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    Polymers comprising superacidic groups, and uses thereof
    4.
    发明申请
    Polymers comprising superacidic groups, and uses thereof 审中-公开
    包含超酸基团的聚合物及其用途

    公开(公告)号：US20080114149A1

    公开(公告)日：2008-05-15

    申请号：US11598948

    申请日：2006-11-14

    申请人： David Roger Moore ,  Hongyi Zhou ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Joyce Hung

    发明人： David Roger Moore ,  Hongyi Zhou ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Joyce Hung

    IPC分类号： C08G63/688

    CPC分类号： C08G75/23 ,  C08G65/4025 ,  C08G65/4056

    摘要： The invention relates generally to polymers derived from monomers having aromatic superacidic functional groups. The superacidic functional groups comprise fluorinated sulfonate moieties. Polymers provided by the present invention include polyethers, polyesters, polycarbonates, polyestercarbonates, polyetherketones, and polyethersulfones among others. The polymers provided by the present invention include block and random copolymers. In one embodiment, the present invention provides a polyetherketone-polyethersulfone block copolymer comprising superacidic functional groups. Polymers comprising superacidic functional groups are useful materials in membrane applications. The superacidic functional groups present in the new polymer compositions impart excellent proton conductivities. In one embodiment, the present invention provides polymers useful as materials for polymer electrolyte fuel cell membranes.

    摘要翻译： 本发明一般涉及衍生自具有芳族超酸官能团的单体的聚合物。 超酸性官能团包括氟化磺酸盐部分。 本发明提供的聚合物包括聚醚，聚酯，聚碳酸酯，聚酯碳酸酯，聚醚酮和聚醚砜等。 本发明提供的聚合物包括嵌段和无规共聚物。 在一个实施方案中，本发明提供了包含超酸官能团的聚醚酮 - 聚醚砜嵌段共聚物。 包含超酸性官能团的聚合物是膜应用中的有用材料。 存在于新聚合物组合物中的超酸性官能团赋予优异的质子导电性。 在一个实施方案中，本发明提供了可用作聚合物电解质燃料电池膜的材料的聚合物。

    Mixed-sulfonation block copolymers
    8.
    发明授权
    Mixed-sulfonation block copolymers 失效
    混合磺化嵌段共聚物

    公开(公告)号：US07598337B2

    公开(公告)日：2009-10-06

    申请号：US11314337

    申请日：2005-12-20

    申请人： Joyce Hung ,  Hongyi Zhou ,  David Roger Moore ,  Marianne Elisabeth Harmon ,  Daniel Joseph Brunelle ,  Hongwei Liu

    发明人： Joyce Hung ,  Hongyi Zhou ,  David Roger Moore ,  Marianne Elisabeth Harmon ,  Daniel Joseph Brunelle ,  Hongwei Liu

    IPC分类号： C08G2/00

    CPC分类号： C08G65/4012 ,  C08G65/48 ,  C08G75/23

    摘要： Sulfonated block copolymers that may be used as membranes for fuel cells include sulfonated polyaryletherketone blocks and lightly sulfonated polyethersulfone blocks.The sulfonated polyaryletherketone blocks include structural units of formula and the lightly sulfonated polyethersulfone blocks include structural units of formula wherein R1, R2, R3, R4, R5 and R6 are independently C1-C10 alkyl, C3-C12 cycloalkyl, C6-C14 aryl, allyl, alkenyl, alkoxy, halo, or cyano; Z, Z1 and Z2 are independently a direct bond or O, S, (CH2)r, (CF2)r, C(CH3)2, C(CF3)2, or a combination thereof; M is H, a metal cation, a non-metallic inorganic cation, an organic cation or a mixture thereof; a and e are independently 0 or an integer from 1 to 3; b, c, d, and f are independently 0 or an integer from 1 to 4; m, n and p are independently 0 or 1; and r is an integer from 1 to 5.

    摘要翻译： 可用作燃料电池膜的磺化嵌段共聚物包括磺化聚芳醚酮嵌段和轻质磺化聚醚砜嵌段。 磺化的聚芳醚酮嵌段包括式的结构单元，轻度磺化的聚醚砜嵌段包括下式的结构单元：其中R1，R2，R3，R4，R5和R6独立地为C1-C10烷基，C3-C12环烷基，C6-C14芳基，烯丙基 ，烯基，烷氧基，卤素或氰基; Z，Z 1和Z 2独立地为直接键或O，S，（CH 2）r，（CF 2）r，C（CH 3）2，C（CF 3） M是H，金属阳离子，非金属无机阳离子，有机阳离子或其混合物; a和e独立地为0或1〜3的整数; b，c，d和f独立地为0或1〜4的整数; m，n和p独立地为0或1; r为1〜5的整数。