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1.发明授权
公开(公告)号：US4357472A
公开(公告)日：1982-11-02
申请号：US219172
申请日：1980-12-22
申请人： Georg Grigoleit , Kurt Matern , Helmut Kohler , Gerd Collin
发明人： Georg Grigoleit , Kurt Matern , Helmut Kohler , Gerd Collin
IPC分类号： C07C319/02 , C07C321/06 , C07D333/54
CPC分类号： C07D333/54
摘要： A process for the production of thionaphthene by dissociation of thionaphthene sulfonic acid such as obtained, for example, in the partial sulfonation of naphthalene fractions of coal tar, characterized in that the density of the reaction mixture is maintained essentially constant during the entire duration of the dissociation reaction and the thionaphthene formed is not removed by azeotropic distillation; a product of high purity is obtained in high yield in a substantially reduced reaction time.
摘要翻译： 通过例如在煤焦油的萘馏分的部分磺化中获得的硫萘磺酸的解离来生产硫茚的方法，其特征在于反应混合物的密度在整个持续时间内保持基本上恒定 解离反应和形成的硫代没有通过共沸蒸馏除去; 在显着降低的反应时间内以高产率获得高纯度的产物。
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公开(公告)号：US3704331A
公开(公告)日：1972-11-28
申请号：US3704331D
申请日：1970-12-15
CPC分类号： C10G7/00
摘要： OILS RICH IN AROMATIC SUBSTANCES OR RESIDUES FROM THE PYROLYSIS OF GASOLINE OR SIMILAR HYDROCARBON MIXTURES ARE USED FOR THE PRODUCTION OF ANTHRACENE THROUGH ENRICHMENT BY DISTILLATION AND RECRYSTALLIZATION FROM AN ARYLALKYL-KETONE, PREFERABLY ACETOPHENONE.
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公开(公告)号：US4414192A
公开(公告)日：1983-11-08
申请号：US415636
申请日：1982-09-07
申请人： Jurgen Palm , Herbert Glaser , Gerd Collin , Rolf Marrett , Maximilian Zander
发明人： Jurgen Palm , Herbert Glaser , Gerd Collin , Rolf Marrett , Maximilian Zander
摘要： A method of producing a highly reactive pitch fraction is disclosed. Coal-tar pitch is extracted with hot chloroform and the pitch solution treated with solid iodine. The solid reaction products are separated and, in the presence of chloroform, decomposed with an aqueous ammonia solution. Following separation of the aqueous phase and removal by distillation of the chloroform, there remains a highly reactive pitch fraction which can be converted into high-anisotropic carbon at low temperatures and in short coking times.
摘要翻译： 公开了一种制备高反应性沥青分数的方法。 煤焦油沥青用热氯仿萃取，沥青溶液用固体碘处理。 将固体反应产物分离，并在氯仿的存在下用氨水溶液分解。 在分离水相并通过氯仿蒸馏除去后，仍然存在高反应性沥青分数，其可在低温和短焦化时间转化为高各向异性碳。
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公开(公告)号：US4379133A
公开(公告)日：1983-04-05
申请号：US275290
申请日：1981-06-19
摘要： An improved process for treating coal tar pitch to form anisotropic carbon comprising treating coal tar pitch with picric acid, recovering the resulting picrates, decomposing the picrates and heating the resulting aromatic hydrocarbons to obtain anisotropic carbon in less time.
摘要翻译： 一种用于处理煤焦油沥青以形成各向异性碳的改进方法，包括用苦味酸处理煤焦油沥青，回收所得苦味酸盐，分解苦味酸盐并加热得到的芳族烃以在较短的时间内获得各向异性碳。
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公开(公告)号：US3991074A
公开(公告)日：1976-11-09
申请号：US524290
申请日：1974-11-15
申请人： Georg Grigoleit , Gerd Collin , Rudolf Oberkobusch
发明人： Georg Grigoleit , Gerd Collin , Rudolf Oberkobusch
IPC分类号： C07D209/08 , C07D209/10
CPC分类号： C07D209/08
摘要： A process for the catalytic conversion of o-ethylaniline to indole in a gaseous phase and in the presence of hydrogen or steam and an SiO.sub.2 -containing catalyst modified by chromium dioxide and copper, wherein said conversion is conducted at about 400.degree. - 700.degree. C.; said catalyst comprising at least about 15% by weight copper and at least about 8% by weight of a chromate of a metal of Group IIA of the Periodic Table. A catalyst for use in the invention is provided.
摘要翻译： 一种在气相和氢气或蒸汽以及由二氧化铬和铜改性的含SiO 2催化剂存在下催化转化邻乙基苯胺至吲哚的方法，其中所述转化在约400-700℃下进行 。 所述催化剂包含至少约15重量％的铜和至少约8重量％的元素周期表IIA族金属的铬酸盐。 提供了用于本发明的催化剂。
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公开(公告)号：US4902492A
公开(公告)日：1990-02-20
申请号：US258394
申请日：1988-10-17
CPC分类号： D01F9/15
摘要： In a process for the production of carbon fibers from high boiling bituminous substances in which a purified and polymerized concentrated carbon fiber precursor is spun into fibers which are oxidized and then carbonized and optionally graphitized, the improvement comprising adding to the carbon fiber precursor just before spinning 2 to 10% by weight of a solvent in which the precursor is insoluble or only slightly soluble under normal conditions and mixing the resulting mixture under hypercritical conditions for the solvent for at least 10 minutes without gas or solid inclusions formed in the fiber and neoformatgion of solids is prevented.
摘要翻译： 在由高沸点沥青物质生产碳纤维的方法中，其中纯化和聚合的浓缩碳纤维前体被纺丝成被氧化然后碳化并任选石墨化的纤维，其改进包括在旋转之前向碳纤维前体添加 2至10重量％的溶剂，其中前体在正常条件下不溶或仅微溶，并将所得混合物在超临界条件下混合至溶剂至少10分钟，而不会在纤维中形成气体或固体夹杂物， 防止了固体。
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公开(公告)号：US4795847A
公开(公告)日：1989-01-03
申请号：US151697
申请日：1988-02-02
申请人： Jens Weitkamp , Marita Neuber , Wilhelm Holtmann , Gerd Collin , Hans Spengler
发明人： Jens Weitkamp , Marita Neuber , Wilhelm Holtmann , Gerd Collin , Hans Spengler
IPC分类号： B01J29/06 , B01J29/40 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/86 , C07C15/24 , C07C67/00 , C07C2/68
CPC分类号： C07C2/66 , B01J29/40 , C07C2/864 , C07C2529/40
摘要： A process for the preparation of 2,6-dialkyl-naphthalenes comprising selectively alkylating naphthalene or 2-alkyl-naphthalene with alkylating agent in the presence of a zeolite catalyst at 250.degree. to 345.degree. C. which dialkyl-naphthalenes are useful for the preparation of naphthalene 2,6-dicarboxylic acid used to produce high-quality polyesters or polyamides.
摘要翻译： 一种制备2,6-二烷基萘的方法，包括在250至345℃的沸石催化剂存在下，用烷基化剂选择性地烷基化萘或2-烷基萘，该二烷基萘可用于制备 用于生产高品质聚酯或聚酰胺的萘2,6-二羧酸。
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8.发明授权Process for the electrochemical conversion of coal and use of the reaction products 失效煤的电化学转化工艺和反应产物的使用
公开(公告)号：US4430175A
公开(公告)日：1984-02-07
申请号：US449952
申请日：1982-12-15
申请人： Gerhard Kreysa , Gerd Collin
发明人： Gerhard Kreysa , Gerd Collin
摘要： Ground coal is dispersed in an aqueous electrolyte and is alternately oxidized anodically and reduced cathodically. The reaction gases and the liquid hydrocarbons obtained and other volatile organic compounds are processed and used in the customary manner. The reactive groups formed in the coal improve its cokeability, extractability and capacity for hydrogenation. In addition, the treated coal because of its good wettability, suspended in water or alcohol, is well suited as a liquid fuel or motor fuel.
摘要翻译： 地煤分散在水性电解质中，并被阳极氧化交替氧化并阴极还原。 所得到的反应气体和液体烃和其它挥发性有机化合物以常规方式加工和使用。 煤中形成的反应性基团提高其可加工性，萃取性和氢化能力。 另外，处理过的煤由于其良好的润湿性，悬浮在水中或酒精中，非常适合作为液体燃料或汽油。
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公开(公告)号：US4304606A
公开(公告)日：1981-12-08
申请号：US046399
申请日：1979-06-06
CPC分类号： C08L95/00
摘要： This invention relates to a plasticized coal tar pitch comprising a mixture consisting essentially of about 50 to about 80 weight percent of a coal tar pitch having a softening point of about 40.degree. to about 75.degree. C. (Kramer-Sarnow); and about 50 to about 20 weight percent of a coal tar fraction rich in crystals and having a boiling point of about 350.degree. C. to about 450.degree. C. The mixture is suitable for blending with crude oil bitumen for producing a binder suitable for application to roadways.
摘要翻译： 本发明涉及一种增塑煤焦油沥青，其包含基本上由约50至约80重量％的软化点为约40至约75℃的煤焦油沥青（Krämer-Sarnow）组成的混合物; 和约50至约20重量％的富含结晶并且沸点为约350℃至约450℃的煤焦油馏分。该混合物适于与原油沥青共混以生产适合于应用的粘合剂 到道路。
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10.发明授权Process for the separation of quinoline-insoluble components from coal tar pitch 失效喹啉不溶性成分与煤焦油沥青分离的方法
公开(公告)号：US4259171A
公开(公告)日：1981-03-31
申请号：US15985
申请日：1979-02-28
申请人： Jurgen Stadelhofer , Gerd Collin
发明人： Jurgen Stadelhofer , Gerd Collin
CPC分类号： C10C1/18
摘要： Quinoline-insoluble components are separated from coal tar pitch by treating the coal tar pitch which has a softening point of greater than 60.degree. C. (according to the method of Kraemer-Sarnow) with a solvent mixture comprising at least one solvent with paraffinic characteristics and at least one tar solvent, wherein the treatment is carried out at a temperature in the range of 200.degree. to 270.degree. C.
摘要翻译： 通过用包含至少一种具有石蜡特性的溶剂的溶剂混合物处理软化点大于60℃的煤焦油沥青（根据Kraemer-Sarnow的方法）将喹啉不溶性组分与煤焦油沥青分离 和至少一种焦油溶剂，其中处理在200-270℃的温度下进行。
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