Abstract:
Novel silicone polymers are provided which possess grafted pendant hydrophilic polyalkylene oxide side chains and, optionally, reactive functional end groups. These features make them well suited for use in chemical, marine, biomedical and industrial applications, particularly those involving surface modifications.
Abstract:
The invention provides highly functional epoxy resins that may be used themselves in coating formulations and applications but which may be further functionalized via ring-opening reactions of the epoxy groups yielding derivative resins with other useful functionalities. The highly functional epoxy resins are synthesized from the epoxidation of vegetable or seed oil esters of polyols having 4 or more hydroxyl groups/molecule. In one embodiment, the polyol is sucrose and the vegetable or seed oil is selected from corn oil, castor oil, soybean oil, safflower oil, sunflower oil, linseed oil, tall oil fatty acid, tung oil, vernonia oil, and mixtures thereof. Methods of making of the epoxy resin and each of its derivative resins are disclosed as are coating compositions and coated objects using each of the resins.
Abstract:
Alkyd resin compositions which comprise the monomer-grafting polymerization of a) an alkyd, which is an ester of a polyol having 4 or more hydroxyl groups and an unsaturated fatty acid, and b) an unsaturated monomer having a carbon-carbon double bond are disclosed. The alkyd may be a partially esterified polyol. Coating compositions of containing the alkyd resin compositions of the invention are also disclosed.
Abstract:
The invention provides an improved unsaturated polyester prepared from the polycondensation of unsaturated diacid monomers or unsaturated acid anhydride mononers and polyol monomers and. optionally, one or more saturated aliphatic or aromatic diacid monomers or anhydride monomers thereof. The improvement comprises 0.5 to 50 weight percent, based on the total monomer weight, of an hydroxyalkyl-functional siloxane of formula (1) below. The invention also relates to a UV curable coating formulation containing a siloxane-functional unsaturated polyester resin, a vinyl ether functional diluents and a photoinitiator. The invention further provides a method of preparing an article with a low-surface energy coating. According to the method, at least one surface of an article with a coating formulation of the invention; and the coating is then cured as described above with UV light to form a low-surface energy coating on the surface. The invention also relates to articles having a low-surface energy coating according to the invention.
Abstract:
A polymeric material may be prepared by reacting a composition that includes polyol, polyisocyanate, and polyorganosiloxane having functional groups capable of reacting with the polyisocyanate, wherein the polymeric material has a surface which includes raised microdomains.
Abstract:
The invention relates to alcohol-modified glycidyl carbamate resins wherein at least some of the glycidol groups in the resin have been replaced with an alcohol. The invention also relates to coating compositions containing the resins.
Abstract:
A polymeric material may be prepared by reacting a mixture comprising an amino functional polyorganosiloxane, polyisocyanate, and polyol. The polyol may comprise a hydroxy-functional poly(meth)acrylate. The polymeric material may be used as a coating for a substrate and may inhibit fouling on a surface exposed to aquatic conditions.
Abstract:
This invention involves a carbamate functional polymer or oligomer made by reacting a cyclic carbonate with ammonia or a primary amine, then reacting the resulting hydroxycarbamate with a polyfunctional material containing groups reactive with hydroxyl groups to form a polyfunctional carbamate. The polymer formed is mixed with an aminoplast, coated on a substrate and cured to form a crosslinked coating.
Abstract:
This invention relates to coating compositions comprising a glycidyl carbamate functional resin, an epoxy resin, and an amine curing agent. The coating compositions have improved corrosion resistance, particularly on untreated steel substrates.