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    Process for manufacturing .alpha.-chloroarylacetic acids
    2.
    发明授权
    Process for manufacturing .alpha.-chloroarylacetic acids 失效
    制备α-氯代芳基乙酸的方法

    公开(公告)号：US4227016A

    公开(公告)日：1980-10-07

    申请号：US865285

    申请日：1977-12-28

    申请人： Emmanuel Herman ,  Helmut Diery ,  Michel Soreau ,  Yani Christidis

    发明人： Emmanuel Herman ,  Helmut Diery ,  Michel Soreau ,  Yani Christidis

    IPC分类号： C07C57/58 ,  C07C59/64 ,  C07C59/68

    CPC分类号： C07C57/58 ,  C07C59/64 ,  C07C59/68

    摘要： Glyoxylic acid and hydrochloric acid are reacted with an aromatic compound having at least one substituent group selected from among the alkyl, aryl, hydroxy, alkoxy and aryloxy groups. The glyoxylic acid is used in a concentration comprised between 60 and 100% and the hydrochloric acid is used in as concentrated an aqueous solution as possible, e.g. in an organic solvent medium such as acetic acid. An acid catalyst such as zinc chloride may be used. The reaction may be carried out under pressure. The products are useful in various syntheses e.g. to produce amino acids or arylacetic acids with medicinal uses.

    摘要翻译： 将乙醛酸和盐酸与具有选自烷基，芳基，羟基，烷氧基和芳氧基中的至少一个取代基的芳族化合物反应。 乙醛酸的使用浓度为60-100％，盐酸以尽可能浓的水溶液使用。 在有机溶剂介质如乙酸中。 可以使用酸催化剂如氯化锌。 反应可以在压力下进行。 该产品可用于各种合成例如 生产氨基酸或芳基乙酸与药用。

    Polyether dispersants
    4.
    发明授权
    Polyether dispersants 失效
    聚醚分散剂

    公开(公告)号：US4450304A

    公开(公告)日：1984-05-22

    申请号：US400274

    申请日：1982-07-21

    申请人： Helmut Diery ,  Reinhold Deubel ,  Joachim Weide

    发明人： Helmut Diery ,  Reinhold Deubel ,  Joachim Weide

    IPC分类号： C07C41/02 ,  B01F17/00 ,  B01F17/42 ,  C07C41/00 ,  C07C43/20 ,  C07C43/205 ,  C07C43/225 ,  C07C67/00 ,  C08G65/04 ,  C08G65/26 ,  C08G65/28 ,  C09B67/20 ,  C09B67/46

    CPC分类号： B01F17/0028 ,  C08G65/04 ,  C08G65/2612 ,  C09B67/0089 ,  Y10S516/01

    摘要： Compounds of the formula ##STR1## in which Y denotes an aryloxy group, which is possibly substituted, R.sub.4 and R.sub.5 denote hydrogen or C.sub.1 -C.sub.4 -alkyl, m denotes 0 to 12 and Z denotes polyalkylene glycol radicals having about 8 to about 200 ethylene glycol units --(CH.sub.2 --CH.sub.2 O)-- or up to about 200 ethylene glycol units and alkylene glycol units of the formula ##STR2## in which R.sub.6 is methyl or ethyl and in which at least 8 ethylene glycol units are present. These compounds are prepared by initially reacting epoxide with a phenol or naphthol and subsequently oxalkylating. The reaction products are used as dispersants for the preparation of aqueous pigment dispersions.

    摘要翻译： 其中Y表示可以被取代的芳氧基的式（I）＆lt; IMAGE＆gt;化合物，R 4和R 5表示氢或C 1 -C 4 - 烷基，m表示0〜12，Z表示具有 约8至约200个乙二醇单元 - （CH 2 -CH 2 O） - 或至多约200个乙二醇单元和式“IMAGE”的亚烷基二醇单元，其中R 6为甲基或乙基，其中至少8个乙二醇单元为 当下。 这些化合物通过首先使环氧化物与苯酚或萘酚反应并随后进行氧烷基化来制备。 反应产物用作制备水性颜料分散体的分散剂。

    Water miscible corrosion inhibitors
    5.
    发明授权
    Water miscible corrosion inhibitors 失效
    水混溶性腐蚀抑制剂

    公开(公告)号：US4297236A

    公开(公告)日：1981-10-27

    申请号：US942337

    申请日：1978-09-14

    申请人： Helmut Diery ,  Rainer Helwerth ,  Horst Frohlich ,  Horst Lorke

    发明人： Helmut Diery ,  Rainer Helwerth ,  Horst Frohlich ,  Horst Lorke

    IPC分类号： C10M159/12 ,  C10M163/00 ,  C10M173/02 ,  C10N30/12 ,  C10N40/08 ,  C10N40/22 ,  C10N40/24 ,  C23F11/10 ,  C23F11/14 ,  C23F11/16 ,  C23F11/18

    CPC分类号： C23F11/10 ,  C10M2201/02 ,  C10M2219/044 ,  C10M2227/061 ,  C10N2240/08 ,  C10N2240/40 ,  C10N2240/401

    摘要： Water-miscible corrosion inhibitors, substantially consisting of(A) reaction products of boric acid and diethanolamine, and(B) arylsulfonamidocarboxylic acids of the formula I ##STR1## in which R.sub.1 and R.sub.2 each represent hydrogen, fluorine, chlorine, bromine, an alkyl or alkoxy radical having from 1 to 4 carbon atoms, with the proviso that the sum of the carbon atoms of R.sub.1 and R.sub.2 does not exceed 7;Ar is a benzene, naphthalene or anthracene radical;R.sub.3 is hydrogen, an aryl radical having up to 4 carbon atoms, a .beta.-cyanoethyl or hydroxyalkyl radical having from 2 to 4 carbon atoms;R.sub.4 is an alkylene radical having more than 3 carbon atoms, optionally substituted by one or more methyl or ethyl radicals; andn is 1 or 2; oralkyl- and/or cycloalkylsulfonamidocarboxylic acids obtained by sulfochlorination of a saturated aliphatic and/or cycloaliphatic hydrocarbon having from 12 to 22 carbon atoms and a boiling temperature range of from about 200.degree. to 350.degree. C., subsequent reaction with ammonia and final condensation with chloroacetic acid.

    摘要翻译： 水混溶性腐蚀抑制剂，基本上由（A）硼酸和二乙醇胺的反应产物和（B）式I的芳基磺酰胺羧酸组成，其中R 1和R 2各自表示氢，氟，氯，溴，烷基 或具有1至4个碳原子的烷氧基，条件是R 1和R 2的碳原子之和不超过7; Ar是苯，萘或蒽基; R3是氢，具有至多4个碳原子的芳基，具有2至4个碳原子的β-氰基乙基或羟烷基; R4是具有多于3个碳原子的亚烷基，任选被一个或多个甲基或乙基取代; n为1或2; 或通过对具有12至22个碳原子的沸点温度范围为约200至350℃的饱和脂族和/或脂环族烃进行磺基氯化获得的烷基和/或环烷基磺酰胺羧酸，随后与氨反应和最终冷凝 与氯乙酸。

    Cationic ethylene oxide/propylene oxide and ethylene oxide/butylene oxide polymers, a process for their preparation and their use
    7.
    发明授权
    Cationic ethylene oxide/propylene oxide and ethylene oxide/butylene oxide polymers, a process for their preparation and their use 失效
    阳离子环氧乙烷/环氧丙烷和环氧乙烷/环氧丁烷聚合物，其制备方法及其用途

    公开(公告)号：US4451671A

    公开(公告)日：1984-05-29

    申请号：US412527

    申请日：1982-08-30

    申请人： Helmut Diery ,  Norbert Wester ,  Martin Hille

    发明人： Helmut Diery ,  Norbert Wester ,  Martin Hille

    IPC分类号： B01D17/04 ,  C08G73/02 ,  C09K8/035 ,  C10G33/04 ,  C07C91/26

    CPC分类号： B01D17/047 ,  C08G73/024 ,  C09K8/035 ,  C10G33/04 ,  Y10S516/07

    摘要： Thus, the invention relates to compounds of the formula I ##STR1## where R is aromatic, preferably phenylene, R.sub.1 and R.sub.2 denote C.sub.1 -C.sub.4 -alkyl, preferably C.sub.1 -C.sub.2 -alkyl, R.sub.3 denotes methyl or ethyl, x and z together denote a number from 2 to 360, preferably from 2 to 140, y denotes a number from 15 to 70, preferably 25 to 60, n denotes a number from 1 to 10 and A.sup.- denotes an anion, preferably chloride or bromide, a process for their preparation and their use as demulsifiers for demulsifying crude oil emulsions and as corrosion inhibitors in equipment for lifting and processing natural gas and crude oil.

    摘要翻译： 因此，本发明涉及式Ⅰ化合物，其中R是芳族的，优选亚苯基，R 1和R 2表示C 1 -C 4烷基，优选C 1 -C 2烷基，R 3表示 甲基或乙基，x和z一起表示2至360，优选2至140的数，y表示15至70，优选25至60的数，n表示1至10的数，A-表示阴离子 ，优选氯化物或溴化物，其制备方法及其用作破乳剂用于破乳原油乳液和用作提升和加工天然气和原油的设备中的腐蚀抑制剂。

    Bisamides, a process for their preparation and their use
    10.
    发明授权
    Bisamides, a process for their preparation and their use 失效
    双酰胺，它们的制备和使用的过程

    公开(公告)号：US4536339A

    公开(公告)日：1985-08-20

    申请号：US414509

    申请日：1982-09-02

    申请人： Werner Ritschel ,  Helmut Diery ,  Martin Hille

    发明人： Werner Ritschel ,  Helmut Diery ,  Martin Hille

    IPC分类号： C10G7/10 ,  C07C67/00 ,  C07C231/00 ,  C07C231/02 ,  C07C231/12 ,  C07C233/18 ,  C07C233/36 ,  C10G33/04 ,  C11C3/00

    CPC分类号： C10G33/04

    摘要： Bisamides of the formula ##STR1## wherein R denotes the alkyl skeleton of a dimerized fatty acid having 22 to 42, preferably 34, C atoms, R.sub.1 denotes hydrogen or a group of the formula--(C.sub.n H.sub.2n --X).sub.a --Z.sub.v --R.sub.2,R.sub.2 denotes hydrogen or a group --COR.sub.3, R.sub.3 denotes C.sub.1 -C.sub.22 -, preferably C.sub.8 -C.sub.22 -alkyl, X denotes an oxygen atom or a group of the formula N--B.sub.m, B denotes hydrogen, methyl, ethyl, benzyl or a group of the formula --Z.sub.v --R.sub.2, n denotes a number from 2 to 6, preferably 2 or 3, a denotes a number from 0 to 5, v denotes a number from 0 to 100, preferably 0 to 20, Z denotes a group of the formula --C.sub.2 H.sub.4 X(C.sub.3 H.sub.6 X).sub.b or CH.sub.2 --CHY O or C.sub.n H.sub.2n, b denotes a number from 0 to 5, preferably 0, 1 or 2, i denotes a number from 0 to 2(a+b)+2 and A denotes an anion, m denotes a number from 1 to 2 and Y denotes hydrogen, methyl or ethyl, a process for their preparation and their use as demulsifiers for crude oil emulsions.

    摘要翻译： 其中R表示具有22至42个，优选34个C原子的二聚脂肪酸的烷基骨架，R1表示氢或式 - （C n H 2n-X）a-Zv-R 2的基团， R 2表示氢或基团-COR 3，R 3表示C 1 -C 22 - ，优选C 8 -C 22 - 烷基，X表示氧原子或式N-Bm基团，B表示氢，甲基，乙基，苄基或基团 式为-Zv-R2，n表示2〜6的数，优选为2或3，a表示0〜5的数，v表示0〜100的数，优选为0〜20，Z表示 式-C2H4X（C3H6X）b或CH2-CHYO或CnH2n，b表示0至5，优选0,1或2的数，i表示0至2（a + b）+2的数，A表示 阴离子，m表示1至2的数，Y表示氢，甲基或乙基，其制备方法及其用作原油乳液的破乳剂。