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1.发明授权Block polymers of poly(tetramethylene oxide) and tetrahydrofuran/alkylene oxide copolymers 失效聚（四氢呋喃）和四氢呋喃/烯化氧共聚物的嵌段聚合物
公开(公告)号：US4211854A
公开(公告)日：1980-07-08
申请号：US935508
申请日：1978-08-21
申请人： Ivan M. Robinson
发明人： Ivan M. Robinson
CPC分类号： C08G65/08 , C08G18/4854 , C08G65/20
摘要： Block polymers containing poly(tetramethylene oxide) as one of their constituent blocks and a random copolymer of tetrahydrofuran and one or more alkylene oxides as one or more of the other constituent blocks are useful in preparing polyurethanes and polyesters.
摘要翻译： 含有聚（四氢呋喃）作为其构成嵌段之一的嵌段聚合物和四氢呋喃与一种或多种环氧烷烃的无规共聚物作为一种或多种其它构成嵌段，可用于制备聚氨酯和聚酯。
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2.发明授权Polyurethanes prepared with tetrahydrofuran-alkylene oxide polymerizates having low oligomeric cyclic ether content 失效用四氢呋喃 - 环氧烷聚合物制备的聚氨酯具有低的低聚环醚含量
公开(公告)号：US4224432A
公开(公告)日：1980-09-23
申请号：US966602
申请日：1978-12-11
IPC分类号： C08G18/48
CPC分类号： C08G18/4854
摘要： The resistance to degradation on exposure to high temperatures, water and organic liquids of a polyurethane prepared by reacting a tetrahydrofuran/alkylene oxide polymerizate, an organic polyisocyanate and a chain extender is significantly improved by using a tetrahydrofuran/alkylene oxide polymerizate which contains no more than about 3%, by weight, of oligomeric cyclic ethers.
摘要翻译： 通过使四氢呋喃/烯化氧聚合物，有机多异氰酸酯和扩链剂反应制得的聚氨酯制备的聚氨酯暴露于高温下的水分和有机液体的耐受性通过使用四氢呋喃/烯化氧聚合物，其不超过 约3重量％的低聚环醚。
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公开(公告)号：US4202964A
公开(公告)日：1980-05-13
申请号：US962311
申请日：1978-11-27
CPC分类号： C08G65/20 , C08G18/4854 , C08G65/30
摘要： The oligomeric cyclic ether content of a tetrahydrofuran/alkylene oxide polymerizate is significantly reduced by bringing the polymerizate into contact at elevated temperatures with an ion exchange resin bearing -SO.sub.3 H groups.
摘要翻译： 通过使带有-SO 3 H基团的离子交换树脂在高温下使聚合物接触，四氢呋喃/烯化氧聚合物的低聚环醚含量显着降低。
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4.发明授权Polymeric carbonate diols of copolyether glycols and polyurethanes prepared therefrom 失效共聚醚二醇的聚碳酸酯二醇和由其制备的聚氨酯
公开(公告)号：US4476293A
公开(公告)日：1984-10-09
申请号：US460569
申请日：1983-01-24
申请人： Ivan M. Robinson
发明人： Ivan M. Robinson
CPC分类号： C08G18/44
摘要： Polymeric carbonate diols are prepared by coupling segments of copolyether glycols with a dialkyl carbonate, with a cyclic carbonate, or with phosgene.The carbonate diols are useful in preparing polyurethanes.
摘要翻译： 通过将共聚醚二醇与碳酸二烷基酯，环状碳酸酯或光气偶联来制备聚碳酸酯二醇。 碳酸二酯可用于制备聚氨酯。
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5.发明授权Sulfur-modified copolyether glycols, a method for preparing them, and polyurethanes prepared therefrom 失效硫改性共聚醚二醇，其制备方法和由其制备的聚氨酯
公开(公告)号：US4374970A
公开(公告)日：1983-02-22
申请号：US281202
申请日：1981-07-07
申请人： Ivan M. Robinson
发明人： Ivan M. Robinson
IPC分类号： C08G18/50 , C08G18/52 , C08G65/334 , C08G65/34 , C09K3/00
CPC分类号： C08G65/334 , C08G18/5072 , C08G18/52 , C08G65/34 , Y10S521/914
摘要： Copolyether glycols are modified so that they contain 1-25%, by weight of .beta.,.beta.'-dihydroxyalkyl sulfide moieties.These modified copolyether glycols have enhanced resistance to degradation by heat and oxygen.The invention also relates to a method of making the modified copolyether glycols, to their use as stabilizers against the degradation of the polyether chains, and to polyurethanes made with them.
摘要翻译： 共聚醚二醇被修饰，使得它们含有1-25重量％的β，β'-二羟烷基硫醚部分。 这些改性的共聚醚二醇具有增强的耐受热和氧降解的能力。 本发明还涉及制备改性共聚醚二醇的方法，其用作防止聚醚链降解的稳定剂，以及用它们制备的聚氨酯。
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6.发明授权Sulfur-modified polytetramethylene ether glycols, a method for preparing them, and polyurethanes prepared therefrom 失效硫改性聚四亚甲基醚二醇，其制备方法和由其制备的聚氨酯
公开(公告)号：US4371687A
公开(公告)日：1983-02-01
申请号：US281198
申请日：1981-07-07
申请人： Ivan M. Robinson
发明人： Ivan M. Robinson
CPC分类号： C08G18/52 , C08G18/5072
摘要： Polytetramethylene ether glycol is modified so that it contains 1-25%, by weight of .beta.,.beta.'-dihydroxyalkyl sulfide moieties.These modified polytetramethylene ether glycols have enhanced resistance to degradation by heat and oxygen.The invention also relates to a method of making the modified PTMEG's, to their use as stabilizers against the degradation of the polyether chain, and to polyurethanes made with them.
摘要翻译： 改性聚四亚甲基醚二醇，使其含有1-25％（重量）的β，β'-二羟烷基硫醚部分。 这些改性的聚四亚甲基醚二醇具有增强的耐受热和氧降解的能力。 本发明还涉及一种制备改性PTMEG作为防止聚醚链降解的稳定剂以及用它们制备的聚氨酯的方法。
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7.发明授权Copolyether glycols of tetrahydrofuran and alkylene oxides having low oligomeric cyclic ether content 失效具有低低聚环醚含量的四氢呋喃和烯化氧的共聚醚二醇
公开(公告)号：US4251654A
公开(公告)日：1981-02-17
申请号：US67352
申请日：1979-08-14
摘要： Tetrahydrofuran/alkylene oxide polymerizates containing no more than 3%, by weight, of oligomeric cyclic ethers are prepared by extracting the ethers from a raw polymerizate with water.
摘要翻译： 通过用水提取原料聚合物的醚制备含有不超过3重量％的低聚环醚的四氢呋喃/烯化氧聚合物。
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8.发明授权Block polymers of hydroxyalkyl phthalate esters and tetrahydrofuran/alkylene oxide copolymers 失效羟基烷基邻苯二甲酸酯和四氢呋喃/烯化氧共聚物的嵌段聚合物
公开(公告)号：US4233436A
公开(公告)日：1980-11-11
申请号：US011717
申请日：1979-02-12
申请人： Ivan M. Robinson
发明人： Ivan M. Robinson
IPC分类号： C08G18/42 , C08G63/672 , C08G63/06 , C08G63/60 , C08L67/04
CPC分类号： C08G18/4261 , C08G63/672
摘要： Block polymers containing an hydroxyalkyl phthalate ester as one of the constituent blocks and a copolymer of tetrahydrofuran and one or more alkylene oxides as one or more of the other constituent blocks are useful in preparing polyurethanes and polyesters.
摘要翻译： 含有邻苯二甲酸羟烷基酯作为构成嵌段之一的嵌段聚合物和四氢呋喃与作为一种或多种其它构成嵌段的一种或多种烯化氧的共聚物可用于制备聚氨酯和聚酯。
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9.发明授权Block polymers of hydroquinone di-(.beta.-hydroxyalkyl) ethers or isomers thereof and tetrahydrofuran/alkylene oxide copolymers 失效氢醌二（β-羟烷基）醚或其异构体和四氢呋喃/烯化氧共聚物的嵌段聚合物
公开(公告)号：US4211862A
公开(公告)日：1980-07-08
申请号：US951387
申请日：1978-10-16
CPC分类号： C08G18/4854 , C08G18/4879 , C08G65/08 , C08G65/20 , C08G65/2612 , C08L2205/05
摘要： Block polymers containing hydroquinone di-(.beta.-hydroxyethyl) ether or one of its isomers or homologs as one of the constitutent blocks and a random copolymer of tetrahydrofuran and one or more alkylene oxides as one or more of the other constituent blocks are useful in preparing polyurethanes and polyesters.
摘要翻译： 含有氢醌二（β-羟乙基）醚或其异构体之一的嵌段聚合物或作为组分嵌段之一的同系物和作为一种或多种其它组分嵌段的四氢呋喃和一种或多种环氧烷烃的无规共聚物可用于制备 聚氨酯和聚酯。
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公开(公告)号：US4163115A
公开(公告)日：1979-07-31
申请号：US869272
申请日：1978-01-13
CPC分类号： C08G65/20
摘要： Esters of poly(tetramethylene ether) glycol are prepared by polymerizing tetrahydrofuran in a reaction mixture which contains, in addition to the tetrahydrofuran, and acylium ion precursor such as acetic anhydride, a polymeric catalyst which contains sulfonic acid groups and, optionally, a carboxylic acid such as acetic acid.
摘要翻译： 聚（四亚甲基醚）二醇的酯通过在包含四氢呋喃和酰基离子前体如乙酸酐的反应混合物中聚合四氢呋喃来制备，含有磺酸基的聚合催化剂和任选的羧酸 如乙酸。
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