摘要:
The invention relates to a network, in particular a PA PROFIBUS network having redundant properties and a linear topology. Two line ends are connected to a redundancy manager which disconnects said line ends in error-free conditions and connects them in error conditions. Said redundancy manager supplies voltage to the first line end for operating customers' mobile telephones each of which is connected to the network by a branching unit. After receiving a supply voltage on one connection thereof, said branching units check the state of a cable which is connected to the other network connection and transmit the supply voltage in the faultless condition thereof only. When the redundancy manager does not detect the supply voltage on the other end of the line end at least during a predetermined space of time after voltage supply, said redundancy manager supplies the voltage thereto. A cable having a disturbance is then disconnected from the line by the adjacent branching units.
摘要:
Alkylsulfonic acids are prepared by oxidation of an alkyl mercaptan or dialkyl disulfide with hydrogen peroxide in an alkylsulfonic acid in the absence of percarboxylic acids and preferably employing 1 to 35 mole % of alkylsulfonic acid based on the alkyl mercaptan or dialkyl disulfide employed.
摘要:
Cyanogen chloride and hydrogen chloride are produced by reacting hydrogen cyanide and chlorine, separating from the gaseous mixture on the one hand hydrogen chloride and on the other hand cyanogen chloride which in a given case can also contain chlorine, by absorption in a halohydrocarbon which has a boiling point between that of cyanogen chloride and cyanuric chloride and after distillative separation of the dissolved cyanogen chloride-chlorine mixture returning the solvent to the absorption column, the process includesA. adding as the solvent for the absorption a trifluoromethyl substituted aromatic hydrocarbon or halohydrocarbon or a mixture of such trifluoromethyl substituted aromatic hydrocarbons or halohydrocarbons,B. subjecting the gas mixture consisting of cyanogen chloride, hydrogen chloride and in a given case chlorine after leaving the reactor for the chlorination of hydrogen cyanide and before entrance into the absorption column to a pretreatment with the solvents set forth under (a) at a temperature between 80.degree.C. and the boiling point of the solvent and/orC. either converting the N-chloro-chloroformimide chloride formed in small amounts from the chlorine and cyanogen chloride in the course of the absorption and distillation into the insoluble chloroformimide chloride hydrochloride by gassing the solvent with hydrogen chloride and separating the insoluble hydrochloride in conventional manner and/or withdrawing the N-chloro-chloroformimide together with some cyanogen chloride and solvent of the previously named distillation column for separation of the cyanogen chloride by means of a side outlet, and in a second subsequently provided distillation column separating into solvent and pure N-chloro-chloroformimide chloride, whereby then the latter can be conducted both into the cyanogen chloride reactor and also, if connected to a plant for the production of cyanuric chloride, into the trimerization reactor for cyanogen chloride and/orD. subjecting the solvent contaminated with byproducts by the suspension resulting from the pretreatment and/or accumulating in the sump of the distillation column for the separation of the cyanogen chloride completely or in a partial stream to an aqueous alkaline treatment or in combination with a cyanuric chloride condensation plant leading the suspension formed in the pretreatment to the cyanuric chloride condensation column.
摘要:
Cyanogen chloride is purified and the service life of activated carbon is increased in the subsequent trimerization of the cyanogen chloride to cyanuric chloride by process comprising reacting hydrogen cyanide with chlorine, in a given case in the presence of cyanogen chloride produced in the presence of water, which in a given case contains chlorine. The improvement comprises passing the cyanogen chloride over granular commercial sodium aluminum silicate or a molecular sieve of the mordenite type, at 20.degree.-100.degree.C., preferably 30.degree.-60.degree.C.
摘要:
The invention is directed to a process for the hydrolysis of 5-(.beta.-methylmercaptoethyl)-hydantoin by reaction at elevated temperature and pressure in an aqueous alkaline medium. There are obtained alkali methioninate solutions from which there can be separated methionine.
摘要:
Aqueous sodium methioninate solutions having a low content of sodium carbonate can be recovered from the crude hydrolysis mixture resulting from the saponification of 5-(.beta.-methylmercaptoethyl)-hydantoin with 1.1 to 6 equivalents of sodium hydroxide and/or sodium carbonate by distilling off the water from the crude hydrolysis mixture until the sodium methioninate content is 40 to 65 weight percent, and after cooling to at most room temperature separating off the precipitated sodium carbonate.
摘要:
The invention relates to a network, in particular a PA PROFIBUS network having redundant properties and a linear topology. Two line ends are connected to a redundancy manager which disconnects said line ends in error-free conditions and connects them in error conditions. Said redundancy manager supplies voltage to the first line end for operating customers' mobile telephones each of which is connected to the network by a branching unit. After receiving a supply voltage on one connection thereof, said branching units check the state of a cable which is connected to the other network connection and transmit the supply voltage in the faultless condition thereof only. When the redundancy manager does not detect the supply voltage on the other end of the line end at least during a predetermined space of time after voltage supply, said redundancy manager supplies the voltage thereto. A cable having a disturbance is then disconnected from the line by the adjacent branching units.
摘要:
Aqueous sodium methioninate solutions having a low content of sodium carbonate can be recovered from the crude hydrolysis mixture resulting from the saponification of 5-(.beta.-methylmercaptoethyl)hydantoin with 1.1 to 6 equivalents of sodium hydroxide and/or sodium carbonate by cooling the crude hydrolysis mixture to a temperature below 10.degree. C., separating off the precipitated sodium carbonate and concentrating the sodium methioninate solution remaining to 40 to 65 weight percent.
摘要:
Alkylsulfonic acids are prepared by oxidation of an alkyl mercaptan or dialkyl disulfide with hydrogen peroxide in an inert medium in the presence of ammonium or alkali molybdate or ammonium or alkali tungstate.
摘要:
Side reactions in the use of gaseous chlorine are avoided by leading the chlorine containing at least 0.0001% of non-volatile compounds such as ferric chloride over silica gel, glass wool, pumice or montmorillonite. Preferably the thus treated chlorine is passed through hexachlorobutadiene or perfluorokerosene in a second absorption step. Ferric chloride can also be removed from the chlorine gas by treating with sulfuric acid.