公开(公告)号：US08241790B2

公开(公告)日：2012-08-14

申请号：US10629815

申请日：2003-07-30

Applicant: Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Masatoshi Nagayama

Inventor： Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Masatoshi Nagayama

IPC: H01M4/13 ,  H01M4/88 ,  C01G1/00

CPC classification number: H01M4/525 ,  H01M4/131 ,  H01M4/505 ,  H01M10/0525 ,  H01M10/058 ,  H01M2004/021

Abstract: In a non-aqueous electrolyte secondary battery comprising: a negative electrode containing, as a negative electrode active material, at least a material capable of absorbing and desorbing lithium ions or metal lithium; a positive electrode; and an electrolyte, an oxide containing nickel and manganese elements, the material comprising primary particles of the oxide having a twining portion and a superlattice arrangement of a [√{square root over ( )}3×√{square root over ( )}3] R30° when assigned as R3-m is used as a positive electrode active material.

Abstract translation: 一种非水电解质二次电池，其特征在于，包括：至少含有能够吸收和解吸锂离子或金属锂的材料作为负极活性物质的负极; 正极; 以及电解质，含有镍和锰元素的氧化物，所述材料包括氧化物的初级颗粒，其具有缠绕部分和[√{平方根超过（）} 3×√{平方根超过（）} 3的超晶格排列 ] R30°时，将R3-m作为正极活性物质使用。

公开(公告)号：US08221922B2

公开(公告)日：2012-07-17

申请号：US12443799

申请日：2008-04-10

Applicant: Masaki Deguchi ,  Tooru Matsui ,  Hiroshi Yoshizawa

Inventor： Masaki Deguchi ,  Tooru Matsui ,  Hiroshi Yoshizawa

IPC: H01M6/16

CPC classification number: H01M2/1646 ,  H01M2/1653 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0569

Abstract: A non-aqueous electrolyte secondary battery including: a positive electrode that contains a transition metal oxide capable of absorbing and desorbing lithium ions; a negative electrode that is capable of absorbing and desorbing lithium ions; a porous film that is interposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte, wherein at least one selected from inorganic oxide and polyamide is contained in the porous film, and 5 to 15 vol % of ethylene carbonate is contained in a non-aqueous solvent that is contained in the non-aqueous electrolyte.

Abstract translation: 一种非水电解质二次电池，包括：含有能够吸收和解吸锂离子的过渡金属氧化物的正极; 能够吸收和解吸锂离子的负极; 介于正极和负极之间的多孔膜; 和非水电解质，其中在多孔膜中含有选自无机氧化物和聚酰胺中的至少一种，在非水电解质中所含的非水溶剂中含有5〜15体积％的碳酸亚乙酯 。

公开(公告)号：US08187744B2

公开(公告)日：2012-05-29

申请号：US12489940

申请日：2009-06-23

Applicant: Tooru Matsui ,  Tetsuo Nanno ,  Hiroshi Yoshizawa

Inventor： Tooru Matsui ,  Tetsuo Nanno ,  Hiroshi Yoshizawa

IPC: H01M6/04

CPC classification number: H01M10/0569 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0037 ,  H01M2300/004

Abstract: A non-aqueous electrolyte secondary battery is produced using a non-aqueous electrolyte including: a non-aqueous solvent that primarily contains a solvent mixture of ethylene carbonate and propylene carbonate and includes a fluorine-substituted ether having a divalent group represented by a formula: —CFX—CH(CH3)—O—, where X is a hydrogen atom or fluorine atom, in a molecule thereof; and a lithium salt that is dissolved in the non-aqueous solvent. The non-aqueous electrolyte has favorable wettability towards a polyolefin separator, and improves the cycle characteristics and the load characteristics of the non-aqueous electrolyte secondary battery.

Abstract translation: 使用非水电解质制造非水电解质二次电池，所述非水电解质包括：主要含有碳酸亚乙酯和碳酸亚丙酯的溶剂混合物的非水溶剂，并且包括具有由下式表示的二价基团的氟取代的醚： -CFX-CH（CH 3）-O-，其中X为氢原子或氟原子; 和溶解在非水溶剂中的锂盐。 非水电解质对聚烯烃隔膜具有良好的润湿性，并且提高了非水电解质二次电池的循环特性和负载特性。

公开(公告)号：US08153297B2

公开(公告)日：2012-04-10

申请号：US11882684

申请日：2007-08-03

Applicant: Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Masatoshi Nagayama

Inventor： Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Masatoshi Nagayama

IPC: H01M4/00 ,  H01M4/88

CPC classification number: H01M4/525 ,  H01M4/131 ,  H01M4/505 ,  H01M10/0525 ,  H01M10/058 ,  H01M2004/021

Abstract: In a non-aqueous electrolyte secondary battery comprising: a negative electrode containing, as a negative electrode active material, at least a material capable of absorbing and desorbing lithium ions or metal lithium; a positive electrode; and an electrolyte, an oxide containing nickel and manganese elements, the material comprising primary particles of the oxide having a twining portion and a superlattice arrangement of a [√{square root over (3)}×√{square root over (3)}] R30° when assigned as R3-m is used as a positive electrode active material.

Abstract translation: 一种非水电解质二次电池，其特征在于，包括：至少含有能够吸收和解吸锂离子或金属锂的材料作为负极活性物质的负极; 正极; 以及电解质，含有镍和锰元素的氧化物，所述材料包括氧化物的初级颗粒，所述氧化物具有缠绕部分，并且[√{平方根超过（3）}×√{平方根超过（3）}的超晶格排列 ] R30°时，将R3-m作为正极活性物质使用。

公开(公告)号：US08067119B2

公开(公告)日：2011-11-29

申请号：US12096262

申请日：2007-05-18

Applicant: Masaki Deguchi ,  Tooru Matsui ,  Hiroshi Yoshizawa

Inventor： Masaki Deguchi ,  Tooru Matsui ,  Hiroshi Yoshizawa

IPC: H01M6/04 ,  H01M6/16

CPC classification number: H01M10/4235 ,  H01M2/16 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0567

Abstract: A non-aqueous electrolyte secondary battery of the present invention includes a positive electrode including an active material absorbing and desorbing lithium ions, a negative electrode including an active material absorbing and desorbing lithium ions, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The separator includes a material containing a substituent group with electron-withdrawing property. The non-aqueous electrolyte includes a non-aqueous solvent and a solute dissolved therein, and the non-aqueous solvent includes at least one selected from the group consisting of a fluorine-containing aromatic solvent, a fluorine-containing cyclic carbonic acid ester, and a fluorine-containing cyclic carboxylic acid ester.The combination of the foregoing separator and the foregoing non-aqueous electrolyte makes it possible to suppress the deterioration in the rate performance of the battery even when the battery is stored under high voltage and high temperature.

Abstract translation: 本发明的非水电解质二次电池包括：包含吸收和解吸锂离子的活性物质的正极，包含吸收和解吸锂离子的活性物质的负极;插入正极和负极之间的隔膜; 和非水电解质。 隔膜包括含有具有吸电子性的取代基的材料。 非水电解质包含非水溶剂和溶解于其中的溶质，非水溶剂包括选自含氟芳香族溶剂，含氟环状碳酸酯和含氟环状碳酸酯中的至少一种， 含氟环状羧酸酯。 上述隔膜和上述非水电解液的组合使得即使在高电压和高温下储存电池的情况下也可以抑制电池的速率性能的劣化。

公开(公告)号：US07939200B2

公开(公告)日：2011-05-10

申请号：US11430994

申请日：2006-05-10

Applicant: Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Kensuke Nakura

Inventor： Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Kensuke Nakura

IPC: H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525

CPC classification number: H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M2010/4292

Abstract: As an alternative technique to lead-acid batteries, the present invention provides an inexpensive 2 V non-aqueous electrolyte secondary battery having excellent cycle life at a high rate by preventing volume change during charge and discharge. The non-aqueous electrolyte secondary battery uses: a positive electrode active material having a layered structure, being represented by chemical formula Li1±α[Me]O2, where 0≦α

Abstract translation: 作为铅酸蓄电池的替代技术，本发明通过防止充放电期间的体积变化，提供了一种廉价的2V非水电解质二次电池，其通过高速率具有优异的循环寿命。 非水电解质二次电池使用具有层状结构的正极活性物质，由化学式Li1±α[Me] O 2表示，其中0＆nlE;α<0.2，Me是包含Ni的至少一种过渡金属，至少 一种选自Mn，Fe，Co，Ti和Cu，并且包括基本相同比例的元素镍和元素钴; 和Li 4 Ti 5 O 12（Li [Li 1/3 Li 5/3）O 4）的负极活性物质。

公开(公告)号：US07872664B2

公开(公告)日：2011-01-18

申请号：US11525964

申请日：2006-09-25

Applicant: Takeshi Yamakawa ,  Hiroshi Yoshizawa ,  Katsunori Shoji ,  Masanori Namba

Inventor： Takeshi Yamakawa ,  Hiroshi Yoshizawa ,  Katsunori Shoji ,  Masanori Namba

IPC: B41J15/14 ,  B41J27/00

CPC classification number: H04N1/00 ,  B41J2/471 ,  B41J29/12 ,  G03G15/0435 ,  G03G2215/0132 ,  G03G2215/0402 ,  H04N1/00909

Abstract: An optical scanning device, that outputs a light beam through an emission window in an optical housing to scan a surface, may include a shutter member that closes or opens the emission window. The shutter member may include a first opening, that may allow the light beam passed through the emission window to pass the first opening, and a second opening, that may be at a position corresponding to an insertion operation of a cleaning member for cleaning the emission window. The shutter member may include a first opening, that may be on a front surface of the shutter member to allow the light beam passed through the emission window to pass the first opening, and a second opening, that may be on a side surface of the shutter member to allow a cleaning member to be inserted through the second opening for cleaning the emission window.

Abstract translation: 通过光学壳体中的发射窗口输出光束以扫描表面的光学扫描装置可以包括关闭或打开发射窗口的活门构件。 闸门构件可以包括第一开口，其可以允许通过发射窗口的光束通过第一开口，以及第二开口，第二开口可以在对应于用于清洁发射的清洁构件的插入操作的位置 窗口。 活门构件可以包括第一开口，其可以在活门构件的前表面上，以允许通过发射窗的光束通过第一开口，第二开口可以在第二开口的侧表面上 挡板构件，以允许清洁构件通过第二开口插入以清洁排放窗。

公开(公告)号：US07824801B2

公开(公告)日：2010-11-02

申请号：US11301027

申请日：2005-12-13

Applicant: Yasutaka Kogetsu ,  Kazuyoshi Honda ,  Toshitada Sato ,  Hiroshi Yoshizawa

Inventor： Yasutaka Kogetsu ,  Kazuyoshi Honda ,  Toshitada Sato ,  Hiroshi Yoshizawa

IPC: H01M4/58 ,  H01M4/48

CPC classification number: H01M10/0525 ,  H01M4/0426 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/1395 ,  H01M4/366 ,  H01M4/386 ,  H01M4/485 ,  H01M4/525 ,  H01M10/0587 ,  H01M2004/027

Abstract: A negative electrode for a lithium ion secondary battery including a current collector and an active material layer carried on the current collector, wherein the active material layer includes a first layer and a second layer alternately laminated in a thickness direction of the active material layer, and wherein the first layer includes silicon or silicon and a small amount of oxygen and the second layer includes silicon and a larger amount of oxygen than the first layer. With the use of the negative electrode, it is possible to provide a high capacity lithium ion secondary battery having excellent high rate charge/discharge characteristics and superior cycle characteristics.

Abstract translation: 1.一种锂离子二次电池用负极，其包含集电体和承载在集电体上的活性物质层的锂离子二次电池，其特征在于，所述活性物质层包括在活性物质层的厚度方向上交替层叠的第一层和第二层， 其中所述第一层包括硅或硅和少量的氧，并且所述第二层包括硅和比所述第一层更大量的氧。 通过使用负极，可以提供具有优异的高速率充放电特性和优异的循环特性的高容量锂离子二次电池。

公开(公告)号：US07579114B2

公开(公告)日：2009-08-25

申请号：US11531887

申请日：2006-09-14

Applicant: Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Masatoshi Nagayama

Inventor： Tsutomu Ohzuku ,  Hiroshi Yoshizawa ,  Masatoshi Nagayama

IPC: H01M4/04 ,  H01M4/50 ,  H01M4/52

CPC classification number: H01M4/1391 ,  B01J19/1875 ,  B01J19/1881 ,  C01B13/363 ,  C01G45/1228 ,  C01G51/42 ,  C01G51/50 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/20 ,  C01P2002/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525 ,  Y10T29/49108

Abstract: A positive electrode active material for a non-aqueous electrolyte battery comprising a lithium-containing transition metal oxide, produced with the use of a dry precursor obtained by: introducing an alkaline solution together with an aqueous solution containing two or more of transition metal salts or two kinds or more of aqueous solutions of different transition metal salts into a reaction vessel to obtain a hydroxide or an oxide as a precursor through coprecipitation with a reductant being coexistent or an inert gas being supplied; and drying the precursor at 300 to 500° C. to obtain a dry precursor.

Abstract translation: 一种非水电解质电池用正极活性物质，其特征在于，含有含锂过渡金属氧化物，其使用干燥前体制造，所述干燥前体通过：将碱性溶液与含有两种以上过渡金属盐的水溶液 两种或更多种不同过渡金属盐的水溶液进入反应容器，以通过共存的还原剂或供应的惰性气体通过共沉淀获得氢氧化物或氧化物作为前体; 并在300〜500℃下干燥前体，得到干燥前体。

公开(公告)号：US20090130565A1

公开(公告)日：2009-05-21

申请号：US11919419

申请日：2006-07-13

Applicant: Tooru Matsui ,  Masaki Deguchi ,  Hiroshi Yoshizawa

Inventor： Tooru Matsui ,  Masaki Deguchi ,  Hiroshi Yoshizawa

IPC: H01M6/16 ,  H01G9/022 ,  H01G9/00 ,  H01M4/36

CPC classification number: H01G9/038 ,  H01G11/58 ,  H01G11/60 ,  H01G11/62 ,  H01M6/162 ,  H01M6/164 ,  H01M6/168 ,  H01M10/0566 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/13

Abstract: A non-aqueous electrolyte of the present invention contains a lithium salt (A), a quaternary ammonium salt (B) containing a straight chain alkyl group having carbon atoms of 4 or less and a solvent (C) composed of at least one compound selected from the group consisting of ethylene carbonate, propylene carbonate, butylene carbonate, γ-butyrolactone, dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, dimethoxyethane, ethoxymethoxyethane and diethoxyethane. The molar ratio C/A of the solvent (C) to the lithium salt (A) or the molar ratio C/B of the solvent (C) to the ammonium salt (B) is 6 or less. The non-aqueous electrolyte has a single phase. Consequently, there can be obtained a non-aqueous electrolyte of a high ion concentration having an excellent oxidation resistance and reduction resistance.

Abstract translation: 本发明的非水电解质含有锂盐（A），含有碳原子数为4以下的直链烷基的季铵盐（B）和选自由至少一种化合物构成的溶剂（C） 由碳酸亚乙酯，碳酸亚丙酯，碳酸亚丁酯，γ-丁内酯，碳酸二甲酯，碳酸甲乙酯，碳酸二乙酯，二甲氧基乙烷，乙氧基甲氧基乙烷，二乙氧基乙烷构成的组。 溶剂（C）与锂盐（A）的摩尔比C / A或溶剂（C）与铵盐（B）的摩尔比C / B为6以下。 非水电解质具有单相。 因此，可以获得具有优异的抗氧化性和耐还原性的高离子浓度的非水电解质。