摘要:
Disclosed is a continuous electrorefining device for recovering metal uranium. The electrorefining device comprises an electrolytic cell 10 having an internal accommodating space filled with electrolyte; a cathode unit 20 including a top plate 22, connecting rods 21 whose top ends are joined to the top plate 22, and cathode electrodes 24 whose top end is joined to lower plates; an anode unit 40 which is placed in a cylinder shape surrounding the cathode electrodes 24; a uranium recovery unit 50 for drawing out the uranium metal by a first drawing-out means; and a transition metal recovery unit 60 for drawing out the metal particles by a second drawing-out means. The cathode unit 20 further comprises an insulating and vibration absorbing member that is interposed between the top plate 22 and the cover plate 12; and a vibration means which is mounted on the top plate 22 to transmit vibration and impact force to the cathode electrode 24 through the connecting rods 21.
摘要:
Disclosed is a structural alloy with oxidation resistance for electrolytic reduction equipment for treatment of spent nuclear fuel. More particularly, the present invention relates to a structural alloy with oxidation resistance for electrolytic reduction equipment for treatment of spent nuclear fuel wherein Cr, Si, Al, Nb and Ti are added to a Ni-based substrate so as to form an oxide coating film which is stable in a LiCl—Li2O molten salt and, in addition, a process thereof and use of the same.
摘要:
Provided is a substrate for forming a pattern comprising an inorganic layer having a modified surface, wherein the modified surface is formed by coating a surface of the inorganic layer with a bifunctional molecule comprising a functional group having an affinity for a nanocrystal at one end of the molecule and a functional group having an affinity for the inorganic layer at the other end of the molecule. A method for forming a pattern of nanocrystals is also provided.
摘要:
Disclosed herein is a continuous electrolytic refining device for metal uranium, the device comprising a cathode section fixed to the lower side of the heat radiation plate, and having a plurality of graphite cathodes; an anode section encompassing the cathode section to face the cathode section, rotatably fixed to the lower side of the heat radiation plate, and receiving the used nuclear fuel; an electrolytic cell receiving the cathode section and the anode section and filled with electrolytes so as to sink the cathode section and the anode section; an uranium collecting section collecting metal uranium deposited on and detached from the graphite cathode in the lower side of the cathode section inside the electrolytic cell and withdrawing the collected metal uranium to the outside of the electrolytic cell; and a transition metal collecting section coupled with the lower side of the electrolytic cell to withdraw the transition metal particles released from the anode section and collected in the lower side of the electrolytic cell, in order to collect high pure uranium deposits and metal transition elements created in an electrolysis process without stopping an electrolysis process, not including a scrapping process.
摘要:
Disclosed herein is a method of preparing uranium metal by electrorefining uranium metal, comprising: applying a predetermined current to an anode electrode included in an anode basket receiving fuel segments made of uranium metal and a cathode electrode of carbon material; electrodepositing uranium on the cathode electrode in accordance with the reaction initiated by the applied current; and collecting the electrodeposited uranium by self-weight. An apparatus for electrorefining uranium metal used in the method according to the present invention, comprises: an anode basket (6) receiving fuel segments made of uranium metal and comprising an anode electrode; and a reactor including a cathode electrode (5) made of carbon material and a uranium collector (10) therein. According to the method of the present invention having the above mentioned constitution and the apparatus thereof, it is possible to separate only pure uranium metal with a high capability from the spent metal nuclear fuels conveniently and economically.
摘要:
Disclosed are a czochralski apparatus for growing crystals and a purification method of waste salts using the same. More particularly, the present invention provides a czochralski apparatus for growing crystals comprising screw thread for fixing salt crystals mounted on a pulling bar of the apparatus in order to prevent desorption of crystals caused by load thereof during a crystal growing process without requiring alternative seed crystals and, in addition, a method for purification of waste salts, which can isolate impurities from molten waste salts using a czochralski crystal growing process without alternative adsorption medium, does not generate secondary wastes and may continuously purify the waste salts.
摘要:
Provided is a substrate for forming a pattern comprising an inorganic layer having a modified surface, wherein the modified surface is formed by coating a surface of the inorganic layer with a bifunctional molecule comprising a functional group having an affinity for a nanocrystal at one end of the molecule and a functional group having an affinity for the inorganic layer at the other end of the molecule. A method for forming a pattern of nanocrystals is also provided.
摘要:
Disclosed relates to a method for preparing tantalum or niobium powders used for manufacturing capacitors in an electrolytic reducing reactor including an anode, a cathode and a molten salt, the method comprising: obtaining a tantalum or niobium oxide, expressed by Ta2O(5-y) or Nb2O(5-y) where y=2.5 to 4.5, from a tantalum pentoxide Ta2O5 or a niobium pentoxide Nb2O5 generated partially by an alkaline metal electrolytically reduced via a first electrolytic reducing reaction that reduces an alkaline metal oxide from a molten salt comprising at least one metal halogen compound, selected from the group consisting of alkaline metal and alkaline earth metal, and an alkaline metal oxide on the cathode; and preparing a tantalum or niobium powder by a first electrolytic reducing reaction that reduces at least one metal halogen compound selected from the group consisting of the alkaline metal oxide and the alkaline earth metal on the cathode and by a second reducing reaction with the tantalum or niobium oxide, represented by Ta2O(5-y) or Nb2O(5-y) where y=2.5 to 4.5.
摘要翻译:本发明涉及一种制备用于在包括阳极,阴极和熔融盐的电解还原反应器中制造电容器的钽或铌粉末的方法,所述方法包括:获得由Ta 2表示的钽或铌氧化物, (5-y)或Nb 2 O(5-y)其中y = 2.5至4.5,从五氧化二钽 或通过碱金属部分地生成的五氧化二铌Nb 2 O 5 O 3,其通过电解还原的碱金属 第一电解还原反应,其从包含至少一种选自碱金属和碱土金属的金属卤素化合物和阴极上的碱金属氧化物的熔融盐中降低碱金属氧化物; 并通过第一次电解还原反应来制备钽或铌粉末,该反应在阴极上还原至少一种选自碱金属氧化物和碱土金属的金属卤素化合物,并通过与钽或铌的第二次还原反应 氧化物,由Ta 2 O(5-y)或Nb 2 O(5-y)表示,其中 y = 2.5〜4.5。
摘要:
The manufacturing method for high-purity Zirconium is characterized by self-propagating high temperature synthesis (SHS) of a raw material having zirconium raw ore containing ZrO2, ZrSiO4, KZr2(PO4)3, or a mixture thereof and a reducing agent that is metal powder, to prepare zirconium intermetallic compound or zirconium nitride, followed by the recovery of high-purity Zr by electrolytic refining the reaction product of the SHS.
摘要:
The manufacturing method for high-purity Zirconium is characterized by self-propagating high temperature synthesis (SHS) of a raw material having zirconium raw ore containing ZrO2, ZrSiO4, KZr2(PO4)3, or a mixture thereof and a reducing agent that is metal powder, to prepare zirconium intermetallic compound or zirconium nitride, followed by the recovery of high-purity Zr by electrolytic refining the reaction product of the SHS.