公开(公告)号：US5446181A

公开(公告)日：1995-08-29

申请号：US140955

申请日：1993-10-25

申请人： Katsuhiro Uehara ,  Mikio Endo ,  Hitoyuki Araki ,  Takeo Arai ,  Yasuhiro Kawase

发明人： Katsuhiro Uehara ,  Mikio Endo ,  Hitoyuki Araki ,  Takeo Arai ,  Yasuhiro Kawase

IPC分类号： B01D3/00 ,  B01J8/02 ,  B01J19/24 ,  C07F7/18 ,  C07F7/10

CPC分类号： C07F7/1892 ,  B01D3/009 ,  B01J19/2415 ,  B01J8/02 ,  B01J2208/00061 ,  B01J2208/00176 ,  B01J2208/00247 ,  B01J2208/00557 ,  Y02P20/127

摘要： The invention produces a 3-[N-(2-aminoethyl)]aminopropylalkoxysilane in high yields by reacting a 3-chloropropylalkoxysilane with ethylene diamine. A distillation pot is charged with ethylene diamine and heated above the boiling point of ethylene diamine for evaporating ethylene diamine, which is then condensed into a liquid. The liquid ethylene diamine is mixed for reaction with a 3-chloropropylalkoxysilane in such a proportion to give a molar ratio of ethylene diamine/3-chloropropylalkoxysilane of at least 12/1, thereby forming a 3-[N-(2-aminoethyl)]aminopropylalkoxysilane. The reaction solution is fed back to the pot where the unreacted ethylene diamine in the reaction solution is evaporated again and then condensed for use in a next cycle of reaction. The apparatus includes a distillation pot, a reflux condenser, a feed means and a reactor connected to form a recirculating system.

摘要翻译： 本发明通过使3-氯丙基烷氧基硅烷与乙二胺反应，以高收率产生3- [N-（2-氨基乙基）]氨丙基烷氧基硅烷。 蒸馏釜中加入乙二胺并加热到乙二胺的沸点以蒸发乙二胺，然后将其冷凝成液体。 将液体乙二胺与3-氯丙基烷氧基硅烷按比例混合，得到至少12/1的乙二胺/ 3-氯丙基烷氧基硅烷的摩尔比，由此形成3- [N-（2-氨基乙基）] 氨丙基烷氧基硅烷。 将反应溶液反馈回锅中，反应溶液中的未反应的乙二胺再次蒸发，然后在下一个反应循环中冷凝。 该装置包括蒸馏罐，回流冷凝器，进料装置和连接以形成再循环系统的反应器。

公开(公告)号：US3983180A

公开(公告)日：1976-09-28

申请号：US511208

申请日：1974-10-02

申请人： Kiichi Habata ,  Shozo Tanaka ,  Hitoyuki Araki

发明人： Kiichi Habata ,  Shozo Tanaka ,  Hitoyuki Araki

IPC分类号： C07C17/00 ,  C07C17/16 ,  C07C17/38 ,  C07C17/383 ,  C07C19/03 ,  C07C67/00

CPC分类号： C07C19/03 ,  C07C17/16 ,  C07C17/38

摘要： A process for preparing methyl chloride by reacting hydrogen chloride with methanol in the liquid-phase non-catalytic reaction, employing a reaction system comprising a reactor and two distillation columns, each being operated under a different pressure, to greatly increase the space time yield and the conversion of hydrogen chloride and methanol, and at the same time to reduce the production of dimethyl ether as a byproduct. The raw materials used may be either gaseous or liquid; they may contain a large amount of water or gases insoluble in water. By this process, hydrogen chloride gas and diluted hydrochloric acid that are produced as a byproduct or waste in various chemical processes can be effectively utilized.

摘要翻译： 一种在液相非催化反应中使氯化氢与甲醇反应制备氯甲烷的方法，采用包含反应器和两个蒸馏塔的反应体系，每个蒸馏塔在不同的压力下操作，大大增加了空间产率和 氯化氢和甲醇的转化，同时减少二甲醚作为副产物的生产。 使用的原料可以是气体或液体; 它们可能含有大量不溶于水的水或气体。 通过该方法，可以有效地利用作为副产物或废弃物在各种化学过程中产生的氯化氢气体和稀盐酸。