Dehydrogenation of dehydrogenatable hydrocarbons
    3.
    发明授权
    Dehydrogenation of dehydrogenatable hydrocarbons 失效
    脱氢烃脱氢

    公开(公告)号:US4827066A

    公开(公告)日:1989-05-02

    申请号:US197782

    申请日:1988-05-23

    CPC分类号: C07C5/325 C07C5/322 C07C5/333

    摘要: A process for the catalytic dehydrogenation of a dehydrogenatable C.sub.2 -plus feed hydrocarbon which comprises the steps of: (a) passing a feed stream comprising the C.sub.2 -plus feed hydrocarbon into an isothermal dehydrogenation zone and through at least one bed of dehydrogenation catalyst maintained at isothermal dehydrogenation conditions selected to convert at least about 50 weight percent of the dehydrogenatable C.sub.2 -plus feed hydrocarbon and producing an isothermal dehydrogenation zone effluent stream comprising hydrogen, unconverted C.sub.2 -plus feed hydrocarbon and C.sub.2 -plus product hydrocarbon; (b) forming an oxidation catalyst bed feed stream by admixing an oxygen-containing stream with the isothermal dehydrogenation zone effluent stream; (c) passing the oxidation catalyst bed feed stream through a bed of hydrogen selective oxidation catalyst maintained at selective oxidation conditions and producing an oxidation zone effluent stream having a reduced concentration of hydrogen and an increased temperature; (d) passing the oxidation zone effluent stream into an adiabatic dehydrogenation zone and through at least one bed of dehydrogenation catalyst maintained at dehydrogenation conditions selected to convert additional unconverted C.sub.2 -plus feed hydrocarbon and producing an adiabatic dehydrogenation zone effluent stream comprising hydrogen, unconverted C.sub.2 -plus feed hydrocarbon and C.sub.2 -plus product hydrocarbon; and (e) recovering the C.sub.2 -plus product hydrocarbon.

    Dehydrogenation of dehydrogenatable hydrocarbons
    4.
    发明授权
    Dehydrogenation of dehydrogenatable hydrocarbons 失效
    脱氢烃脱氢

    公开(公告)号:US4806624A

    公开(公告)日:1989-02-21

    申请号:US63058

    申请日:1987-06-17

    CPC分类号: C07C5/325 C07C5/3337

    摘要: A process for the catalytic dehydrogenation of a dehydrogenatable C.sub.2 -plus feed hydrocarbon which comprises the steps of: (a) passing a feed stream comprising the C.sub.2 -plus feed hydrocarbon into a dehydrogenation zone and through at least one bed of dehydrogenation catalyst maintained at dehydrogenation conditions and producing a dehydrogenation zone effluent stream comprising hydrogen, the C.sub.2 -plus feed hydrocarbon and a C.sub.2 -plus product hydrocarbon; (b) forming an oxidation catalyst bed feed stream by admixing an oxygen-containing stream with the dehydrogenation zone effluent stream; (c) passing the oxidation catalyst bed feed stream through a bed of hydrogen selective oxidation catalyst maintained at selective oxidation conditions and producing an oxidation zone effluent stream having a reduced concentration of hydrogen; and (d) recovering the product hydrocarbon from the oxidation zone effluent stream without contacting the oxidation zone effluent stream with dehydrogenation catalyst.

    摘要翻译: 一种可脱氢C2加进料烃的催化脱氢方法,其包括以下步骤:(a)使包含C2加进料烃的进料流进入脱氢区,并通过至少一个保持脱氢的脱氢催化剂床 条件并产生包含氢,C2加进料烃和C2加产物烃的脱氢区流出物流; (b)通过将含氧流与脱氢区流出物流混合形成氧化催化剂床进料流; (c)使氧化催化剂床进料流通过保持在选择性氧化条件下的氢选择性氧化催化剂床,并产生具有降低的氢浓度的氧化区流出物流; 和(d)从氧化区流出物流中回收产物烃,而不与脱氢催化剂接触氧化区流出物流。

    Fluid particle backmixed cooling apparatus
    6.
    发明授权
    Fluid particle backmixed cooling apparatus 失效
    流体颗粒回混冷却装置

    公开(公告)号:US4483276A

    公开(公告)日:1984-11-20

    申请号:US590132

    申请日:1984-03-16

    摘要: An apparatus for the cooling of hot fluidized solid particles. The apparatus comprises in combination: (a) a vertically oriented combustion chamber; (b) a disengagement chamber above and connected to the combustion chamber; (c) a collection section at the bottom of the disengagement chamber; (d) a vertically oriented shell and tube heat exchanger with the shell closed at the bottom and the top of the shell in sealed communication with the disengagement chamber such that the particles can circulate to and from the shell and disengagement chamber; (e) a fluidizing gas inlet in the bottom of the shell such that fluidizing gas can enter the shell and continuously backmix the particles; (f) an inlet and outlet to the tubes of the heat exchanger such that a cooling fluid can flow through the tubes; and (g) a control valve in the fluidizing gas inlet with a control system which controls the quantity of cooling fluid removed from the tubes by controlling the amount of fluidizing gas to the heat exchanger which regulates the duty of the heat exchanger.

    摘要翻译: 一种用于冷却热流化固体颗粒的装置。 该装置包括:(a)垂直取向的燃烧室; (b)在燃烧室之上并连接到燃烧室的脱离室; (c)分离室底部的收集部分; (d)垂直定向的壳管式热交换器,壳体在底部封闭,壳体的顶部与分离室密封连通,使得颗粒可以在壳体和分离室中循环; (e)壳体底部的流化气体入口,使得流化气体可以进入壳体并连续地混合颗粒; (f)热交换器的管的入口和出口,使得冷却流体可以流过管; 和(g)流化气体入口中的控制阀,其具有控制系统,该控制系统通过控制调节热交换器的占空比的热交换器的流化气体的量来控制从管中去除的冷却流体的量。

    Fluid particle backmixed cooling process
    7.
    发明授权
    Fluid particle backmixed cooling process 失效
    流体颗粒回混冷却过程

    公开(公告)号:US4439533A

    公开(公告)日:1984-03-27

    申请号:US412698

    申请日:1982-08-30

    摘要: A process and associated apparatus for the cooling of hot fluidized solid particles. The particles flow from a first dense phase fluidized bed into the shell side of a vertically oriented shell and tube heat exchanger where cooling occurs via indirect heat exchange with a cooling medium circulating in the tubes. The extent of cooling is controlled by the varying of the heat transfer coefficient between the tubes and particles in the heat exchanger which are maintained as a second dense phase fluidized bed. The coefficient is varied by varying the quantity of fluidizing gas to the fluidized bed in the heat exchanger. The particles flow freely to and from the first and second dense phase fluidized beds through which the particles recirculate and are backmixed. The process has particular applicability to a combustive regeneration process and most particular applicability to the FCC process.

    摘要翻译: 一种用于冷却热流化固体颗粒的方法和相关设备。 颗粒从第一密相流化床流入垂直取向的壳管式热交换器的壳侧,其中通过与在管中循环的冷却介质的间接热交换进行冷却。 冷却的程度通过保持为第二致密相流化床的热交换器中的管和颗粒之间的传热系数的变化来控制。 通过改变热交换器中流化床的流化气体的量来改变系数。 颗粒自由地流入和流出第一和第二致密相流化床,颗粒通过该流化床再循环并被混合。 该方法特别适用于燃烧再生过程以及对FCC方法的最特别的适用性。