摘要:
A process for preparing an emulsion is disclosed. The process entails mixing an aqueous mineral acid that contains phosphorous in an organic solvent, the mixing being continuous and with the degree of intensity sufficient to form a homogeneous emulsion. The emulsion prepared by the process is useful in the process of preparing polycarbonate by the interfacial process. Accordingly the washed organic polycarbonate that has been washed without the use of a phosphorous containing mineral acid solution is mixed with the novel emulsion. The resulting polycarbonate is characterized by its improved thermal stability.
摘要:
A process for producing polymer pellets is disclosed. The process that is particular suitable for making polycarbonate pellets entails extruding a polymer melt, cooling the extrudate by contacting it with a cooling fluid and pelletizing the solidified polymer. The process is characterized in that the cooling fluid has a solids particle content of at most 10 ppm.
摘要:
A device and process for the removal of volatile constituents from polymers is disclosed. The device entails a container having an inlet for a polymer solution, an outlet for the volatile components, an outflow for the polymer from which the volatile components have been removed and a heat exchanger. The heat exchanger is characterized in that it contains a plurality of specially structured channels.
摘要:
An improvement in the continuous two-phase interfacial condensation process for preparing polycarbonate is disclosed. In the process that entails at least one diphenol, phosgene, at least one chain terminator, and optionally branching agents and is carried out in the presence of a catalyst the improvement comprising maintaining the concentration of the catalyst at a level of at least 0.012 mol per mol of diphenol.
摘要:
The present invention provides a polycarbonate having a low particle content, a process for producing high-purity polycarbonate and polycarbonate of maximum purity and molded products made from such polycarbonate.
摘要:
This invention relates to a multistep process for evaporating polymer solutions of thermoplastic polymers and for removing volatile constituents from thermoplastic polymers by indirect heat exchange. The invention relates in particular to a process for evaporating volatile constituents out of polymer solutions using shell-and-tube heat exchangers having a special geometry, coiled-tube evaporators and extrusion evaporators.
摘要:
A process for producing phosgene having low content of carbon tetrachloride is disclosed. The process entails reacting carbon monoxide with chlorine in the presence of elemental carbon, in a reactor. Critically the temperature of the gas stream emerging from the reactor is restricted to 30 to 80° C. and its pressure, measured directly downstream from said reactor is restricted to 120 to 400 kPaabs. The phosgene thus produced has a content of carbon tetrachloride that is less than 150 ppm.
摘要:
A strand devolatilizer that includes a degassing container, a product inlet, a product distributor, a product outlet and a vapor outlet is disclosed. The product distributor is in the form of a tube distributor with at least one distributor tube (1) and a plurality of die tubes (2) arranged in parallel, each containing a plurality of apertures (15) in the tube wall. The die tubes (2) are preferably arranged in several planes one above the other and staggered laterally relative to one another.
摘要:
A process for the production of polycarbonate is disclosed. The process, representing an improvement over the known interfacial polycondensation process entails introducing into the loop of a circulating reactor that additionally contains, a residence tank, an optional mixer, a pump, and a heat exchanger (i) an organic phase that contains a solvent for polycarbonate and phosgene and (ii) an aqueous phase that contains an aqueous lye solution, a dihydroxy compound and an optional monophenol to form an emulsion. Maintaining specified temperature and process conditions results in polycarbonate resin having good properties and in waste water that are characterized by their purity.