Energy efficient synthesis of boranes
    1.
    发明授权
    Energy efficient synthesis of boranes 有权
    能量高效合成硼烷

    公开(公告)号:US08101786B2

    公开(公告)日:2012-01-24

    申请号:US12914595

    申请日:2010-10-28

    IPC分类号: C01B6/24 C08G79/08

    CPC分类号: C01B6/15 C01B6/19 C01B35/061

    摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.

    摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其电还原电位或通过甲酸盐的热解提供还原电位。

    ENERGY EFFICIENT SYNTHESIS OF BORANES
    2.
    发明申请
    ENERGY EFFICIENT SYNTHESIS OF BORANES 有权
    能量有效地合成硼

    公开(公告)号:US20110105706A1

    公开(公告)日:2011-05-05

    申请号:US12914595

    申请日:2010-10-28

    IPC分类号: C08F130/04 C07F5/02 C07F7/22

    CPC分类号: C01B6/15 C01B6/19 C01B35/061

    摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.

    摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其还原电位通过电化学方法或通过甲酸盐的热解提供。

    ANION-CONDUCTING POLYMER, COMPOSITION, AND MEMBRANE
    3.
    发明申请
    ANION-CONDUCTING POLYMER, COMPOSITION, AND MEMBRANE 失效
    阴离子导电聚合物,组合物和膜

    公开(公告)号:US20090318575A1

    公开(公告)日:2009-12-24

    申请号:US12549021

    申请日:2009-08-27

    IPC分类号: C08J5/22

    摘要: Anion-conducing polymers and membranes with enhanced stability to aqueous alkali include a polymer backbone with attached sulfonium, phosphazenium, phosphazene, and guanidinium residues. Compositions also with enhanced stability to aqueous alkali include a support embedded with sulfonium, phosphazenium, and guanidinium salts.

    摘要翻译: 具有增强的碱水溶液稳定性的阴离子导电聚合物和膜包括具有连接的锍,磷腈鎓,磷腈和胍残基的聚合物主链。 具有增强的碱水溶液稳定性的组合物包括含有锍,磷腈鎓和胍盐的载体。

    Anion-conducting polymer, composition, and membrane
    5.
    发明授权
    Anion-conducting polymer, composition, and membrane 有权
    阴离子导电聚合物,组合物和膜

    公开(公告)号:US08063111B2

    公开(公告)日:2011-11-22

    申请号:US12917041

    申请日:2010-11-01

    摘要: Anion-conducing polymers and membranes with enhanced stability to aqueous alkali include a polymer backbone with attached sulfonium, phosphazenium, phosphazene, and guanidinium residues. Compositions also with enhanced stability to aqueous alkali include a support embedded with sulfonium, phosphazenium, and guanidinium salts.

    摘要翻译: 具有增强的碱水溶液稳定性的阴离子导电聚合物和膜包括具有连接的锍,磷腈鎓,磷腈和胍残基的聚合物主链。 具有增强的碱水溶液稳定性的组合物包括含有锍,磷腈鎓和胍盐的载体。

    ANION-CONDUCTING POLYMER, COMPOSITION, AND MEMBRANE
    10.
    发明申请
    ANION-CONDUCTING POLYMER, COMPOSITION, AND MEMBRANE 有权
    阴离子导电聚合物,组合物和膜

    公开(公告)号:US20110046246A1

    公开(公告)日:2011-02-24

    申请号:US12917041

    申请日:2010-11-01

    IPC分类号: B01J41/12

    摘要: Anion-conducing polymers and membranes with enhanced stability to aqueous alkali include a polymer backbone with attached sulfonium, phosphazenium, phosphazene, and guanidinium residues. Compositions also with enhanced stability to aqueous alkali include a support embedded with sulfonium, phosphazenium, and guanidinium salts.

    摘要翻译: 具有增强的碱水溶液稳定性的阴离子导电聚合物和膜包括具有连接的锍,磷腈鎓,磷腈和胍残基的聚合物主链。 具有增强的碱水溶液稳定性的组合物包括含有锍,磷腈鎓和胍盐的载体。