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公开(公告)号：US4207409A
公开(公告)日：1980-06-10
申请号：US952804
申请日：1978-10-19
摘要： In the hydrogenation of polymers or copolymers synthesized from dienes, or containing diene hydrocarbons, which is as a rule carried out in an organic solvent using hydrogen in the presence of conventional complex hydrogenation catalysts based on metals of sub-group 8 of the periodic table of the elements and aluminum trialkyls it is important to have from 0.5 to 50 moles of water present in the hydrogenation zone per mole of the heavy metal component of the catalyst. The hydrogenation time can be substantially reduced by this measure.
摘要翻译： 在由二烯或二烯烃合成的聚合物或共聚物的氢化中，其通常在有机溶剂中使用氢气在常规的基于周期表第8族金属的复合氢化催化剂存在下进行 元素和三烷基铝在加氢区中每摩尔催化剂的重金属组分中存在0.5至50摩尔的水是重要的。 通过这种措施可以显着降低氢化时间。
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公开(公告)号：US4066580A
公开(公告)日：1978-01-03
申请号：US693502
申请日：1976-06-07
CPC分类号： C08G18/4615 , C08G18/2036 , C08G18/4263 , C08G2105/02 , Y10S521/902 , Y10S521/906
摘要： A process for the manufacture of urethane group containing polyisocyanurate foams produced by mixing polyisocyanates and polyols and (if required) frothing agents, auxiliaries and additives in the presence of a co-catalyst system which consists of a 1,3,5-tris(N,N-dialkylaminoalkyl)-s-hexahydrotriazine and an organic mono- or polycarboxylic acid, a polyesterol with an acid number greater than 4 or a mono-ester of polycarboxylic acid.
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3.发明授权Block or graft copolymers of polyalkylene oxides and vinylaromatic or diene polymers 失效聚环氧烷和乙烯基芳族或二烯聚合物的嵌段或接枝共聚物
公开(公告)号：US4029720A
公开(公告)日：1977-06-14
申请号：US555026
申请日：1975-03-03
申请人： Erhard Seiler , Gerhard Fahrbach , Dieter Stein
发明人： Erhard Seiler , Gerhard Fahrbach , Dieter Stein
CPC分类号： D06M15/53 , C08G18/6204 , C08G18/694 , C08G81/025 , D06M15/263
摘要： A process for the manufacture of block or graft copolymers of polyalkylene oxides and vinylaromatic polymers or diene polymers. The block or graft copolymers are manufactured by reacting vinylaromatic polymers or diene polymers bearing methyl methacrylate end groups with polyalkylene oxides bearing alkali metal alcoholate end groups. The block or graft copolymers may be used as antistatic agents for plastics, as coating materials for non-woven webs, as intermediates in the manufacture of polyurethanes and as surfactants, protective colloids or emulsifiers.
摘要翻译： 一种制备聚环氧烷和乙烯基芳族聚合物或二烯聚合物的嵌段或接枝共聚物的方法。 嵌段或接枝共聚物通过使具有甲基丙烯酸甲酯端基的聚乙烯基芳族聚合物或二烯聚合物与具有碱金属醇化物端基的聚环氧烷反应来制备。 嵌段或接枝共聚物可以用作塑料的抗静电剂，作为无纺网的涂料，作为制备聚氨酯和表面活性剂，保护胶体或乳化剂的中间体。
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公开(公告)号：US4724062A
公开(公告)日：1988-02-09
申请号：US899605
申请日：1986-08-25
申请人： Herbert Naarmann , Franz Haaf , Gerhard Fahrbach
发明人： Herbert Naarmann , Franz Haaf , Gerhard Fahrbach
CPC分类号： D01F11/14 , C08G61/123 , D01F11/16
摘要： A layer of electrically conductive polymers is applied by a process in which carbon fibers of filaments or sheet-like structures of carbon fibers or filaments are coated with sulfonic acids of phthalocyanines or porphyrins, the filaments treated in this manner are made the anode in a solution which contains monomers from the class consisting of the 5-membered heterocycles, and the monomers are anodically polymerized so that a conductive layer is formed on the fibers, filaments or sheet-like structures.
摘要翻译： 一层导电聚合物通过其中碳纤维或细丝的碳纤维或纤维的片状结构被酞菁或卟啉的磺酸涂覆的方法施加，以这种方式处理的长丝被制成溶液中的阳极 其包含由5元杂环组成的类别的单体，并且单体被阳极聚合，使得在纤维，长丝或片状结构上形成导电层。
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公开(公告)号：US4282334A
公开(公告)日：1981-08-04
申请号：US97815
申请日：1979-11-27
申请人： Manfred Walter , Dieter Stein , Gerhard Fahrbach , Rudolf Jung , Adolf Echte
发明人： Manfred Walter , Dieter Stein , Gerhard Fahrbach , Rudolf Jung , Adolf Echte
IPC分类号： C08F291/00 , C08F279/02 , C08F291/02
CPC分类号： C08F279/02
摘要： A process for the manufacture of high impact and translucent polystyrene, in which, in a first stage, styrene is prepolymerized in mass or in solution in the presence of a rubber, and the polymerization is then completed in mass, in solution or in aqueous suspension. The prepolymerization is taken to a stage where the amount of styrene converted is from 3 to 10 times the amount of the elastomer constituent of the rubber, and at this conversion the disperse soft-component phase formed should have a mean particle size of less than 1 .mu.m and should contain from 35 to 65% by weight of free or chemically bonded polystyrene segments. The translucent styrene polymers of high impact strength may be used for packaging purposes.
摘要翻译： 用于制造高冲击和半透明聚苯乙烯的方法，其中在第一阶段中，苯乙烯在橡胶存在下以质量或溶液预聚合，然后在溶液或水悬浮液中完成聚合 。 将预聚合物进行到苯乙烯转化量为橡胶的弹性体成分的3〜10倍的阶段，在该转化条件下，形成的分散软组分相的平均粒径应小于1 并且应含有35至65重量％的游离或化学键合的聚苯乙烯段。 具有高冲击强度的半透明苯乙烯聚合物可用于包装目的。
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6.发明授权
公开(公告)号：US4031166A
公开(公告)日：1977-06-21
申请号：US443750
申请日：1974-02-19
申请人： Klaus Bronstert , Gerhard Fahrbach , Eduard Krahe , Volker Ladenberger , Ernst-Guenther Kastning , Hans Mittnacht , Herbert Willersinn , Hans-Georg Trieschmann
发明人： Klaus Bronstert , Gerhard Fahrbach , Eduard Krahe , Volker Ladenberger , Ernst-Guenther Kastning , Hans Mittnacht , Herbert Willersinn , Hans-Georg Trieschmann
摘要： Impact-resistant thermoplastic molding materials prepared from a rigid component and a soft component. The rigid component consists of polystyrene, the soft component consists of a mixture of a polyolefin with a copolymer of a vinylaromatic and a diene hydrocarbon which has been prepared by anionic solution polymerization and which may have been hydrogenated. The molding materials may be used for the production of molded parts for use in domestic appliances, automobiles and refrigerators.
摘要翻译： 由刚性组分和软组分制备的耐冲击热塑性成型材料。 刚性组分由聚苯乙烯组成，软组分由聚烯烃与乙烯基芳族化合物和二烯烃的共聚物的混合物组成，其通过阴离子溶液聚合制备并且可以被氢化。 成型材料可用于生产用于家用电器，汽车和冰箱的模制零件。
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公开(公告)号：US4002703A
公开(公告)日：1977-01-11
申请号：US603857
申请日：1975-08-12
申请人： Gerhard Fahrbach , Erhard Seiler , Dieter Stein
发明人： Gerhard Fahrbach , Erhard Seiler , Dieter Stein
CPC分类号： C08G81/025
摘要： This invention relates to a process for the manufacture of graft copolymers based on methyl methacrylate polymers. The methyl methacrylate polymer is reacted with a high molecular weight organic compound containing at least one alkylene oxide unit having an alkali metal alcoholate end group, during which reaction transesterification occurs to eliminate alkali metal methoxide and cause chain joining. The graft copolymers may be used for the production of shaped articles or coating compositions and as additives, antistatic agents or adhesion promoters for plastics materials.
摘要翻译： 本发明涉及一种制备基于甲基丙烯酸甲酯聚合物的接枝共聚物的方法。 甲基丙烯酸甲酯聚合物与含有至少一个具有碱金属醇化物端基的烯化氧单元的高分子量有机化合物反应，在此期间进行反应酯交换以除去碱金属甲醇盐并引起链接。 接枝共聚物可用于生产成形制品或涂料组合物，以及用作塑料材料的抗静电剂或粘合促进剂的添加剂。
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公开(公告)号：US3933774A
公开(公告)日：1976-01-20
申请号：US453375
申请日：1974-03-21
申请人： Franz Neumayr , Gerhard Fahrbach , Erhard Seiler
发明人： Franz Neumayr , Gerhard Fahrbach , Erhard Seiler
IPC分类号： C08C19/26 , C08F8/42 , C08F236/04 , C08F257/00 , C08F279/02 , C08F210/00 , C08F136/02 , C08F212/00
CPC分类号： C08F279/02 , C08C19/26 , C08F236/04 , C08F257/00 , C08F8/42
摘要： Modified copolymers of vinyl aromatic compounds or diene hydrocarbons with diisopropenylbenzene. They contain at least 0.2% of polymerized units of a group of the general formulaThe copolymers are intermediates in the manufacture of block copolymers and graft copolymers suitable for use as impact-resistant plastics or polymeric antistatic agents.
摘要翻译： 乙烯基芳族化合物或二烯烃与二异丙烯基苯的改性共聚物。 它们含有至少0.2％的通式基团的聚合单元。该共聚物是制备适合用作抗冲击塑料或聚合抗静电剂的嵌段共聚物和接枝共聚物的中间体。
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9.发明授权公开(公告)号：US06629653B2
公开(公告)日：2003-10-07
申请号：US09147185
申请日：1999-02-19
IPC分类号： B02C1702
CPC分类号： B03B1/00 , B02C13/13 , B03B1/04 , B07B1/20 , B29B17/02 , B29B2017/0251 , B29K2021/00 , B29K2023/06 , B29K2023/12 , B29K2025/00 , B29K2027/06 , B29K2055/02 , B29K2067/00 , B29K2711/12 , Y02W30/622 , Y02W30/68
摘要： The invention relates to a process for separating tenaciously elastic materials such as plastics and rubber from materials tearing and/or defiberizing under high mechanical stress, particularly paper, and to a device for performing said process. The process is characterized in that the mixture of materials to be separated is subjected to high radial, axial and tangential acceleration forces, whereby a mass flow of shredded fibrous material and a mass flow of substantially unshredded plastics is withdrawn separately. The device for performing the process consists of a screen basket which is cylindrical or preferably polygonal in shape and has borings in its jacket to let the defiberized material pass through, a rotatable driving shaft being arranged coaxially inside the screen basket, with blades being attached to said driving shaft, preferably in rigid connection.
摘要翻译： 本发明涉及一种在高机械应力特别是纸张上分解和/或分解的材料和用于执行所述方法的装置中分离顽固弹性材料如塑料和橡胶的方法。 该方法的特征在于，要分离的材料的混合物经受高的径向，轴向和切向的加速力，由此分开地抽出切碎的纤维材料的质量流量和基本上未加热的塑料的质量流。 用于执行该过程的装置由圆筒形或优选多边形形状的筛篮组成，并且在其护套中具有穿孔以使脱纤维材料通过，可旋转的驱动轴同轴地布置在筛篮内，其中叶片附接到 所述驱动轴优选地刚性连接。
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公开(公告)号：US5969195A
公开(公告)日：1999-10-19
申请号：US76134
申请日：1998-05-12
申请人： Uwe Stabel , Gerhard Fahrbach , Werner Neumann
发明人： Uwe Stabel , Gerhard Fahrbach , Werner Neumann
CPC分类号： C07C29/124 , Y02P20/52
摘要： A process for hydrolyzing alkyl monohalides comprises using activated carbon impregnated with alkali metal hydroxide or alkaline earth metal hydroxide in the presence of water and converting the alkyl monohalides virtually quantitatively into the corresponding alcohols. Apparatus for carrying out the process comprises at least one, preferably two, especially three, reactors (2), especially tubular reactors. The process is also particularly useful for preparing alcohols.
摘要翻译： 用于水解单卤代烷基的方法包括在水存在下使用浸渍有碱金属氢氧化物或碱土金属氢氧化物的活性炭，并将卤代烷基卤化物实际上定量转化为相应的醇。 用于进行该方法的装置包括至少一个，优选两个，特别是三个反应器（2），特别是管式反应器。 该方法对于制备醇也特别有用。
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