摘要:
A lithium secondary battery (10) includes a positive electrode active material of lithium transition metal oxide which contains at least a nickel element and a manganese element as transition metals and for which, with respect to a diffraction peak A located at a diffraction angle 20 of 17° to 20° and a diffraction peak B located at a diffraction angle 2Θ of 43° to 46° from X-ray diffraction measurements, when the integrated intensity ratio is R1=IA/IB, the peak intensity ratio is RH=HA/HB, and the ratio between the integrated intensity ratio R1 and the peak intensity ratio RH is SF=RH/R1>> the SF satisfies 1.1≦SF≦2.2.
摘要翻译:锂二次电池(10)包括锂过渡金属氧化物的正极活性物质,其至少包含镍元素和锰元素作为过渡金属,并且对于衍射峰A,位于衍射角20的衍射角 17°〜20°的衍射峰B和衍射角2θ为43°〜46°的X射线衍射测定时的衍射峰B,当积分强度比为R1 = IA / IB时,峰强度比为RH = HA / HB,积分强度比R1与峰值强度比RH之比为SF = RH / R1 >> SF满足1.1≤SS≤2.2。
摘要:
A lithium secondary battery of the present invention has a positive electrode is provided with a positive electrode mix layer that includes a positive electrode active material and a conductive material. The positive electrode mix layer has two peaks, large and small, of differential pore volume over a pore size ranging from 0.01 μm to 10 μm in a pore distribution curve measured by a mercury porosimeter. A pore size of the smaller peak B of the differential pore volume is smaller than a pore size of the larger peak A of the differential pore volume.
摘要:
A secondary battery 100 includes a positive electrode current collector 221 and a positive electrode mixture layer 223 which is coated over the positive electrode current collector 221. The positive electrode mixture layer 223 includes a positive electrode active material 610, an electrically conductive material 620, and a binder 630. In addition, the positive electrode active material 610 has secondary particles 910 formed by an aggregation of a plurality of primary particles of a lithium transition metal oxide, a hollow portion 920 formed in the secondary particle 910, and through holes 930 penetrating the secondary particles 910 so as to connect the hollow portion 920 and the outside. A ratio (Vbc/Va) of an inner volume Vbc of holes formed inside the positive electrode mixture layer 223 to an apparent volume Va of the positive electrode mixture layer 223 satisfies 0.25≦(Vbc/Va). In addition, in a section of the positive electrode mixture layer 223, a ratio (Vb/Vc) of an inner volume Vb of holes B formed inside the positive electrode active material 610 to an inner volume Vc of holes C formed outside the positive electrode active material 610 satisfies 0.05≦(Vb/Vc)≦2.5.
摘要:
An electrode is provided with a metal terminal extending from a battery module main body, a bolt which has an expanded section configuring a retaining section at a rear end portion and penetrates the metal terminal upward, and an insulating body which insulates the metal terminal and the battery module case one from the other. The insulating body is provided with a drop preventing section which abuts at least a lower surface of the expanded section of the bolt and prevents the bolt from dropping from the metal terminal.
摘要:
An electrode is provided with a metal terminal extending from a battery module main body, a bolt which has an expanded section configuring a retaining section at a rear end portion and penetrates the metal terminal upward, and an insulating body which insulates the metal terminal and the battery module case one from the other. The insulating body is provided with a drop preventing section which abuts at least a lower surface of the expanded section of the bolt and prevents the bolt from dropping from the metal terminal.
摘要:
A battery includes a current breaking mechanism 20 provided in a battery and configured such that an external terminal 21 connecting a terminal rivet 31 connected to a power generating element 16 to an electrode terminal is provided with thick portions 48 and 49 and a breakable portion 45 so that the thick portions 48 and 49 are continuous through the breakable portion 45 only. The battery further includes: the terminal rivet 31 placed passing through a closing plate 12 forming a part of a battery case 11, a part of the terminal rivet 31 located outside the battery case 11 being placed on the thick portion 48 of the external terminal 21 in close contact relation, the terminal rivet 31 having a through hole 32; and a sealing cap 25 covering an exit of the through hole 32 on the outside of the battery case 11 and being joined to the external terminal 21 over the entire circumference of the through hole 32 or joined to both the external terminal 21 and the terminal rivet 31 across them. When the internal pressure of the battery case 11 rises, at least part of the sealing cap 25 is moved away from the battery case 11, deforming a part of the external terminal 21, thereby breaking the breakable portion 45.
摘要:
A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode. The positive electrode of this secondary battery contains a positive electrode active substance having a hollow structure, which has a shell portion and a hollow portion formed inside the shell portion. In addition, a heat-resistant barrier layer is disposed between the positive electrode and the separator.
摘要:
A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a heat-resistant layer disposed between the positive electrode and the negative electrode. The positive electrode of this secondary battery contains a positive electrode active substance having a hollow structure, which has a shell portion and a hollow portion formed inside the shell portion. In addition, the heat-resistant layer contains plate-shaped inorganic filler particles as the main component.
摘要:
The method for producing a lithium ion secondary battery includes: selecting a positive electrode sheet, negative electrode sheet, and separator sheet; constructing an electrode assembly by superimposing the selected sheets; and housing the above electrode assembly in a battery case along with an electrolyte solution. In the method, at least one of the sheets is selected such that it satisfies the relationship 0.8
摘要:
The lithium rechargeable battery of the present invention is provided with a current collector and an active material layer containing active material particles 10 supported on this current collector. The active material particles 10 are secondary particles 14 in which a plurality of primary particles 12 of a lithium transition metal oxide are aggregated, and have a hollow structure that contains a hollow section 16 formed inside the secondary particle 14 and a shell section 15 that surrounds the hollow section 16. A through hole 18 that penetrates from the outside to the hollow section 16 is formed in the secondary particle 14. The ratio (A/B) in a powder x-ray diffraction pattern of the active material particles 10, where A is the full width at half maximum of the diffraction peak obtained for the (003) plane and B is the full width at half maximum of the diffraction peak obtained for the (104) plane, satisfies the equation (A/B)≦0.7.