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    Process for making triglyceride plasticizer
    2.
    发明授权
    Process for making triglyceride plasticizer 有权
    制备甘油三酯增塑剂的方法

    公开(公告)号：US08771815B2

    公开(公告)日：2014-07-08

    申请号：US12971629

    申请日：2010-12-17

    申请人： Jihad Mohammed Dakka ,  Edmund John Mozeleski

    发明人： Jihad Mohammed Dakka ,  Edmund John Mozeleski

    IPC分类号： C08K5/103 ,  C08K5/101

    CPC分类号： C07C67/08 ,  C08K5/0016 ,  C08K5/103 ,  C08L23/0853 ,  C08L91/00 ,  Y02P20/582 ,  Y10T428/1352 ,  Y10T428/139 ,  C07C69/30 ,  C08L27/06

    摘要： Provided are processes for making, and processes for using triglycerides as plasticizers. The process for making the triglyceride plasticizer includes: (i) recovering at least one linear C4 to C10 aldehyde, one branched C4 to C10 aldehyde, or a combination thereof from a hydroformylation product; (ii) oxidizing the linear, branched or combination thereof C4 to C10 aldehyde to form a linear, branched or combination thereof C4 to C10 acid; (iii) esterifying the linear, branched or combination thereof C4 to C10 acid with a polyol to yield a linear alkyl triglyceride, a branched alkyl triglyceride, or a combination thereof, and reaction byproducts; (iv) purifying the linear, branched or combination thereof alkyl triglyceride to form a plasticizer stream, a reaction byproduct stream, and an unreacted input stream, wherein the total carbon number of the triester groups ranges from 20 to 25 for greater than or equal to 45 wt % of the plasticizer; and (v) recycling from the purifying step back to the esterifying step the unreacted input stream and the reaction byproduct stream.

    摘要翻译： 提供了制备方法和使用甘油三酯作为增塑剂的方法。 制备甘油三酯增塑剂的方法包括：（i）从加氢甲酰化产物中回收至少一种线性C 4至C 10醛，一个支链C 4至C 10醛或其组合; （ii）将其直链，支链或其组合C4至C10醛氧化以形成其直链，支链或其组合C4至C10的酸; （iii）用多元醇酯化其直链，支链或其组合C4至C10酸，得到直链烷基甘油三酯，支链烷基甘油三酸酯或其组合，以及反应副产物; （iv）纯化其直链，支链或其组合的烷基甘油三酸酯以形成增塑剂流，反应副产物流和未反应的输入流，其中三酯基团的总碳数在20至25之间，大于或等于 45重量％的增塑剂; 和（v）从净化步骤回收到酯化步骤未反应的输入流和反应副产物流。

    Process for making olefin oligomers and alkyl benzenes in the presence of mixed metal oxide catalysts
    8.
    发明申请
    Process for making olefin oligomers and alkyl benzenes in the presence of mixed metal oxide catalysts 有权
    在混合金属氧化物催化剂存在下制备烯烃低聚物和烷基苯的方法

    公开(公告)号：US20090163608A1

    公开(公告)日：2009-06-25

    申请号：US12005027

    申请日：2007-12-21

    申请人： Jihad Mohammed Dakka ,  Jeffrey T. Elks ,  James C. Vartuli

    发明人： Jihad Mohammed Dakka ,  Jeffrey T. Elks ,  James C. Vartuli

    IPC分类号： C07C27/22

    CPC分类号： C07C2/10 ,  B01J23/002 ,  B01J23/10 ,  B01J23/30 ,  B01J23/888 ,  B01J27/16 ,  B01J27/1804 ,  B01J27/1853 ,  B01J27/188 ,  B01J37/03 ,  B01J2523/00 ,  C07C2/66 ,  C07C2521/06 ,  C07C2523/10 ,  C07C2523/30 ,  C07C2523/745 ,  C07C2529/48 ,  B01J2523/48 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/3712 ,  B01J2523/31 ,  B01J2523/51

    摘要： Provided is a process for oligomerizing n-olefins. The process has the step of reacting (oligomerizing) an amount of one or more n-olefins in the presence of a catalytically effective amount of a two or more metal oxides at a temperature effective to effect oligomerization. The two or more metal oxides are represented by the formula MOn/M′On′. M and M′, are, independently, selected from the group consisting of Al, Ce, Fe, P, W, Zr, and combinations thereof. M and M′ are different metals or combinations of metals. “n” and “n′” are positive numbers and vary stoichiometrically depending on the valency of M and M′, respectively. Provided is also a process for alkylation of an alkylatable aromatic compound. The process has the step of contacting an amount of one or more n-olefins with an amount of aromatic compound in the presence of a catalytically effective amount of the two or more metal oxides at a temperature effective to effect alkylation of the aromatic compound.

    摘要翻译： 提供了一种使正烯烃低聚的方法。 该方法在有效地进行低聚反应的温度下，在催化有效量的两种或更多种金属氧化物的存在下，使一定量的一种或多种正构烯烃反应（低聚）。 两种或更多种金属氧化物由式MOn / M'On'表示。 M和M'独立地选自Al，Ce，Fe，P，W，Zr及其组合。 M和M'是不同的金属或金属的组合。 “n”和“n”分别为正数，并且分别取决于M和M'的化合价而化学计量。 还提供了可烷基化芳族化合物的烷基化方法。 该方法具有在有效量的芳族化合物烷基化的温度下，在催化有效量的两种或更多种金属氧化物的存在下，使一定量的一种或多种正构烯烃与一定量芳族化合物接触的步骤。

    Process for oxidizing alkylaromatic compounds
    10.
    发明申请
    Process for oxidizing alkylaromatic compounds 有权
    氧化烷基芳族化合物的方法

    公开(公告)号：US20080033217A1

    公开(公告)日：2008-02-07

    申请号：US11827952

    申请日：2007-07-13

    申请人： Jihad Mohammed Dakka ,  Doron Levin ,  John Scott Buchanan ,  Jon Edmond Randolph Stanat

    发明人： Jihad Mohammed Dakka ,  Doron Levin ,  John Scott Buchanan ,  Jon Edmond Randolph Stanat

    IPC分类号： C07C37/08

    CPC分类号： C07C409/08 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C409/14 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/10 ,  C07C49/04 ,  C07C49/403 ,  C07C39/04

    摘要： In a process for oxidizing alkylaromatic compounds to the corresponding hydroperoxide, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of an added catalyst comprising tert-butyl hydroperoxide and in the absence of any other catalyst, to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I). The hydroperoxide may then be converted into a phenol and a ketone of the general formula R1COCH2R2 (III), in which R1 and R2 have the same meaning as in formula (I).

    摘要翻译： 在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有 如果R 1和R 2可以连接形成具有4至10个碳原子的环状基团，则所述环状基团任选被取代 ，R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基与氧在含叔丁基过氧化氢的加成催化剂存在下与氧接触， 不存在任何其它催化剂，以产生通式（II）的氢过氧化物：其中R 1，R 2和R 3 3具有 与式（I）中相同的含义。 然后将氢过氧化物转化成通式为R 1，R 2，R 2，（III）的苯酚和酮，其中R ＆lt; SUP＆gt;和＆lt; 2＆gt;具有与式（I）中相同的含义。