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公开(公告)号：US5536886A
公开(公告)日：1996-07-16
申请号：US305920
申请日：1994-09-16
申请人： Esa Tamminen , Juhani Aittamaa , Juha Jakkula
发明人： Esa Tamminen , Juhani Aittamaa , Juha Jakkula
CPC分类号： B01D3/009 , C07C41/06 , C07C41/42 , Y02P20/127
摘要： The invention relates to a process for preparing tertiary alkyl ethers. According to the process the feedstock containing hydrocarbons is fed to a catalytic distillation reactor system, in which the isoolefines, in particular the C.sub.4 to C.sub.7 isoolefines, of the feed are reacted with an alkanol in the presence of a cation exchange resin in order to produce tertiary alkyl ether products. The reaction product containing the ethers is removed from the distillation system as the bottoms product and, if necessary, it is subjected to an additional treatment for producing a gasoline component. The unreacted alkanol is removed as the overhead product of the distillation. According to the invention, the distillate withdrawn mainly contains an azeotrope of C.sub.4 hydrocarbons and alkanol, the C.sub.4 amount of which at least approximately corresponds to the C.sub.4 hydrocarbon concentration of the hydrocarbon feed, a substantial amount of the unreacted alkanol being removed in the form of said azeotrope. By means of the invention the need for a separate alkanol washing unit is eliminated in the apparatus which considerably reduces apparatus investment costs.
摘要翻译： 本发明涉及一种制备叔烷基醚的方法。 根据该方法，将含有烃的原料进料到催化蒸馏反应器系统中，其中进料的异烯烃，特别是C4至C7异烯烃在阳离子交换树脂的存在下与烷醇反应，以产生 叔烷基醚产物。 含有醚的反应产物作为塔底产物从蒸馏系统中除去，如果需要，将其进行额外处理以生产汽油组分。 将未反应的链烷醇作为蒸馏塔顶产物除去。 根据本发明，取出的馏出物主要含有C 4烃和链烷醇的共沸物，其C4量至少近似对应于烃进料的C 4烃浓度，大量未反应的链烷醇以 说共沸物。 通过本发明，在装置中消除了对单独的烷醇洗涤单元的需求，这大大降低了设备的投资成本。
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公开(公告)号：US5852220A
公开(公告)日：1998-12-22
申请号：US771417
申请日：1996-12-20
申请人： Harri Jarvelin , Petri Lindqvist , Esa Tamminen
发明人： Harri Jarvelin , Petri Lindqvist , Esa Tamminen
CPC分类号： C07C41/06
摘要： A process for producing tertiary alkyl ethers by reacting an olefinic hydrocarbon feedstock, which contains a mixture of reactive C.sub.4 -C.sub.7 isoolefins, with an alkanol in the presence of a catalyst that will enhance the reaction between the isoolefins and the alkanol. By adjusting the weight ratio of the isobutylene to the reactive C.sub.6 isoolefins of the feed to a value of about 0.2 to 10, it is possible to increase the conversion of reactive C.sub.4 's to over 95%, of reactive C.sub.5 's to over 85% and of reactive C.sub.6 's to over 57%.
摘要翻译： 在催化剂存在下，使含有活性C4-C7异烯烃的混合物的烯烃原料与烷醇反应生成叔烷基醚的方法，该催化剂将增强异烯烃和链烷醇之间的反应。 通过将异丁烯与进料的活性C 6异烯烃的重量比调节至约0.2至10的值，可以将反应性C4的转化率增加至超过95％，反应性C5的转化率超过85％，反应性 C6超过57％。
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公开(公告)号：US20110308932A1
公开(公告)日：2011-12-22
申请号：US13162601
申请日：2011-06-17
申请人： Esa Tamminen , Matti Happonen , Ulla Happonen , Simo Jortikka , Martti Ruskoaho
发明人： Esa Tamminen , Matti Happonen , Ulla Happonen , Simo Jortikka , Martti Ruskoaho
CPC分类号： B01D3/008 , B01D1/06 , B01D3/06 , B01D3/14 , B01D3/20 , B01D3/32 , B01D19/0036 , B01D19/0063 , B01D19/0094
摘要： The present invention relates to a feed distribution device in separation columns and a method of operation. In particular it relates to distillation columns in which the feed stream is substantially liquid phase, or a mixture of gas and liquid upstream of the column, but where the feed vaporizes or vaporizes more when it enters the column. More specifically, the feed distribution device contains a plurality of opening which allow the feed to vaporize inside the column and where the openings are maintained in critical condition during operation. Significant advantage is achieved through the implementation and use of the present feed distribution device.
摘要翻译： 本发明涉及分离塔中的进料分配装置和操作方法。 特别地，其涉及其中进料流基本上为液相的蒸馏塔，或塔的上游的气体和液体的混合物，但是当进料进入塔时进料蒸发或蒸发更多的蒸馏塔。 更具体地，进料分配装置包含多个开口，其允许进料在塔内蒸发，并且其中开口在操作期间保持在临界状态。 通过实施和使用本发明的饲料分配装置可以实现显着的优点。
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公开(公告)号：US08926799B2
公开(公告)日：2015-01-06
申请号：US13169155
申请日：2011-06-27
申请人： Esa Tamminen
发明人： Esa Tamminen
CPC分类号： B01D1/06 , B01D3/008 , B01D3/06 , B01D3/14 , B01D3/32 , B01D19/0036 , B01D19/0063 , B01D19/0094
摘要： A feed distribution device in separation columns and a method of operation for such a device. In particular, distillation columns in which the feed stream is substantially liquid phase, or a mixture of gas and liquid upstream of the column, but where the feed vaporizes or partially vaporizes prior to or as it enters the column. More specifically, the feed distribution device contains a plurality of opening which allow the feed to vaporize prior to or as it enters the column and where the openings are maintained in critical condition during operation. Significant advantage is achieved through the implementation and use of the present feed distribution devices.
摘要翻译： 分离柱中的进料分配装置和这种装置的操作方法。 特别地，其中进料流基本上为液相的蒸馏塔，或塔的上游的气体和液体的混合物，但是进料在其进入塔之前或进入塔时蒸发或部分蒸发。 更具体地，进料分配装置包含多个开口，其允许进料在其进入塔之前或进入塔时蒸发，并且其中开口在操作期间保持在临界状态。 通过实施和使用本发明的馈送分配装置可以实现显着的优点。
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公开(公告)号：US20110308931A1
公开(公告)日：2011-12-22
申请号：US13169155
申请日：2011-06-27
申请人： Esa Tamminen
发明人： Esa Tamminen
IPC分类号： B01D3/06
CPC分类号： B01D1/06 , B01D3/008 , B01D3/06 , B01D3/14 , B01D3/32 , B01D19/0036 , B01D19/0063 , B01D19/0094
摘要： The present invention relates to a feed distribution device in separation columns and a method of operation. In particular it relates to distillation columns in which the feed stream is substantially liquid phase, or a mixture of gas and liquid upstream of the column, but where the feed vaporizes or vaporizes prior to or as it enters the column. More specifically, the feed distribution device contains a plurality of opening which allow the feed to vaporize prior to or as it enters the column and where the openings are maintained in critical condition during operation. Significant advantage is achieved through the implementation and use of the present feed distribution devices.
摘要翻译： 本发明涉及分离塔中的进料分配装置和操作方法。 特别地，其涉及其中进料流基本上为液相的蒸馏塔，或塔的上游的气体和液体的混合物，但是进料在其进入塔之前或进入塔时蒸发或蒸发。 更具体地，进料分配装置包含多个开口，其允许进料在其进入塔之前或进入塔时蒸发，并且其中开口在操作期间保持在临界状态。 通过实施和使用本发明的馈送分配装置可以实现显着的优点。
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公开(公告)号：US20110259728A1
公开(公告)日：2011-10-27
申请号：US13083640
申请日：2011-04-11
申请人： Esa Tamminen , Jari Sutinen
发明人： Esa Tamminen , Jari Sutinen
IPC分类号： B01D3/10
CPC分类号： B01D3/008 , B01D45/08 , B01D53/185
摘要： A separation column containing a feed distribution device and a feed distribution device for a separation column, such as a vacuum distillation column. The feed distribution device being capable of diffusing and directing a feed flow from a feed inlet so as to distribute the feed substantially evenly over the surface area of a separation plate in the column thereby increasing the columns efficiency. The separation column containing the feed distribution device being capable of shorter height, less costly design and lower operating cost than a separation column without the feed distribution device.
摘要翻译： 一种分离柱，其包含用于分离塔的进料分配装置和进料分配装置，例如真空蒸馏塔。 进料分配装置能够使来自进料入口的进料流扩散并引导，使得进料基本上均匀地分布在塔中的分离板的表面区域上，从而提高柱效率。 含有进料分配装置的分离塔能够具有比没有进料分配装置的分离塔更短的高度，更便宜的设计和更低的操作成本。
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公开(公告)号：US06369280B1
公开(公告)日：2002-04-09
申请号：US09640893
申请日：2000-08-17
申请人： Esa Tamminen , Petri Lindqvist
发明人： Esa Tamminen , Petri Lindqvist
IPC分类号： C07C4100
CPC分类号： C07C41/42 , B01D3/009 , C07C41/06 , C10L1/023 , Y02P20/127 , C07C43/046
摘要： The invention relates to a process for preparing tertiary alkyl ethers, in particular MTBE, ETBE or mixtures of these ethers with heavier ethers. According to the process the feedstock containing hydrocarbons is fed to a catalytic distillation reactor system, in which the isoolefines, in particular the C4 to C7 isoolefines, of the feed are reacted with an alkanol in the presence of a cation exchange resin in order to produce tertiary alkyl ether products. The reaction product containing the ethers is removed from the distillation system as the bottoms product and, if necessary, it is subjected to an additional treatment for producing a gasoline component. The unreacted alkanol is removed as the overhead product of the distillation. According to the invention, the distillate withdrawn mainly contains an azeotrope of C3 hydrocarbons and alkanol, the C3 amount of which at least approximately corresponds to the C3 hydrocarbon concentration of the hydrocarbon feed, a substantial amount of the unreacted alkanol being removed in the form of said azeotrope. By means of the invention the need for a separate alkanol washing unit is eliminated in the apparatus which considerably reduces apparatus investment costs.
摘要翻译： 本发明涉及一种制备叔烷基醚，特别是MTBE，ETBE或这些醚与较重醚的混合物的方法。 根据该方法，将含有烃的原料进料到催化蒸馏反应器系统中，其中进料的异烯烃，特别是C4至C7异烯烃在阳离子交换树脂的存在下与烷醇反应，以产生 叔烷基醚产物。 含有醚的反应产物作为塔底产物从蒸馏系统中除去，如果需要，将其进行额外处理以生产汽油组分。 将未反应的链烷醇作为蒸馏塔顶产物除去。 根据本发明，取出的馏出物主要含有C 3烃和链烷醇的共沸物，其C3量至少大约对应于烃进料的C 3烃浓度，大量未反应的链烷醇以 说共沸物。 通过本发明，在装置中消除了对单独的烷醇洗涤单元的需求，这大大降低了设备的投资成本。
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公开(公告)号：US08974640B2
公开(公告)日：2015-03-10
申请号：US13162601
申请日：2011-06-17
申请人： Esa Tamminen , Simo Jortikka , Martti Ruskoaho , Ulla Happonen
发明人： Esa Tamminen , Matti Happonen , Simo Jortikka , Martti Ruskoaho
CPC分类号： B01D3/008 , B01D1/06 , B01D3/06 , B01D3/14 , B01D3/20 , B01D3/32 , B01D19/0036 , B01D19/0063 , B01D19/0094
摘要： The present invention relates to a feed distribution device in separation columns and a method of operation. In particular it relates to distillation columns in which the feed stream is substantially liquid phase, or a mixture of gas and liquid upstream of the column, but where the feed vaporizes or vaporizes more when it enters the column. More specifically, the feed distribution device contains a plurality of opening which allow the feed to vaporize inside the column and where the openings are maintained in critical condition during operation. Significant advantage is achieved through the implementation and use of the present feed distribution device.
摘要翻译： 本发明涉及分离塔中的进料分配装置和操作方法。 特别地，其涉及其中进料流基本上为液相的蒸馏塔，或塔的上游的气体和液体的混合物，但是当进料进入塔时进料蒸发或蒸发更多的蒸馏塔。 更具体地，进料分配装置包含多个开口，其允许进料在塔内蒸发，并且其中开口在操作期间保持在临界状态。 通过实施和使用本发明的饲料分配装置可以实现显着的优点。
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公开(公告)号：US08888076B2
公开(公告)日：2014-11-18
申请号：US13083640
申请日：2011-04-11
申请人： Esa Tamminen , Jari Sutinen
发明人： Esa Tamminen , Jari Sutinen
CPC分类号： B01D3/008 , B01D45/08 , B01D53/185
摘要： A separation column containing a feed distribution device and a feed distribution device for a separation column, such as a vacuum distillation column. The feed distribution device being capable of diffusing and directing a feed flow from a feed inlet so as to distribute the feed substantially evenly over the surface area of a separation plate in the column thereby increasing the columns efficiency. The separation column containing the feed distribution device being capable of shorter height, less costly design and lower operating cost than a separation column without the feed distribution device.
摘要翻译： 一种分离柱，其包含用于分离塔的进料分配装置和进料分配装置，例如真空蒸馏塔。 进料分配装置能够使来自进料入口的进料流扩散并引导，使得进料基本上均匀地分布在塔中的分离板的表面区域上，从而提高柱效率。 含有进料分配装置的分离塔能够具有比没有进料分配装置的分离塔更短的高度，更便宜的设计和更低的操作成本。
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