Abstract:
The present invention relates to a battery separator including: a porous substrate; and a layer of a crosslinked polymer supported on at least one surface of the porous substrate, in which the crosslinked polymer is obtained by reacting (a) a reactive polymer having, in the molecule thereof, a first reactive group containing active hydrogen and a second reactive group having cationic polymerizability with (b) a polycarbonate urethane prepolymer terminated by an isocyanate group.
Abstract:
A battery separator (13) of the present invention includes a porous film (12) serving as a substrate and a crosslinked polymer layer (11) supported on the porous film (12). The crosslinked polymer layer (11) contains a crosslinked polymer and inorganic particles, and is non-porous. The crosslinked polymer is obtained by reacting a reactive polymer having a functional group in its molecule with a polyfunctional compound reactive with the functional group so as to crosslink at least a part of the reactive polymer. A lithium ion secondary battery of the present invention includes a positive electrode (14), a negative electrode (15), the battery separator (13) of the present invention disposed between the positive electrode (14) and the negative electrode (15), and a non-aqueous electrolyte solution. The battery separator (13) is disposed so that the porous film (12) faces the negative electrode (15) and the crosslinked polymer layer (11) faces the positive electrode (14).
Abstract:
The present invention relates to a crosslinking polymer-supported porous film for battery separator, including: a porous film; and a crosslinking polymer supported on the porous film, the crosslinking polymer having a plurality of cation-polymerizable functional groups in the molecule thereof and having oxyalkylene groups represented by general formula (I): in which the Rs may be the same or different and each independently represent a hydrogen atom or a methyl group, and n represents an integer of 4 to 9, in a side chain thereof.
Abstract:
The invention provides a battery separator comprising a porous resin film and a crosslinked polymer supported thereon and having iminodiacetic acid groups in side chains of the polymer chains. The iminodiacetic acid group is preferably represented by the formula wherein M1 and M2 are each independently a hydrogen atom, a lithium atom, a potassium atom, a sodium atom, or triethylamine. It is preferred that the layer of the crosslinked polymer is substantially nonporous or solid, and ion conductive, and that the crosslinked polymer has in the molecule oxetanyl groups which are capable of cation polymerization.
Abstract:
The present invention relates to a battery separator including: a porous substrate; and a layer of a crosslinked polymer supported on at least one surface of the porous substrate, in which the crosslinked polymer is obtained by reacting (a) a reactive polymer having, in the molecule thereof, a first reactive group containing active hydrogen and a second reactive group having cationic polymerizability with (b) a polycarbonate urethane prepolymer terminated by an isocyanate group.
Abstract:
A solid electrolytic capacitor having an anode of valve metal or of an alloy of which main component is the valve metal; a dielectric layer formed by anodizing the anode; an electrolyte layer formed on the dielectric layer; and a cathode formed on the electrolyte layer; wherein the cathode has a carbon layer containing coated carbon particles in which at least a part of the surface of carbon particles is coated with metal and/or metal compound having higher conductivity than carbon.
Abstract:
The invention provides a nonaqueous electrolyte secondary battery having a cathode and an anode arranged so as to be opposite to each other, and an electrolyte layer put therebetween; wherein the cathode comprises: (a) a conductive polymer and (b) at least one selected from the group consisting of a polycarboxylic acid and a metal salt thereof, and wherein the anode comprises a material into which a base metal or ions thereof can be inserted and from which a base metal or ions thereof can be extracted. The invention further provides a cathode sheet for use in the nonaqueous electrolyte secondary battery mentioned above.
Abstract:
The present invention provides a nonaqueous electrolyte electricity storage device including a separator that can be produced by a method in which use of a solvent that places a large load on the environment can be avoided and in which control of parameters such as the pore diameter is relatively easy, the nonaqueous electrolyte electricity storage device being capable of trapping ions of metals that tend to form a complex other than lithium. The present invention is a nonaqueous electrolyte electricity storage device including a cathode, an anode, a separator disposed between the cathode and the anode, and an electrolyte having ion conductivity. The cathode and/or the anode is formed of a material containing at least one metal element selected from the group consisting of transition metals, aluminum, tin, and silicon. The separator includes a porous epoxy resin body having a porous structure with a specific surface area of 5 to 60 m2/g, and the porous epoxy resin body contains at least one amino group selected from the group consisting of a primary amino group, a secondary amino group, and a tertiary amino group.
Abstract:
Provided is a separator for nonaqueous electrolyte electricity storage devices that includes an improved porous epoxy resin membrane. At least one compound selected from a carboxylic acid, a carboxylic acid salt, a carboxylic acid anhydride, and a carboxylic acid halide, is brought into contact with a porous epoxy resin membrane, and thus hydroxyl groups contained in the porous membrane are reacted with the compound to produce carboxylic acid ester bonds. As a result of this treatment, the amount of active hydroxyl groups present in the porous epoxy resin membrane is reduced, and the porous epoxy resin membrane becomes suitable as a separator for nonaqueous electrolyte electricity storage devices. An epoxy resin sheet yet to be made porous may be subjected to reaction with the compound.
Abstract:
The present invention relates to a battery separator including: a porous substrate; and a layer of a crosslinked polymer supported on at least one surface of the porous substrate, in which the crosslinked polymer is obtained by reacting (a) a reactive polymer having, in the molecule thereof, a reactive group containing active hydrogen with (b) a polycarbonate urethane prepolymer terminated by an isocyanate group.