯基聚合物，将双峰乙烯基聚合物与至少约30ppm过氧化物共混以形成改性聚乙烯并将改性聚乙烯形成吹塑薄膜。

公开(公告)号：US07683137B2

公开(公告)日：2010-03-23

申请号：US11174854

申请日：2005-07-05

申请人： Vincent Henri Barre ,  Tim J. Coffy ,  Cyril Chevillard

发明人： Vincent Henri Barre ,  Tim J. Coffy ,  Cyril Chevillard

IPC分类号： C08F8/06 ,  C08F210/02

CPC分类号： C08F6/02 ,  C08K3/22 ,  C08K5/05 ,  C08K5/098 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/2967 ,  C08L23/04

摘要： Polyethylene modified by using radical initiators such as oxygen and peroxides sometimes has a yellow color which may be reduced or eliminated by incorporating additives such as polyethylene glycol, and/or neutralizing species such as alkali metal stearates, particularly calcium stearate, and zinc oxide.

摘要翻译： 通过使用自由基引发剂如氧和过氧化物改性的聚乙烯有时具有黄色，其可以通过掺入添加剂如聚乙二醇和/或中和物质如碱金属硬脂酸盐，特别是硬脂酸钙和氧化锌而被还原或消除。

公开(公告)号：US20070007680A1

公开(公告)日：2007-01-11

申请号：US11174815

申请日：2005-07-05

申请人： Vincent Henri Barre ,  Son Nguyen ,  Cyril Chevillard ,  Gerhard Guenther

发明人： Vincent Henri Barre ,  Son Nguyen ,  Cyril Chevillard ,  Gerhard Guenther

IPC分类号： B29C45/76

CPC分类号： B29C48/10 ,  B29C48/18 ,  B29C48/92 ,  B29C49/04 ,  B29C2948/92047 ,  B29C2948/922 ,  B29C2948/92314 ,  B29K2023/06 ,  B29K2023/0625 ,  B29K2023/0633 ,  B29K2023/0641 ,  B29K2023/065 ,  B29K2105/0008 ,  B29K2105/0032 ,  B29K2105/0044 ,  B29K2105/005

摘要： The rheology of polyethylene resin may be controlled by measuring the specific energy input (SEI) to the extruder and then adjusting a process parameter in response to a change in the SEI and/or by introducing both a free radical initiator and an alkali earth metal stearate into the polymerization. Indeed, the process parameter changed in response to the SEI measurement may be adjusting the proportion of free radical initiator, adjusting the proportion of alkali earth metal stearate, or both. The free radical initiator may be a peroxide, and the alkali earth metal stearate may be calcium stearate.

摘要翻译： 聚乙烯树脂的流变学可以通过测量挤出机的比能量输入（SEI）来控制，然后响应于SEI的变化调整工艺参数和/或通过引入自由基引发剂和碱土金属硬脂酸酯 进入聚合。 实际上，响应于SEI测量而改变的工艺参数可以调节自由基引发剂的比例，调节硬脂酸碱土金属的比例，或两者。 自由基引发剂可以是过氧化物，碱土金属硬脂酸酯可以是硬脂酸钙。

公开(公告)号：US07041733B2

公开(公告)日：2006-05-09

申请号：US10691827

申请日：2003-10-23

申请人： Cyril Chevillard ,  Jose M. Sosa

发明人： Cyril Chevillard ,  Jose M. Sosa

IPC分类号： C08F279/02 ,  C08F4/38

CPC分类号： C08F279/02 ,  C08F212/08

摘要： It has been discovered that certain compounds serve as particle size regulators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers in the presence of diene polymers. Suitable compounds that can control particle size include, but are not necessarily limited to, cobalt naphthenate, zinc naphthenate, iron octoate, calcium octoate, zinc octoate, zinc neodecanoate, potassium octoate, copper naphthenate, calcium versalate, and the like. Use of these metal carboxylates when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in reduced polybutadiene particles. Grafting and morphology characteristics may also be improved.

摘要翻译： 已经发现，当与二烯聚合物存在下乙烯基芳族单体聚合时，某些化合物与过氧化物引发剂一起使用时用作粒度调节剂。 可以控制颗粒尺寸的合适的化合物包括但不一定限于环烷酸钴，环烷酸锌，辛酸铁，辛酸钙，辛酸锌，新癸酸锌，辛酸钾，环烷酸铜，三钙酸钙等。 当乙烯基芳族单体在聚丁二烯和过氧化物引发剂存在下聚合时，这些金属羧酸盐的使用导致聚丁二烯颗粒减少。 接枝和形态特征也可以改善。

公开(公告)号：US20050277754A1

公开(公告)日：2005-12-15

申请号：US11208909

申请日：2005-08-22

申请人： Brad Stiles ,  Jose Sosa ,  Cyril Chevillard ,  Aron Griffith ,  Jay Reimers

发明人： Brad Stiles ,  Jose Sosa ,  Cyril Chevillard ,  Aron Griffith ,  Jay Reimers

IPC分类号： C08F2/38 ,  C08F4/36 ,  C08F12/02 ,  C08F279/02 ,  C08L20060101 ,  C08L51/00

CPC分类号： C08F2/00 ,  C08F112/08 ,  C08F279/02 ,  C08F2400/02 ,  C08L25/06 ,  C08L2205/02 ,  C08L2666/04 ,  C08F212/08

摘要： Disclosed are novel non-linear vinyl polymers comprised of a multifunctional peroxide, and a cross-linking agent and/or a chain transfer agent, and methods of making such polymers having: at least 0.03 branches/1000 backbone carbons; linear portions with a molecular weight (Mw) of 350,000 or less; 0.2 to 3.0 branches/molecule; or, a Mz/Mw of from 1.7 to 5.7. Methods of quantifying branching are disclosed using a linear reference having 0.0 to 0.06 branches/1000 backbone carbons along with SEC techniques and measurements of molecular weight, molecular size, and concentration. Also discovered is a vinyl polymer resin comprised of from 0.1 to 50 weight percent of non-linear polymers having at least 0.06 branches/1000 backbone carbons, where branching is measured using a heat polymerized polystyrene having from 0.0 to 0.06 branches/1000 backbone carbons as a linear reference.

摘要翻译： 公开了由多官能过氧化物，交联剂和/或链转移剂组成的新型非线性乙烯基聚合物，以及制备这种聚合物的方法，其具有：至少0.03个支链/ 1000个骨架碳; 分子量（Mw）为350,000以下的线性部分; 0.2〜3.0支/分子; 或者为1.7至5.7的Mz / Mw。 使用具有0.0至0.06个支链/ 1000个骨架碳的线性参考文献以及SEC技术和分子量，分子大小和浓度的测量来公开定量分支的方法。 还发现了乙烯基聚合物树脂，其由0.1至50重量％的具有至少0.06个支链/ 1000个骨架碳的非线性聚合物组成，其中使用具有0.0至0.06个支链/ 1000个骨架碳的热聚合聚苯乙烯测量分支， 线性参考。

公开(公告)号：US08859703B2

公开(公告)日：2014-10-14

申请号：US13338304

申请日：2011-12-28

申请人： Tim Coffy ,  Steven Gray ,  David Knoeppel ,  Cyril Chevillard ,  David Rauscher ,  Carlos Corleto ,  Gerhard Guenther ,  Brian B. Cole ,  Stan Biesert ,  Vincent Barre ,  Ruby L. Curtis ,  Son Nguyen ,  Danielle Childress

发明人： Tim Coffy ,  Steven Gray ,  David Knoeppel ,  Cyril Chevillard ,  David Rauscher ,  Carlos Corleto ,  Gerhard Guenther ,  Brian B. Cole ,  Stan Biesert ,  Vincent Barre ,  Ruby L. Curtis ,  Son Nguyen ,  Danielle Childress

IPC分类号： C08F10/02 ,  B29C47/00 ,  C08F10/00 ,  C08F210/16 ,  C08F110/02

CPC分类号： C08F10/00 ,  B29C47/92 ,  B29C2947/922 ,  B29C2947/924 ,  B29C2947/92514 ,  B29C2947/92542 ,  B29C2947/92695 ,  B29C2947/92714 ,  B29C2947/92895 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F2400/02 ,  C08F4/6567 ,  C08F4/6557 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/05 ,  C08F2500/12 ,  C08F210/08

摘要： Disclosed is a bimodal Ziegler-Natta catalyzed polyethylene, having a density of from 0.930 g/cc to 0.960 g/cc, and a molecular weight distribution of from 10 to 25, wherein an article formed therefrom has a PENT of at least 1500. Also disclosed is a method of preparing a tubular article including obtaining a bimodal polyethylene having a density of from 0.930 g/cc to 0.960 g/cc and a molecular weight distribution of from 10 to 25, and processing the polyethylene under conditions where a specific energy input (SEI) is less than 300 kW·h/ton, and wherein the article has a PENT of at least 1500. Further disclosed is a method for controlling the degradation of polyethylene including polymerizing ethylene monomer, recovering polyethylene, extruding the polyethylene, and controlling the degradation of polyethylene by measuring the SEI to the extruder and adjusting throughput and/or gear suction pressure keep SEI less than 300 kW·h/ton, and forming an article.

摘要翻译： 公开了一种双峰型齐格勒 - 纳塔催化聚乙烯，其密度为0.930g / cc至0.960g / cc，分子量分布为10至25，其中由其形成的制品具有至少1500的PENT。另外 公开了一种制备管状制品的方法，包括获得密度为0.930g / cc至0.960g / cc和分子量分布为10至25的双峰聚乙烯，并在特定能量输入条件下处理聚乙烯 （SEI）小于300kW·h / ton，其中制品的PENT为至少1500.另外公开了一种控制聚乙烯降解的方法，包括聚合乙烯单体，回收聚乙烯，挤出聚乙烯，控制 通过测量SEI到挤出机并调整产量和/或齿轮吸入压力，聚乙烯的降解使SEI小于300kW·h / ton，形成物品。

公开(公告)号：US08026305B2

公开(公告)日：2011-09-27

申请号：US12243315

申请日：2008-10-01

申请人： Michael McLeod ,  John Ashbaugh ,  Cyril Chevillard ,  Gerhard Guenther ,  Ruby L. Curtis ,  Jay Nguyen ,  Juan Aguirre ,  Raleigh McBride ,  Ben Hicks

发明人： Michael McLeod ,  John Ashbaugh ,  Cyril Chevillard ,  Gerhard Guenther ,  Ruby L. Curtis ,  Jay Nguyen ,  Juan Aguirre ,  Raleigh McBride ,  Ben Hicks

IPC分类号： C08K5/04 ,  C08K5/09 ,  C08L23/06

CPC分类号： C08K5/0083 ,  C08L23/0815 ,  C08L23/06

摘要： Polymer articles and processes of forming the same are described herein. The processes generally include providing an ethylene based polymer, blending the ethylene based polymer with a modifier to form modified polyethylene and forming the modified polyethylene into a polymer article, wherein the polymer article exhibits a haze that is at least about 10% less than a polymer article prepared with a similarly modified polyethylene.

摘要翻译： 本文描述了聚合物制品及其形成方法。 该方法通常包括提供基于乙烯的聚合物，将基于乙烯的聚合物与改性剂共混以形成改性的聚乙烯并将改性的聚乙烯形成聚合物制品，其中聚合物制品的雾度比聚合物低至少约10％ 用类似改性聚乙烯制备的制品。

公开(公告)号：US20100081746A1

公开(公告)日：2010-04-01

申请号：US12568357

申请日：2009-09-28

申请人： Vincent Henri Barre ,  Tim J. Coffy ,  Cyril Chevillard

发明人： Vincent Henri Barre ,  Tim J. Coffy ,  Cyril Chevillard

IPC分类号： C08K5/098 ,  C08K5/05 ,  C08K3/22

CPC分类号： C08F6/02 ,  C08K3/22 ,  C08K5/05 ,  C08K5/098 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/2967 ,  C08L23/04

摘要： Polyethylene modified by using radical initiators such as oxygen and peroxides sometimes has a yellow color which may be reduced or eliminated by incorporating additives such as polyethylene glycol, and/or neutralizing species such as alkali metal stearates, particularly calcium stearate, and zinc oxide.

摘要翻译： 通过使用自由基引发剂如氧和过氧化物改性的聚乙烯有时具有黄色，其可以通过掺入添加剂如聚乙二醇和/或中和物质如碱金属硬脂酸盐，特别是硬脂酸钙和氧化锌而被还原或消除。

公开(公告)号：US20070007681A1

公开(公告)日：2007-01-11

申请号：US11267984

申请日：2005-11-07

申请人： Cyril Chevillard ,  Son Nguyen ,  Gerhard Guenther ,  Vincent Barre

发明人： Cyril Chevillard ,  Son Nguyen ,  Gerhard Guenther ,  Vincent Barre

IPC分类号： B29C45/76

CPC分类号： B29C48/10 ,  B29C48/18 ,  B29C48/92 ,  B29C49/04 ,  B29C2948/92047 ,  B29C2948/922 ,  B29C2948/92314 ,  B29K2023/06 ,  B29K2023/0625 ,  B29K2023/0633 ,  B29K2023/0641 ,  B29K2023/065 ,  B29K2105/0008 ,  B29K2105/0032 ,  B29K2105/0044 ,  B29K2105/005

摘要： Improving polyethylene film properties may be accomplished by measuring the specific energy input (SEI) to the extruder and then adjusting a process parameter in response to a change in the SEI and/or by introducing both a free radical initiator and an alkali earth metal stearate into the polymerization. Alternatively or in addition thereto, selecting the optimum free radical initiator for a particular polyethylene resin polymerized in the presence of a selected catalyst between two resin properties may be accomplished by examining the ratio of: % ⁢   ⁢ variation ⁢   ⁢ in ⁢   ⁢ a ⁢   ⁢ first ⁢   ⁢ property % ⁢   ⁢ variation ⁢   ⁢ in ⁢   ⁢ a ⁢   ⁢ second ⁢   ⁢ property of polyethylene resins individually made with each free radical initiator under consideration. The free radical initiator may be oxygen, peroxides, peroxyketals, peroxyesters, and/or dialkyl peroxides.

公开(公告)号：US20050090614A1

公开(公告)日：2005-04-28

申请号：US10691827

申请日：2003-10-23

申请人： Cyril Chevillard ,  Jose Sosa

发明人： Cyril Chevillard ,  Jose Sosa

IPC分类号： C08F279/02 ,  C08G63/48 ,  C08F4/00

CPC分类号： C08F279/02 ,  C08F212/08

摘要： It has been discovered that certain compounds serve as particle size regulators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers in the presence of diene polymers. Suitable compounds that can control particle size include, but are not necessarily limited to, cobalt naphthenate, zinc naphthenate, iron octoate, calcium octoate, zinc octoate, zinc neodecanoate, potassium octoate, copper naphthenate, calcium versalate, and the like. Use of these metal carboxylates when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in reduced polybutadiene particles. Grafting and morphology characteristics may also be improved.

摘要翻译： 已经发现，当与二烯聚合物存在下乙烯基芳族单体聚合时，某些化合物与过氧化物引发剂一起使用时用作粒度调节剂。 可以控制颗粒尺寸的合适的化合物包括但不一定限于环烷酸钴，环烷酸锌，辛酸铁，辛酸钙，辛酸锌，新癸酸锌，辛酸钾，环烷酸铜，三钙酸钙等。 当乙烯基芳族单体在聚丁二烯和过氧化物引发剂存在下聚合时，这些金属羧酸盐的使用导致聚丁二烯颗粒减少。 接枝和形态特征也可以改善。