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1.发明授权公开(公告)号：US5091350A
公开(公告)日：1992-02-25
申请号：US605939
申请日：1990-10-29
Applicant: Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
Inventor： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
IPC: B01J23/96 , B01J31/40 , C01G55/00 , C07C45/50 , C07C45/80 , C07C45/85 , C22B3/38 , C22B7/00 , B01J38/68 , C22B11/04
CPC classification number: C22B11/048 , B01J31/2404 , B01J31/4046 , C01G55/001 , C07C45/50 , C07C45/80 , C07C45/85 , C22B3/0051 , C22B7/009 , B01J2231/321 , B01J23/464 , B01J2531/822 , Y02P10/214 , Y02P10/234 , Y02P20/584
Abstract: A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.
Abstract translation: 一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。 还阐述了在络合剂和增溶剂存在下制备醛的方法。 增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个 碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。
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公开(公告)号：US4740626A
公开(公告)日：1988-04-26
申请号：US907033
申请日：1986-09-12
Applicant: Helmut Bahrmann , Werner Konkol , Jugen Weber , Hanswilhelm Bach , Ludger Bexten
Inventor： Helmut Bahrmann , Werner Konkol , Jugen Weber , Hanswilhelm Bach , Ludger Bexten
CPC classification number: C07C45/50
Abstract: The present invention relates to a process for the preparation of aldehydes by the reaction of olefinic compounds with hydrogen and carbon monoxide in the presence of a catalyst system containing rhodium and aromatic phosphines. The aromatic phosphines are soluble in organic media and represent salts of sulfonated or carboxylated triarylphosphines which are insoluble in water. After hydroformylation, the reaction product is treated with a diluted aqueous solution of a base and the aqueous phase containing rhodium and aromatic phosphines is separated. Thus, thermal loading of the catalyst, for example by the redistillation of the reaction product, is avoided.
Abstract translation: 本发明涉及通过烯烃化合物与氢和一氧化碳在含铑和芳香膦的催化剂体系存在下反应制备醛的方法。 芳族膦可溶于有机介质，代表不溶于水的磺化或羧化三芳基膦的盐。 加氢甲酰化后，反应产物用碱的稀释水溶液处理，分离含有铑和芳香族膦的水相。 因此，避免了催化剂的热负荷，例如通过反应产物的再蒸馏。
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3.发明授权
公开(公告)号：US5266729A
公开(公告)日：1993-11-30
申请号：US931891
申请日：1992-08-18
Applicant: Hanswilhelm Bach , Werner Kohl , Gregor Deckers , Detlef Kampmann , Claus Kniep
Inventor： Hanswilhelm Bach , Werner Kohl , Gregor Deckers , Detlef Kampmann , Claus Kniep
IPC: B01J23/78 , C07C49/453 , C07C45/29
CPC classification number: C07C49/453 , B01J23/78 , C07C2103/68
Abstract: A process for the preparation of tricyclo[5.2.1.0.sup.2,6 ]decan-8(9)-one by the conversion of 8(9)-hydroxytricyclo[5.2.1.0.sup.2,6 ]dec-3-ene by means of a supported catalyst containing nickel and magnesium oxide at elevated temperature and, if necessary, at elevated pressure.
Abstract translation: 通过使用载体催化剂转化8（9） - 羟基三环[5.2.1.02,6]癸-3-烯来制备三环[5.2.1.02,6]癸烷-8-（9） - 酮的方法 在升高的温度下含有镍和氧化镁，如果需要，在升高的压力下。
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公开(公告)号：US4808757A
公开(公告)日：1989-02-28
申请号：US193956
申请日：1988-05-13
Applicant: Boy Cornils , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Helmut Bahrmann , Heinz-Dieter Hahn
Inventor： Boy Cornils , Werner Konkol , Hanswilhelm Bach , Wilhelm Gick , Ernst Wiebus , Helmut Bahrmann , Heinz-Dieter Hahn
CPC classification number: C07C45/50
Abstract: A process for the preparation of aldehydes by hydroformylation of olefins in the presence of an aqueous solution containing rhodium as a catalyst. The aqueous solution preferably contains rhodium in a concentration of 450 to 800 weight-ppm and sulfonated or carboxylated triarylphosphines as complex ligands in a concentration of 25 to 30% by weight, both based on the aqueous solution.
Abstract translation: 在含有铑作为催化剂的水溶液存在下通过烯烃的加氢甲酰化来制备醛的方法。 该水溶液优选含有浓度为450-800重量ppm的铑和基于水溶液的25-30重量％浓度的磺化或羧化三芳基膦作为络合配体。
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公开(公告)号：US4795727A
公开(公告)日：1989-01-03
申请号：US47663
申请日：1987-05-08
Applicant: Hanswilhelm Bach , Helmut Bahrmann , Boy Cornils , Werner Konkol , Ernst Wiebus
Inventor： Hanswilhelm Bach , Helmut Bahrmann , Boy Cornils , Werner Konkol , Ernst Wiebus
IPC: C07B61/00 , B01J31/00 , B01J31/02 , B01J31/20 , B01J31/24 , B01J37/04 , C07C45/00 , C07C45/50 , C07C47/02 , C07C47/06 , C07C47/07 , C07C67/00 , C07F9/50 , B01J31/22
CPC classification number: C07C45/50
Abstract: A process for the preparation of a rhodium catalyst comprising dissolving a carboxylic acid salt of rhodium in a solvent taken from the class consisting of aliphatic, cycloaliphatic, aromatic hydrocarbons and mixtures thereof. The carboxylic acid has 2 to 18 carbon atoms. This salt is reacted with carbon monoxide and hydrogen to form a rhodium hydridrocarbonyl which is reacted with an aqueous solution of a triaryl phosphine. The aqueous solution may be present during the initial reaction of the rhodium salt or may be added thereafter. A catalyst which is the product of the foregoing process is also disclosed, as is a method of producing aldehydes using the catalyst.
Abstract translation: 一种制备铑催化剂的方法，包括将铑的羧酸盐溶解在从脂族，脂环族，芳族烃及其混合物组成的溶剂中。 羧酸具有2至18个碳原子。 该盐与一氧化碳和氢气反应形成与三芳基膦水溶液反应的铑氢化羰基。 水溶液可以在铑盐的初始反应期间存在，或者可以在其后加入。 还公开了作为上述方法的产物的催化剂，以及使用该催化剂生产醛的方法。
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6.发明授权Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom 失效用铑催化剂加氢甲酰化和从中分离铑的方法
公开(公告)号：US4731485A
公开(公告)日：1988-03-15
申请号：US9734
申请日：1987-02-02
Applicant: Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
Inventor： Boy Cornils , Werner Konkol , Helmut Bahrmann , Hanswilhelm Bach , Ernest Wiebus , Wolfgang Lipps
IPC: C07C45/50
CPC classification number: C07C45/50
Abstract: A process for separating rhodium from mixtures thereof, comprising extracting said rhodium with an aqueous solution of a rhodium complexing agent and a solubilizer. A process for preparing aldehydes in the presence of both the complexing agent and the solubilizer is also set forth. The solubilizer is generally selected from salts of carboxylic acids having 8-20 carbon atoms, alkyl sulfonates, alkyl aryl sulfonates, amines and quaternary ammonium compounds of Formula II ##STR1## wherein A is alkyl, alkoxy, hydroxyalkyl, aryl having 6-25 carbon atoms, or R.sup.7 CONHCH.sub.2 CH.sub.2 CH.sub.2 --wherein R.sup.7 is alkyl having 5-11 carbon atoms; B is an alkyl having 1-25 carbon atoms, an aryl having 6-25 carbon atoms, or an .omega.-hydroxy alkyl having 1-4 carbon atoms; C and D are each independently an alkyl or .omega.-hydroxy alkyl having 1-4 carbon atoms or form, together with each other and the bridging N, a 5 or 6 membered heterocyclic ring; E is a halide, sulfate, borate, sulfonate, lactate or citrate; and p is the number of charges on E. The rhodium complexing agent is preferably a triaryl phosphine carboxylate or sulfonate.
Abstract translation: 一种从其混合物中分离铑的方法，包括用铑络合剂和增溶剂的水溶液萃取所述铑。 还阐述了在络合剂和增溶剂存在下制备醛的方法。 增溶剂通常选自具有8-20个碳原子的羧酸盐，烷基磺酸盐，烷基芳基磺酸盐，胺和季铵化合物，其中A是烷基，烷氧基，羟基烷基，具有6-25个 碳原子或R7CONHCH2CH2CH2-，其中R7是具有5-11个碳原子的烷基; B是具有1-25个碳原子的烷基，具有6-25个碳原子的芳基，或具有1-4个碳原子的ω-羟基烷基; C和D各自独立地为具有1-4个碳原子的烷基或ω-羟基烷基，或彼此形成桥连N和5或6元杂环; E是卤化物，硫酸盐，硼酸盐，磺酸盐，乳酸盐或柠檬酸盐; 并且p是E上的电荷数。铑络合剂优选为三芳基膦羧酸盐或磺酸盐。
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公开(公告)号：US5008473A
公开(公告)日：1991-04-16
申请号：US98047
申请日：1987-09-17
Applicant: Norbert Breitkopf , Georg Dambkes , Hanswilhelm Bach
Inventor： Norbert Breitkopf , Georg Dambkes , Hanswilhelm Bach
CPC classification number: C07C29/86
Abstract: A process for the purification of propanediol-1,3, especially when produced by hydration of acrolein with water, including extracting the diol with cyclohexane. Preferably, from 2 to 10 parts by weight of cyclohexane per part by weight of diol is used. The purification is usually carried out below 60.degree. C.
Abstract translation: 丙二醇-1,3-的纯化方法，特别是通过丙烯醛与水的水合反应制备的方法，包括用环己烷萃取二醇。 优选使用每重量份二醇2至10重量份的环己烷。 纯化通常在60℃以下进行。
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公开(公告)号：US4723047A
公开(公告)日：1988-02-02
申请号：US910650
申请日：1986-09-23
Applicant: Helmut Bahrmann , Boy Cornils , Werner Konkol , Jurgen Weber , Ludger Bexten , Hanswilhelm Bach
Inventor： Helmut Bahrmann , Boy Cornils , Werner Konkol , Jurgen Weber , Ludger Bexten , Hanswilhelm Bach
IPC: C07C29/16 , B01J31/00 , B01J31/24 , C07B61/00 , C07C27/00 , C07C29/158 , C07C31/20 , C07C45/49 , C07C67/00 , C07C29/14
CPC classification number: C07C45/49 , C07C29/158 , C07C31/20
Abstract: The present invention relates to a process for the preparation of nonadecanediols by the hydroformylation of oleyl alcohol. Rhodium and salts of sulfonated or carboxylated triarylphosphines, which are soluble in organic media and insoluble in water, are used as hydroformylation catalysts. The hydroformylation product is then treated with a diluted solution of a base dissolved in water, the aqueous phase separated and the hydroformylation product treated with hydrogen at elevated temperature in the presence of a hydrogenation catalyst.
Abstract translation: 本发明涉及通过油醇加氢甲酰化来制备非十二烷二醇的方法。 可溶于有机介质并且不溶于水的磺化或羧化的三芳基膦的铑和盐被用作加氢甲酰化催化剂。 然后用溶解在水中的碱的稀释溶液处理加氢甲酰化产物，分离出水相，加氢甲酰化产物在氢化催化剂存在下在高温下用氢气处理。
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公开(公告)号：US4711648A
公开(公告)日：1987-12-08
申请号：US906455
申请日：1986-09-11
Applicant: Werner Konkol , Helmut Bahrmann , Georg Dambkes , Wilhelm Gick , Ernst Wiebus , Hanswilhelm Bach
Inventor： Werner Konkol , Helmut Bahrmann , Georg Dambkes , Wilhelm Gick , Ernst Wiebus , Hanswilhelm Bach
IPC: B01D53/52 , B01D53/00 , B01D53/14 , B01D53/54 , B01D53/77 , C01B3/52 , C07C45/50 , C07C45/78 , C10K1/16 , B01D19/00
CPC classification number: B01D53/14 , B01D53/1493 , C01B3/52 , C10K1/16 , C01B2203/0415 , C01B2203/0465
Abstract: A process for the purification of a gas containing one or more of hydrogen sulfide, hydrogen cyanide, and carbonyl sulfide as impurities comprising contacting the gas with at least one aliphatic aldehyde which is liquid under the purification conditions. The gas is inert to the aldehyde under such conditions. The process is useful in the purification of synthesis gas for use in reactions wherein sensitive catalysts are employed.
Abstract translation: 纯化含有一种或多种硫化氢，氰化氢和羰基硫化物作为杂质的气体的方法，包括使气体与至少一种在纯化条件下为液体的脂族醛接触。 在这种条件下，气体对醛是惰性的。 该方法可用于纯化用于其中使用敏感催化剂的反应中的合成气。
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公开(公告)号：US4435603A
公开(公告)日：1984-03-06
申请号：US242772
申请日：1981-03-11
Applicant: Boy Cornils , Hanswilhelm Bach , Roderich Gartner , Wilhelm Gick
Inventor： Boy Cornils , Hanswilhelm Bach , Roderich Gartner , Wilhelm Gick
CPC classification number: C07C29/94
Abstract: A polyol composition comprising a solid polyol which is crystalline under normal conditions and, as an anti-caking agent therefor, a tertiary amine containing at least two identical organic substituents, each having two to twenty carbon atoms. A method of preventing caking of polyols is disclosed wherein to such polyols there is added at least one of such tertiary amines, preferably in a concentration of 0.05 to 0.25 percent by weight based on the weight of the polyol.
Abstract translation: 一种多元醇组合物，其包含在正常条件下为结晶的固体多元醇，作为其抗结块剂，含有至少两个相同有机取代基的叔胺，每个具有2至20个碳原子。 公开了防止多元醇结块的方法，其中对于这种多元醇，基于多元醇的重量，加入至少一种这样的叔胺，优选浓度为0.05-0.25重量％。
