公开(公告)号：US20080090974A1

公开(公告)日：2008-04-17

申请号：US11954273

申请日：2007-12-12

申请人： Patrick Brant ,  Kiss Gabor ,  Chris Friedersdorf ,  James Lattner ,  Gary Casty

发明人： Patrick Brant ,  Kiss Gabor ,  Chris Friedersdorf ,  James Lattner ,  Gary Casty

IPC分类号： C08F4/16 ,  C08F2/01 ,  C08F2/04

CPC分类号： C08F10/06 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F2/14 ,  C08F2/00 ,  C08F2/06 ,  C08F2500/15 ,  C08F2500/20 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/01 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/23 ,  C08F210/14 ,  C08F4/64144

摘要： This invention relates to a process to polymerize olefins comprising contacting propylene, at a temperature of 65° C. to 150° C. and a pressure of 1.72 to 34.5 MPa, with: 1) a catalyst system comprising one or more activators and one or more nonmetallocene metal-centered, heteroaryl ligand catalyst compounds, where the metal is chosen from the Group 4, 5, 6, the lanthanide series, or the actinide series of the Periodic Table of the Elements, 2) optionally one or more comonomers selected from ethylene and C4 to C12 olefins, 3) diluent or solvent, and 4) optionally scavenger, wherein: a) the olefin monomers and any comonomers are present in the polymerization system at 30 wt % or more, b) the propylene is present in the feed at 80 wt % or more, c) the polymerization occurs at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure greater than 1 MPa below the cloud point pressure of the polymerization system, and d) the polymerization occurs: (1) at a temperature below the critical temperature of the polymerization system, or (preferably and) (2) at a pressure below the critical pressure of the polymerization system.

摘要翻译： 本发明涉及聚合烯烃的方法，包括使丙烯在65℃至150℃的温度和1.72至34.5MPa的压力下接触，其中：1）包含一种或多种活化剂和一种或多种活化剂的催化剂体系 更多的非金属茂金属中心的杂芳基配位体催化剂化合物，其中金属选自第4,5,6族，镧系元素或元素周期表的锕系列，2）任选的一种或多种共聚单体，其选自 乙烯和C 4至C 12烯烃，3）稀释剂或溶剂，和4）任选的清除剂，其中：a）烯烃单体和任何共聚单体在聚合体系中以30重量％或更多存在，b）丙烯存在于 进料为80重量％以上，c）在高于聚合体系的固体 - 流体相转变温度的温度和低于聚合体系浊点压力1MPa的压力下进行聚合，和d）聚合反应 n发生：（1）在低于聚合体系临界温度的温度下，或（优选和）（2）在低于聚合体系临界压力的压力下。

公开(公告)号：US20060166809A1

公开(公告)日：2006-07-27

申请号：US10534072

申请日：2003-11-18

申请人： Andrzej Malek ,  James Vartuli ,  Stuart Soled ,  Sabato Miseo ,  Jennifer Feeley ,  Gary Casty ,  Gabor Kiss ,  Jeffrey Dysard ,  Joseph Baumgartner ,  Christine Kliewer ,  Steven Ragomo

发明人： Andrzej Malek ,  James Vartuli ,  Stuart Soled ,  Sabato Miseo ,  Jennifer Feeley ,  Gary Casty ,  Gabor Kiss ,  Jeffrey Dysard ,  Joseph Baumgartner ,  Christine Kliewer ,  Steven Ragomo

IPC分类号： B01J38/00 ,  B01J21/08 ,  B01J20/10 ,  B01J20/00 ,  B01J27/28 ,  B01J21/12

CPC分类号： C10G2/331 ,  B01J20/02 ,  B01J20/08 ,  B01J20/103 ,  B01J20/223 ,  B01J20/3204 ,  B01J20/3236 ,  B01J23/462 ,  B01J23/75 ,  B01J23/8896 ,  B01J37/0203 ,  B01J37/08 ,  B01J37/082 ,  C07C7/12 ,  C10G25/003 ,  C10G29/04

摘要： The present invention is directed to processes for preparing supported metal catalysts comprising one or more catalytically active metals applied to a porous catalyst support and to processes that use such catalysts. The process requires the formation of an organic complex during the manufacture of the catalyst which after its formation is either partially or fully decomposed before reduction if the metal to form the catalyst. The catalysts have high levels of metal dispersion and uniform distribution of catalytically active metals on the support. The catalysts obtained form the processes are particularly effective in catalysing Fischer-Tropsch reactions and as adsorbants for the removal or organosulfur compounds from hydrocarbons.

公开(公告)号：US20070055028A1

公开(公告)日：2007-03-08

申请号：US11514007

申请日：2006-08-31

申请人： Gary Casty ,  Evan Piland

发明人： Gary Casty ,  Evan Piland

IPC分类号： C08F4/44

CPC分类号： B01J31/143 ,  B01J31/02 ,  B01J31/1608 ,  B01J31/2295 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/14 ,  C08F2500/03

摘要： A process for polymerizing propylene is provided. The process comprises contacting propylene and optionally one or more monomers with a catalyst system comprising a bis-indenyl Group 4 metallocene compound supported on silica, the silica treated with one or more organoaluminum compounds and one or more heterocyclic compounds, under slurry conditions in the presence of hydrogen at a temperature of about 50° C. to about 160° C. and a pressure of from about 3 MPa to about 5 MPa to provide a catalyst activity of greater than 30,000 pounds of product per pound of catalyst; and then recovering isotactic polypropylene having a melt flow rate of 20 dg/min or less as measured according to ASTM D-1238 at 230° C. and 2.16 kg.

摘要翻译： 提供聚合丙烯的方法。 该方法包括使丙烯和任选的一种或多种单体与催化剂体系接触，所述催化剂体系包含负载在二氧化硅上的双茚基基团4金属茂化合物，在一定条件下，在一定条件下，在一种或多种有机铝化合物和一种或多种杂环化合物 的氢气在约50℃至约160℃的温度和约3MPa至约5MPa的压力下提供大于30,000磅每磅催化剂的产物的催化剂活性; 然后回收根据ASTM D-1238在230℃和2.16kg下测量的熔体流动速率为20dg / min或更低的全同立构聚丙烯。

公开(公告)号：US20050148743A1

公开(公告)日：2005-07-07

申请号：US10753153

申请日：2004-01-07

申请人： Gary Casty ,  Smita Kacker ,  Jack Johnson ,  Murielle Scott ,  Steven Hegwood ,  Robert Simpson ,  Robert Reynolds

发明人： Gary Casty ,  Smita Kacker ,  Jack Johnson ,  Murielle Scott ,  Steven Hegwood ,  Robert Simpson ,  Robert Reynolds

IPC分类号： B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  B01J31/16 ,  B01J31/22 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F4/44 ,  B01J31/00

CPC分类号： C08F10/00 ,  B01J31/02 ,  B01J31/143 ,  B01J31/1608 ,  B01J31/2295 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65927 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/14 ,  C08F2500/03

摘要： This invention relates to supported activators comprising the product of the combination of an ion-exchange layered silicate, an organoaluminum compound, and a heterocyclic compound, which may be substituted or unsubstituted. This invention further relates to catalyst systems comprising catalyst compounds and such activators, as well as processes to polymerize unsaturated monomers using the supported activators. For the purposes of this patent specification and the claims thereto, the term “activator” is used interchangeably with the term “co-catalyst”, the term “catalyst” refers to a metal compound that when combined with an activator polymerizes olefins, and the term “catalyst system” refers to the combination of a catalyst and an activator with or without a support. The terms “support” or “carrier”, for purposes of this patent specification, are used interchangeably and are any ion-exchange layered silicates.

摘要翻译： 本发明涉及负载的活化剂，其包括可以是取代或未取代的离子交换层状硅酸盐，有机铝化合物和杂环化合物的组合的产物。 本发明还涉及包含催化剂化合物和这种活化剂的催化剂体系，以及使用负载的活化剂聚合不饱和单体的方法。 为了本专利说明书及其权利要求的目的，术语“活化剂”可与术语“助催化剂”互换使用，术语“催化剂”是指当与活化剂组合时使烯烃聚合的金属化合物， 术语“催化剂体系”是指催化剂和具有或不具有载体的活化剂的组合。 为了本专利说明书的目的，术语“支持”或“载体”可互换使用，并且是任何离子交换层状硅酸盐。