Electronic Device Module Comprising Heterogeneous Polyolefin Copolymer and Optionally Silane
    1.
    发明申请
    Electronic Device Module Comprising Heterogeneous Polyolefin Copolymer and Optionally Silane 审中-公开
    包含非均相聚烯烃共聚物和任选的硅烷的电子器件模块

    公开(公告)号:US20130087198A1

    公开(公告)日:2013-04-11

    申请号:US13703405

    申请日:2011-06-15

    IPC分类号: H01L31/0203 H05K1/03

    摘要: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer characterized as having has an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less than about 1.95 and wherein the copolymer has a CDBI of less than 60%, (2) optionally, a vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (4) optionally, a co-agent in an amount of at least about 0.05 wt % based upon the weight of the copolymer.

    摘要翻译: 一种电子设备模块,包括:A.至少一个电子设备,例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料,所述聚合物材料包括(1)聚烯烃共聚物, 具有在互聚物和高结晶部分Thc之间具有平均Mv和谷值温度,使得在ATREF之上的Thc以上的分数的平均Mv除以ATREF(Mhc / Mp)之外的整个聚合物的平均Mv小于 约1.95,并且其中所述共聚物的CDBI小于60%,(2)任选的乙烯基硅烷,(3)任选的自由基引发剂或光引发剂,其量为至少约0.05重量% 共聚物,和(4)任选地,基于共聚物的重量,至少约0.05重量%的助剂。

    Electronic Device Module Comprising Film of Homogeneous Polyolefin Copolymer and Adhesive Property Enhancing Graft Polymer
    6.
    发明申请
    Electronic Device Module Comprising Film of Homogeneous Polyolefin Copolymer and Adhesive Property Enhancing Graft Polymer 审中-公开
    包含均匀聚烯烃共聚物膜和粘合剂性能的电子装置模块增强接枝聚合物

    公开(公告)号:US20130206224A1

    公开(公告)日:2013-08-15

    申请号:US13701060

    申请日:2011-06-06

    IPC分类号: H05K1/03 H01L31/048

    摘要: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm3; total unsaturation of not more than 125 per 100,000 carbons; and; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/Mn), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145° C.) and 1H-NMR (125° C.), (2) a graft polymer to enhance the adhesion, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt % based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.

    摘要翻译: 一种电子设备模块,包括:A.至少一个电子设备,例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料,所述聚合物材料包含(1)乙烯互聚物,其包含 总聚合物密度不大于0.905g / cm3; 总不饱和度不超过125 / 100,000个碳; 和; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 和总数(1000 / Mn)的乙烯基/ 1000个碳的总数,其中通过凝胶渗透色谱(145℃)和1 H-NMR(125°)测量乙烯基-3含量和乙烯基测量值 (3)任选的自由基引发剂或光引发剂,其量为至少约0.05重量%,基于共聚物的重量,和(3)任选地, 基于共聚物的重量,至少约0.05重量%的量的助剂。

    ELECTRONIC DEVICE MODULE COMPRISING POLYOLEFIN COPOLYMER WITH LOW UNSATURATION AND OPTIONAL VINYL SILANE
    8.
    发明申请
    ELECTRONIC DEVICE MODULE COMPRISING POLYOLEFIN COPOLYMER WITH LOW UNSATURATION AND OPTIONAL VINYL SILANE 审中-公开
    具有低不饱和度和可选的乙烯基硅烷的聚烯烃共聚物的电子器件模块

    公开(公告)号:US20110290317A1

    公开(公告)日:2011-12-01

    申请号:US13116520

    申请日:2011-05-26

    IPC分类号: H01L31/0216

    摘要: An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene-based polymer composition characterized by a Comonomer Distribution Constant greater than about 45, more preferably greater than 50, most preferably greater than 95, and as high as 400, preferably as high as 200, wherein the composition has less than 120 total unsaturation unit/1,000,000C, preferably the ethylene-based polymer compositions comprise up to about 3 long chain branches/1000 carbons, more preferably from about 0.01 to about 3 long chain branches/1000 carbons; the ethylene-based polymer composition can have a ZSVR of at least 2; the ethylene-based polymer compositions can be further characterized by comprising less than 20 vinylidene unsaturation unit/1,000,000C; the ethylene-based polymer compositions can have a bimodal molecular weight distribution (MWD) or a multi-modal MWD; the ethylene-based polymer compositions can have a comonomer distribution profile comprising a mono or bimodal distribution from 35° C. to 120° C., excluding purge; the ethylene-based polymer compositions can comprise a single DSC melting peak; the ethylene-based polymer compositions can comprise a weight average molecular weight (Mw) from about 17,000 to about 220,000, (2) optionally, a vinyl silane, (3) optionally, a free radical initiator, e.g., a peroxide or azo compound, or a photoinitiator, e.g., benzophenone, and (4) optionally, a co-agent.

    摘要翻译: 一种电子设备模块,包括:A.至少一个电子设备,例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料,所述聚合物材料包括(1)基于乙烯的 聚合物组合物的特征在于共聚单体分布常数大于约45,更优选大于50,最优选大于95,高达400,优选高达200,其中组合物具有小于120总不饱和单元/ 1,000,000C 优选地,基于乙烯的聚合物组合物包含最多约3个长链分支/ 1000个碳,更优选约0.01至约3个长支链/ 1000个碳; 基于乙烯的聚合物组合物可以具有至少2的ZSVR; 基于乙烯的聚合物组合物可以进一步表征为包含少于20个亚乙烯基不饱和单元/ 1,000,000C; 乙烯基聚合物组合物可以具有双峰分子量分布(MWD)或多模态MWD; 乙烯基聚合物组合物可以具有包含35℃至120℃的单峰或双峰分布的共聚单体分布分布,不包括吹扫; 基于乙烯的聚合物组合物可以包含单个DSC熔融峰; 基于乙烯的聚合物组合物可包含约17,000至约220,000的重均分子量(Mw),(2)任选的乙烯基硅烷,(3)任选的自由基引发剂,例如过氧化物或偶氮化合物, 或光引发剂,例如二苯甲酮,和(4)任选的助剂。