摘要:
The present invention provides a compound represented by formula (1) defined in the specification. The invention further provides a liquid crystal composition comprising at least two compounds, which at least one compound out of them is the above compound. The invention still further provides a polymer obtained by polymerizing the above composition, and uses of the polymer such as a molded article having an optical anisotropy, an optical compensation element, a wavelength functional plate, an optical element, and a liquid crystal display element comprising the polymer.
摘要:
Provided is a liquid-crystalline, polymerizable vinyl ketone compound of formula (1): Preferably, R1 is hydrogen, halogen, —CN, —CF3, —CF2H, —CFH2, —OCF3, —OCF2H, or alkyl, alkoxy, alkoxyalkyl or alkenyl having from 1 to 10 carbon atoms; R2, R3 and R5 are hydrogen; A1 to A4 are independently 1,4-cyclohexylene, 1,4-cyclohexenylene or 1,4-phenylene where any hydrogen may be substituted with halogen; Z1 to Z3 are independently a single bond, —(CH2)2—, —CH═CH—, —CF═CF—, —OCF2— or —CF2O—; Z4 is a single bond, —(CH2)3— or —(CH2)4—; m, n and q are independently 0, 1 or 2. The uppermost temperature of the liquid crystalline phase of the compound is high, and the compound has good compatibility with other compounds and has the necessary characteristics such as optical anisotropy. Also provided are a polymer having many good characteristics of transparency, mechanical strength, coatability, solubility, crystallinity, shrinkage, water permeability, water absorption, melting point, glass transition point, clearing point and chemical resistance; an optically-anisotropic material of the polymer; a liquid-crystal display device that comprises the polymer; and a method for producing the liquid-crystalline compound.
摘要:
A compound capable of shortening the response time of liquid crystal display elements and a composition containing the same are provided, which compound is expressed by the formula ##STR1## wherein R.sup.1 represents a linear or branched chain alkyl group or alkoxy group, each of 1C-18C; Ar represents ##STR2## wherein X represents H, halogen atom, cyano group or methyl; A represents --COO-- or --CH.sub.2 O--; R.sup.2 represents a C.sub.1 -C.sub.18 alkyl, A C.sub.2 -C.sub.18 alkanoyl, a C.sub.3 -C.sub.18 alkoxycarbonyl or a C.sub.4 -C.sub.18 2-alkoxypropanoyl; C having a symbol * attached thereonto represents asymmetric carbon atom; and when R.sup.2 represents a linear chain alkyl and A represents --COO--, Ar is not ##STR3##
摘要:
An optically active liquid crystal compound having specific features suitable to a display mode utilizing ferroelectric chiral smectic phases and particularly having a large spontaneous polarization value, and a chiral liquid crystal composition containing the compound are provided, which compound is expressed by the formula ##STR1## wherein R.sup.1 represents an alkyl group of 2 to 18 carbon atoms; R.sup.2 represents an alkyl group or alkoxy group each of 1 to 20 carbon atoms, hydrogen atom, a halogen atom or cyano group; A represents --COO-- or --OCO--; B and C each represent a single bond, ##STR2## wherein X represents hydrogen atom, a halogen atom or cyano group; and l, m and n each represent 0 or 1.
摘要:
A compound useful as a component constituting ferroelectric liquid crystal display elements and a liquid crystal composition containing the same are provided, which compound is expressed by the formula ##STR1## wherein R represents a linear or branched chain alkyl group of 1 to 20 carbon atoms and R* represents an optically active alkyl group, alkoxy group, alkoxyalkyl group, alkoxyalkoxy group, alkanoyloxyalkyl group, alkanoyloxyalkoxy group, halogenated alkyl group or halogenated alkoxy group each of 2 to 20 carbon atoms.
摘要:
A novel chiral liquid crystal compound having an optically active group which affords a superior response rate when used as a liquid crystal display element, and a liquid crystal composition containing the same are provided, which chiral liquid crystal compound is expressed by the formula ##STR1## wherein R represents an alkyl group of 1 to 18 carbon atoms; R* represents an optically active alkyl group of 4 to 15 carbon atoms; X represents single bond, --O--, ##STR2## Y represents --CH.sub.2 O-- or --OCH.sub.2 --; Z represents single bond, --O--, ##STR3## and m and n each represent 1 or 2.
摘要:
Provided is a liquid-crystalline, polymerizable vinyl ketone compound of formula (1): Preferably, R1 is hydrogen, halogen, —CN, —CF3, —CF2H, —CFH2, —OCF3, —OCF2H, or alkyl, alkoxy, alkoxyalkyl or alkenyl having from 1 to 10 carbon atoms; R2, R3 and R5 are hydrogen; A1 to A4 are independently 1,4-cyclohexylene, 1,4-cyclohexenylene or 1,4-phenylene where any hydrogen may be substituted with halogen; Z1 to Z3 are independently a single bond, —(CH2)2—, —CH═CH—, —CF═CF—, —OCF2— or —CF2O—; Z4 is a single bond, —(CH2)3— or —(CH2)4—; m, n and q are independently 0, 1 or 2. The uppermost temperature of the liquid crystalline phase of the compound is high, and the compound has good compatibility with other compounds and has the necessary characteristics such as optical anisotropy. Also provided are a polymer having many good characteristics of transparency, mechanical strength, coatability, solubility, crystallinity, shrinkage, water permeability, water absorption, melting point, glass transition point, clearing point and chemical resistance; an optically-anisotropic material of the polymer; a liquid-crystal display device that comprises the polymer; and a method for producing the liquid-crystalline compound.
摘要翻译:提供式(1)的液晶可聚合乙烯基酮化合物:优选R 1是氢,卤素,-CN,-CF 3,-CF 3, H 2,-CF 2 H 2,-OCF 3,-OCF 2 H或烷基,烷氧基,烷氧基烷基或 具有1至10个碳原子的烯基; R 2,R 3和R 5是氢; A 4 S 4独立地是1,4-亚环己基,1,4-亚环己基或1,4-亚苯基,其中任何氢可以被卤素取代; Z 1至Z 3独立地为单键, - (CH 2)2 - , - CH- CH-,-CF-CF-,-OCF 2 - 或-CF 2 O-; Z 4是单键, - (CH 2 CH 2)3 - 或 - (CH 2 2 N) 4 SUB> - ; m,n和q独立地为0,1或2.化合物的液晶相的最高温度高,并且该化合物与其它化合物具有良好的相容性,并且具有必要的光学各向异性特性。 还提供了具有透明性,机械强度,可涂布性,溶解性,结晶度,收缩率,透水性,吸水性,熔点,玻璃化转变点,清除点和耐化学性等许多良好特性的聚合物。 聚合物的光学各向异性材料; 包含聚合物的液晶显示装置; 和液晶化合物的制造方法。
摘要:
.alpha.-hydroxyketone derivatives represented by the general formula (I) which are novel optically active compounds; liquid crystal compositions, such as chiral smectic or chiral nematic compositions, containing the derivatives; and liquid crystal devices using the compositions. ##STR1## wherein A and B are independently a radical represented by the general formula (II): ##STR2## wherein R.sup.2 is an aliphatic hydrocarbon having 1 to 16 carbon atoms, which may contain --O-- and may be substituted by a cyano group and/or a halogen atom, ##STR3## are independently a single bond, ##STR4## etc., X and Y are independently a single bond, or --CH.sub.2 CH.sub.2 --, etc., or an aliphatic hydrocarbon having 1 to 16 carbon atoms; R.sup.1 is an alkyl group, a phenyl group, or a cyclohexyl group; n is 0 or 1; and the asterisk (*) indicates an asymmetric carbon atom.
摘要:
An optically active compound having a large spontaneous polarization value and capable of affording a composition exhibiting a suitable ferroelectric liquid crystal temperature range and a liquid crystal composition containing the same are provided, which compound is expressed by the formula ##STR1## wherein either one of R.sup.1 and R.sup.2 represents an alkyl group or an alkoxy group each of 1 to 20 carbon atoms and another thereof represents an optically active group.
摘要翻译:提供具有大的自发极化值并且能够提供具有合适的铁电液晶温度范围的组合物的光学活性化合物和含有该组合物的液晶组合物,该化合物由式(I)表示,其中任一 R 1和R 2之一表示碳原子数为1〜20的烷基或烷氧基,另一个表示光学活性基团。
摘要:
A novel smectic C liquid crystal compound useful as a component of ferroelectric liquid crystal materials capable of effecting high-speed response is provided, which compound is a smectic liquid crystalline 5-alkoxy-2-(4-alkylphenyl)pyrimidine compound expressed by the formula ##STR1## wherein R.sup.1 represents a linear alkyl group of 4 to 20 carbon atoms and R.sup.2 represents a linear alkyl group of 7 to 20 carbon atoms.