公开(公告)号：US08349291B2

公开(公告)日：2013-01-08

申请号：US12821555

申请日：2010-06-23

申请人： Mark A. Miller ,  Jaime G. Moscoso ,  Gregory J. Lewis

发明人： Mark A. Miller ,  Jaime G. Moscoso ,  Gregory J. Lewis

IPC分类号： C01B39/46 ,  C01B39/48

CPC分类号： B01J29/70 ,  C01B39/06 ,  C01B39/48 ,  C10G29/205 ,  C10G45/64 ,  C10G49/08 ,  C10G50/00

摘要： Crystalline microporous zeolites designated calcined UZM-22 and UZM-22HS have been synthesized. The calcined UZM-22 is represented by the empirical formula: M1′mn+Al1-xExSiyOz and UZM-22HS has an empirical formula of: M1an+Al(1-x)ExSiy′Oz″ where M1 and M1′ are exchangeable cations such as lithium or strontium and E is a framework element such as gallium. Both zeolites are obtained from an as synthesized microporous crystalline composition having an empirical formula of: Mmn+RrAl1-xExSiyOz either by calcination for UZM-22 or by various treatments such as ammonium hexafluorosilicate treatment for UZM-22HS.M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium.

摘要翻译： 已经合成了称为煅烧UZM-22和UZM-22HS的结晶微孔沸石。 煅烧的UZM-22由经验式表示：M1'mn + Al1-xExSiyOz，UZM-22HS具有经验式：M1an + Al（1-x）ExSiy'Oz“，其中M1和M1'是可交换阳离子 作为锂或锶，E是诸如镓的骨架元素。 两种沸石均由具有经验式：Mmn + RrAl1-xExSiyOz的合成微孔结晶组合物获得，其通过煅烧UZM-22或通过各种处理如六氟硅酸铵处理用于UZM-22HS。M是碱，碱土 ，或稀土金属如锂和锶，R是单电荷的有机铵阳离子，如胆碱阳离子，E是骨架元素如镓。

公开(公告)号：US08158104B2

公开(公告)日：2012-04-17

申请号：US13172453

申请日：2011-06-29

申请人： Gregory J. Lewis ,  Mark A. Miller ,  Lisa M. Knight

发明人： Gregory J. Lewis ,  Mark A. Miller ,  Lisa M. Knight

IPC分类号： C01B39/48 ,  C01B39/04

CPC分类号： C01B39/48 ,  B01J29/70 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/10 ,  C07C2/12 ,  C07C2/58 ,  C07C2/66 ,  C07C2529/70 ,  C10G29/205 ,  C10G35/095 ,  C10G47/16 ,  C10G73/00 ,  C10G2300/1044 ,  C10G2300/1059 ,  C10G2300/1096 ,  C10G2400/02 ,  C10G2400/30 ,  C07C15/02 ,  C07C9/16

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized designated UZM-7. These zeolites are represented by the empirical formula. Mmn+Rrp+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium, potassium and barium, R is an organoammonium cation such as the choline or the diethyldimethylammonium cation and E is a framework element such as gallium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石，称为UZM-7。 这些沸石由经验公式表示。 Mmn + Rrp + Al（1-x）ExSiyOz其中M为碱金属，碱土金属或稀土金属如锂，钾和钡，R为有机铵阳离子，如胆碱或二乙基二甲基铵阳离子，E为骨架 元素如镓。 这些沸石的特征在于独特的x射线衍射图案和组合物，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US07790133B2

公开(公告)日：2010-09-07

申请号：US11748656

申请日：2007-05-15

申请人： Syed A. Faheem ,  Gregory J. Lewis ,  J.W. Adriaan Sachtler ,  John J. Low ,  David A. Lesch ,  Paul M. Dosek ,  Christopher M. Wolverton ,  Donald J. Siegel ,  Andrea C. Sudik ,  Jun Yang

发明人： Syed A. Faheem ,  Gregory J. Lewis ,  J.W. Adriaan Sachtler ,  John J. Low ,  David A. Lesch ,  Paul M. Dosek ,  Christopher M. Wolverton ,  Donald J. Siegel ,  Andrea C. Sudik ,  Jun Yang

IPC分类号： C01B21/00 ,  C01B21/06 ,  C01B3/02 ,  C01B3/00

CPC分类号： C01B3/0031 ,  C01B3/001 ,  Y02E60/327

摘要： A reversible hydrogen storage composition having an empirical formula of: Li(x+z)NxMgyBzHw where 0.4≦x≦0.8; 0.2≦y≦0.6; 0

摘要翻译： 具有以下经验式的可逆储氢组合物：Li（x + z）NxMgyBzHw其中0.4＆nlE; x＆nlE; 0.8; 0.2＆nlE; y＆nlE; 0.6; 0

公开(公告)号：US07744850B2

公开(公告)日：2010-06-29

申请号：US11462056

申请日：2006-08-03

申请人： Mark A. Miller ,  Jaime G. Moscoso ,  Gregory J. Lewis

发明人： Mark A. Miller ,  Jaime G. Moscoso ,  Gregory J. Lewis

IPC分类号： C01B39/04

CPC分类号： B01J29/70 ,  C01B39/48 ,  C07C2/58 ,  C07C2/66 ,  C07C2529/70 ,  C10G29/205 ,  C10G45/64 ,  C10G50/00 ,  C07C9/16

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium. These zeolites are similar to ZSM-18 but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M是碱金属，碱土金属或稀土金属如锂和锶，R是单一带电的有机铵阳离子，如胆碱阳离子，E是骨架元素， 镓。 这些沸石类似于ZSM-18，但是其特征在于独特的x射线衍射图和组成，并具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US20100160701A1

公开(公告)日：2010-06-24

申请号：US12337723

申请日：2008-12-18

申请人： Mark A. Miller ,  Gregory J. Lewis

发明人： Mark A. Miller ,  Gregory J. Lewis

IPC分类号： C07C2/02 ,  C07C2/24 ,  C07C5/22

CPC分类号： C07C2/12 ,  C07C5/22

摘要： This invention relates to hydrocarbon conversion processes using a new family of crystalline aluminosilicate compositions designated the UZM-27 family. These include the UZM-27 and UZM-27HS which have unique structures. UZM-27 is a microporous composition which has a three-dimensional structure and is obtained by calcining the as synthesized form designated UZM-27P. UZM-27HS is a high silica version of UZM-27 and includes an essentially pure silica version of UZM-27.

摘要翻译： 本发明涉及使用称为UZM-27族的新型结晶硅铝酸盐组合物的烃转化方法。 这些包括具有独特结构的UZM-27和UZM-27HS。 UZM-27是具有三维结构的微孔组合物，通过煅烧为UZM-27P的合成形式获得。 UZM-27HS是UZM-27的高二氧化硅版本，包括基本上纯二氧化硅版本的UZM-27。

公开(公告)号：US20100056837A1

公开(公告)日：2010-03-04

申请号：US12613896

申请日：2009-11-06

申请人： Deng-Yang Jan ,  Mathias P. Koljack ,  John E. Bauer ,  Paula L. Bogdan ,  Gregory J. Lewis ,  Susan C. Koster ,  Michael G. Gatter ,  Jaime G. Moscoso

发明人： Deng-Yang Jan ,  Mathias P. Koljack ,  John E. Bauer ,  Paula L. Bogdan ,  Gregory J. Lewis ,  Susan C. Koster ,  Michael G. Gatter ,  Jaime G. Moscoso

IPC分类号： C07C5/22

CPC分类号： B01J29/06 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/74 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/42 ,  C07C5/2708 ,  C07C2529/74 ,  C10G29/205 ,  C10G45/62 ,  C10G45/64 ,  Y02P20/52 ,  C07C15/08

摘要： A process for isomerizing alkyl aromatic hydrocarbons using a catalyst comprising a zeolite and a platinum group metal component is described. The zeolite comprises a new family of zeolites designated UZM-8HS which are derived from UZM-8 zeolites by treating the UZM-8 with a fluoro-silicate salt, an acid, etc. The UZM-8HS zeolites have unique x-ray diffraction patterns.

摘要翻译： 描述了使用包含沸石和铂族金属组分的催化剂使烷基芳族烃异构化的方法。 该沸石包括通过用氟硅酸盐，酸等处理UZM-8而由UZM-8沸石衍生的新型沸石系列UZM-8HS。UZM-8HS沸石具有独特的X射线衍射图 。

公开(公告)号：US20080170987A1

公开(公告)日：2008-07-17

申请号：US12036893

申请日：2008-02-25

申请人： Gregory J. Lewis ,  Lisa M. Knight ,  Mark A. Miller ,  Stephen T. Wilson

发明人： Gregory J. Lewis ,  Lisa M. Knight ,  Mark A. Miller ,  Stephen T. Wilson

IPC分类号： B01J29/04

CPC分类号： B01J29/06 ,  B01J29/70 ,  C01B39/48

摘要： A series of crystalline layered and microporous compositions have been prepared. Compositions that have a layered structure and are identified as UZM-13, UZM-17 and UZM-19. Upon calcination at a temperature of about 400° C. to about 600° C., these compositions form a microporous crystalline zeolite with a three dimensional framework which has been identified as UZM-25. A process for preparing all these compositions and processes for using these compositions are also disclosed.

摘要翻译： 已经制备了一系列结晶层状和微孔组合物。 具有分层结构并被识别为UZM-13，UZM-17和UZM-19的组合物。 在约400℃至约600℃的温度下煅烧时，这些组合物形成具有三维框架的微孔结晶沸石，其已被鉴定为UZM-25。 还公开了制备所有这些组合物和使用这些组合物的方法的方法。

公开(公告)号：US07344694B2

公开(公告)日：2008-03-18

申请号：US10959453

申请日：2004-10-06

申请人： Mark A. Miller ,  Gregory J. Lewis ,  Jana L. Gisselquist ,  Jaime G. Moscoso ,  R. Lyle Patton

发明人： Mark A. Miller ,  Gregory J. Lewis ,  Jana L. Gisselquist ,  Jaime G. Moscoso ,  R. Lyle Patton

IPC分类号： C01B39/30

CPC分类号： C01B39/48 ,  B01J29/50 ,  C01B39/305

摘要： A series of crystalline alumino-silicate zeolites identified as UZM-12 have been synthesized. These UZM-12 compositions have the ERI topology, a Si/Al>5.5 and can be prepared as nanocrystallites having an average particle size of about 15 to about 50 nanometers and a spheroidal morphology. The UZM-12 composition can be treated to remove at least a fraction of the framework aluminum atoms thereby providing zeolites with a Si/Al>5.75 and identified as UZM-12HS. Both the UZM-12 and UZM-12HS can catalyze various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列标准为UZM-12的结晶铝硅酸盐沸石。 这些UZM-12组合物具有ERI拓扑结构，Si / Al> 5.5，并且可以制备为具有约15至约50纳米的平均粒度和球形形态的纳米晶体。 可以处理UZM-12组合物以除去至少一部分骨架铝原子，从而提供具有Si / Al> 5.75的沸石并鉴定为UZM-12HS。 UZM-12和UZM-12HS都可以催化各种烃转化过程。

公开(公告)号：US06982074B2

公开(公告)日：2006-01-03

申请号：US10251590

申请日：2002-09-20

申请人： Deng-Yang Jan ,  Jaime G. Moscoso ,  Gregory J. Lewis ,  Michael G. Gatter ,  Beckay J. Mezza ,  Susan C. Koster

发明人： Deng-Yang Jan ,  Jaime G. Moscoso ,  Gregory J. Lewis ,  Michael G. Gatter ,  Beckay J. Mezza ,  Susan C. Koster

IPC分类号： C01B39/06

CPC分类号： C10G45/12 ,  B01J29/70 ,  B01J2229/16 ,  B01J2229/183 ,  B01J2229/32 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/06 ,  C01B39/065 ,  C01B39/46 ,  C10G11/05 ,  C10G35/06

摘要： A family of crystalline aluminosilicate zeolites designated UZM-5HS and derived from UZM-5 have been synthesized. The aluminum content of the UZM-5HS is lower than that of the starting UZM-5 thus changing its ion exchange capacity and acidity. These UZM-5HS are represented by the empirical formula: M1an+Al(1−x)ExSiy′Oz″ and are prepared by treatments such as acid extraction and AFS treatments.

摘要翻译： 已经合成了一系列名为UZM-5HS并衍生自UZM-5的结晶硅铝酸盐沸石。 UZM-5HS的铝含量低于起始UZM-5的铝含量，从而改变其离子交换能力和酸度。 这些UZM-5HS由经验公式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> M1 n + （1-x） x description =“In-Line Formulas”end =“tail”？>，并通过酸萃取和AFS处理等方法制备。

公开(公告)号：US06677162B1

公开(公告)日：2004-01-13

申请号：US09884508

申请日：2001-06-15

申请人： Rune Wendelbo ,  Duncan E. Akporiaye ,  Ivar M. Dahl ,  Arne Karlsson ,  Gregory J. Lewis ,  David S. Bem ,  Andrzej Z. Ringwelski ,  Richard C. Murray, Jr. ,  Cheryl M. Bratu

发明人： Rune Wendelbo ,  Duncan E. Akporiaye ,  Ivar M. Dahl ,  Arne Karlsson ,  Gregory J. Lewis ,  David S. Bem ,  Andrzej Z. Ringwelski ,  Richard C. Murray, Jr. ,  Cheryl M. Bratu

IPC分类号： B01L300

CPC分类号： B01L3/50255 ,  B01J19/0046 ,  B01J2219/00313 ,  B01J2219/00333 ,  B01J2219/00351 ,  B01J2219/00585 ,  B01J2219/00659 ,  B01J2219/00702 ,  B01J2219/00707 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/0289 ,  B01L3/5085 ,  B01L2200/0657 ,  B01L2300/0829 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14 ,  G01N23/20 ,  G01N23/20025 ,  Y10T436/25

摘要： A process of forming an array of powder samples arranged in predefined locations where all samples have a flat surface in a common plane has been developed. A main support having at least N perforations from a first surface of the main support through a second surface of the main support in predefined locations, where N is the number of samples in the array is provided. The main support is equipped with a flat support temporarily attached to its first surface. All N samples are loaded simultaneously with sample X in perforation X of the main support where X is an integer from 1 to N. A flat surface of each sample where the flat surfaces are a common plane is formed by forcing the samples within the perforations against the flat support. The samples are retained in position within the perforations against the flat support, and are made ready for analysis by exposing the flat surfaces of the samples by removing the flat support. The exposed flat surfaces of the samples are in predefined locations and are all in a common plane. Alternatively, the flat support may be permanently attached to the main support.

摘要翻译： 已经开发了形成布置在所有样品在共同平面中具有平坦表面的预定位置的粉末样品阵列的方法。 主支架具有从主支架的第一表面穿过主支撑件的第二表面至少N个穿孔的预定位置，其中N是阵列中的采样数。 主支架配有一个临时安装在其第一个表面上的平坦支撑。 所有N个样品与主支架的穿孔X中的样品X同时加载，其中X是从1到N的整数。平坦表面是共同平面的每个样品的平坦表面是通过迫使穿孔中的样品抵抗 平坦的支持。 将样品保持在穿孔内的位置上抵抗平坦的支撑，并且通过移除平坦的支撑件使样品的平坦表面暴露而使其准备好进行分析。 样品的暴露的平坦表面在预定义的位置并且都在共同的平面中。 或者，扁平支撑件可以永久地附接到主支撑件。