摘要:
Halophthalic anhydrides are prepared by the liquid phase reaction of a brominating agent with halogen substituted hexa- or tetra-hydrophthalic anhydrides.
摘要:
Disclosed is a method of making potassium tripolyphosphate by loading an ion exchange resin with either potassium or hydrogen ions and passing an aqueous solution of sodium tripolyphosphate through the resin so that the sodium ions of the sodium tripolyphosphate are exchanged with the ions loaded onto the resin, forming either potassium tripolyphosphate or tripolyphosphoric acid, respectively. The tripolyphosphoric acid is reacted with potassium hydroxide to form potassium tripolyphosphate. When the ion exchange resin becomes exhausted it is regenerated using a potassium-containing ionic solution, forming a sodium ion containing stream. The sodium ion containing stream is reacted with a phosphoric acid to form a stream of sodium phosphates.
摘要:
Disclosed is a method of making hexametaphosphates by reacting sodium tripolyphosphate, tetrasodium pyrophosphate, or trisodium phosphate with phosphoric acid, forming a molten glass of said mixture, and chilling said molten glass to form a solid.
摘要:
A process for the preparation of a halophthalic anhydride, such as chlorophthalic anhydride, comprising the liquid phase reaction of bromine with a halogen substituted hexa- or tetra-hydrophthalic anhydride to produce halophthalic anhydride and gaseous HBr, and reacting the gaseous HBr with chlorine to regenerate bromine.
摘要:
Disclosed is a method of preventing fluids in the ground from rising around an oil well pipe by filling the space around the pipe with an oil well completion fluid comprising water, about 50 to about 65% by weight, based on total fluid weight, of dipotassium phosphate, and at least about 10 ppm hexavalent chromium. The fluid can be prepared by neutralizing wet process phosphoric acid with potassium hydroxide to a pH of less than 12 and filtering off any solids. Also disclosed is an oil well employing the completion fluid.
摘要:
Disclosed is a method of making phosphorous acid or hypophosphorous acid by reacting hydrogen chloride with a sodium phosphite or a sodium hypophosphite, respectively, in the presence of water to precipitate sodium chloride crystals and form the acid. The acid is separated from the sodium chloride crystals and can be passed through an anion exchange column that is preferably loaded with phosphite or hypophosphite ions, respectively, to remove residual chloride ions.
摘要:
Disclosed is a method of making a eutectic mixture of copper and tricopper phosphide by reacting elemental copper with phosphine. The elemental copper is heated to a temperature above about 714.degree. C. and the liquid eutectic mixture runs off of the cooper as it is formed, exposing more copper for reaction. The liquid eutectic mixture can be used as a source of copper and phosphorus in making metal alloys.
摘要:
Thianthrene compounds are prepared by adding sulfur monochloride to an excess of a benzene compound in the presence of aluminum chloride, and reacting to form a thianthrene compound as an insoluble aluminum chloride complex; slurrying the complex in an inert organic liquid; treating the slurry with a Lewis base, such as ammonia to free the thianthrene compound from the complex.
摘要:
Thianthrene is prepared by adding sulfur monochloride to an excess of benzene in the presence of aluminum chloride, and reacting at a temperature of 60.degree. to 80.degree. C to form thianthrene as an insoluble thianthrene-aluminum chloride complex; separating the complex by filtration, slurrying the complex in an inert organic liquid; treating the slurry with a Lewis base, such as ammonia to free the thianthrene from the complex and recovering a relatively high purity thianthrene product.
摘要:
Disclosed is a process for producing phosphorous trichloride, phosphorous pentachloride, or phosphorous tribromide by reacting phosphine gas with chlorine gas or bromine gas, in a mixture with hydrogen gas. The phosphine is dried and the reaction is performed at a temperature up to about 250° C. The phosphorous trichloride or phosphorous tribromide product can be reacted with oxygen to form phosphorous oxychloride or phosphorous oxybromide, respectively.