公开(公告)号：US20150232646A1

公开(公告)日：2015-08-20

申请号：US14433054

申请日：2013-10-04

Applicant: Christopher B. WALKER, JR. ,  Joseph D. RULE ,  Vivek KRISHNAN ,  John C. CLARK ,  Steven J. MCMAN ,  Bola T. ALABI ,  Charlie C. HO ,  Ryan E. MARX ,  Alexander J. KUGEL ,  3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christopher B. Walker, JR. ,  Joseph D. Rule ,  Vivek Krishnan ,  John C. Clark ,  Steven J. McMan ,  Bola T. Alabi ,  Charlie C. Ho ,  Ryan E. Marx ,  Alexander J. Kugel

IPC: C08K7/20 ,  B32B27/20 ,  B32B27/36 ,  B32B27/08 ,  B32B27/40

CPC classification number: C08J5/18 ,  B32B3/085 ,  B32B27/08 ,  B32B27/20 ,  B32B27/306 ,  B32B27/308 ,  B32B27/36 ,  B32B27/40 ,  B32B2037/243 ,  B32B2255/00 ,  B32B2260/025 ,  B32B2260/046 ,  B32B2264/101 ,  B32B2264/104 ,  B32B2307/418 ,  B32B2451/00 ,  B44C5/0476 ,  C08J2375/04 ,  C08K3/08 ,  C08K3/22 ,  C08K3/40 ,  C08K7/18 ,  C08K7/20 ,  C09D7/70 ,  C09D183/04 ,  Y10T428/24893 ,  Y10T428/252 ,  Y10T428/254

Abstract: There is provided an article comprising at least a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities, where the first binder layer has a first major surface opposite a second major surface; and a plurality of microspheres at least partially embedded in the first major surface of the first binder layer. For at least a portion of the first major surface, the plurality of micro spheres may cover 30% to 50% of that portion, and the microspheres may be substantially uniformly spaced.

Abstract translation: 提供了一种制品，其至少包括具有选自线性树脂和交联密度低的树脂中的至少一种的第一粘合剂层的第一表面，其中第一粘合剂层具有与第二主表面相对的第一主表面; 以及至少部分地嵌入第一粘合剂层的第一主表面中的多个微球。 对于第一主表面的至少一部分，多个微球可以覆盖该部分的30％至50％，并且微球体可以基本均匀地间隔开。

公开(公告)号：US20130126161A1

公开(公告)日：2013-05-23

申请号：US13813000

申请日：2011-07-27

Applicant: Joseph D. Rule ,  Mohit Malik ,  Randy S. Frank

Inventor： Joseph D. Rule ,  Mohit Malik ,  Randy S. Frank

IPC: C09K8/80 ,  E21B43/267

CPC classification number: C09K8/80 ,  C09K8/62 ,  E21B43/267

Abstract: A plurality of particles comprising an elastomer-modified crosslinked aromatic epoxy vinyl ester polymer, wherein a particle from the plurality of particles maintains at least 50 percent of its height under a pressure of 1.7×107 Pascals at a temperature of at least 150° C. is disclosed. Mixtures of the plurality of particles and other particles, fluids containing the plurality of particles, methods of making the plurality of particles, and methods of fracturing a subterranean geological formation are also disclosed.

Abstract translation: 包含弹性体改性的交联芳族环氧乙烯基酯聚合物的多个颗粒，其中来自多个颗粒的颗粒在至少150℃的温度下在1.7×107帕斯卡的压力下保持其高度的至少50％。 被披露。 还公开了多个颗粒和其它颗粒的混合物，含有多个颗粒的流体，制备多个颗粒的方法以及压裂地下地质层的方法。

公开(公告)号：US20100316845A1

公开(公告)日：2010-12-16

申请号：US12814553

申请日：2010-06-14

Applicant: Joseph D. Rule ,  Kevin M. Lewandowski ,  Michael D. Determan

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski ,  Michael D. Determan

IPC: B32B3/00 ,  B05D5/10 ,  B29C65/52 ,  B29C65/02 ,  B29C65/48

CPC classification number: B32B37/06 ,  B29C61/0608 ,  B29C61/0616 ,  B29C61/0625 ,  B32B37/1284 ,  C09J7/24 ,  C09J2201/32 ,  C09J2205/302 ,  C09J2423/006 ,  C09J2433/00 ,  H05B3/36 ,  Y10T156/10 ,  Y10T428/24355 ,  Y10T428/24612 ,  Y10T428/28 ,  Y10T428/2813

Abstract: An adhesive article is described that is debondable from substrates or adherends with the application of heat.

Abstract translation: 描述了从施加热量的基底或被粘物脱粘的粘合剂制品。

公开(公告)号：US20100113659A1

公开(公告)日：2010-05-06

申请号：US12263704

申请日：2008-11-03

Applicant: Lisa S. Lim ,  Eumi Pyun ,  Joseph D. Rule

Inventor： Lisa S. Lim ,  Eumi Pyun ,  Joseph D. Rule

IPC: C08K5/5415 ,  C07F9/02

CPC classification number: C07F9/4012 ,  C08G77/30 ,  C08L63/00 ,  C08L2666/14

Abstract: A phosphorus-containing silsesquioxane is represented by the formula [R13SiO1/2]m[R2SiO3/2]n[R3SiO3/2]p[(R4O)2PO(CH2)xSiO3/2]q wherein each of R1, R2, R3, and R4 independently represents a hydrocarbyl group; x represents an integer of from 1 to 8; m is a positive number less than 1.5; n and q are positive numbers greater than 0 and less than 1; and p is a number greater than or equal to 0 and less than 1. Further, (n+p)/q is in a range of from 0.5 to 99, and (n+p+q)=1. Curable and cured compositions comprising the phosphorus-containing silsesquioxane are disclosed.

Abstract translation: 含磷的倍半硅氧烷由式[R13SiO1 / 2] m [R2SiO3 / 2] n [R3SiO3 / 2] p [（R4O）2PO（CH2）xSiO3 / 2] q表示，其中R1，R2，R3， 并且R 4独立地表示烃基; x表示1〜8的整数， m是小于1.5的正数; n和q是大于0且小于1的正数; 并且p是大于或等于0且小于1的数字。此外，（n + p）/ q在0.5至99的范围内，并且（n + p + q）= 1。 公开了包含含磷倍半硅氧烷的可固化和固化的组合物。

公开(公告)号：US20080085381A1

公开(公告)日：2008-04-10

申请号：US11866616

申请日：2007-10-03

Applicant: Gunnar H. Gunnarsson ,  David M. Snively ,  Xuequn Hu ,  Ying-Yuh Lu ,  Kevin M. Lewandowski ,  Joseph D. Rule ,  Pradnya V. Nagarkar

Inventor： Gunnar H. Gunnarsson ,  David M. Snively ,  Xuequn Hu ,  Ying-Yuh Lu ,  Kevin M. Lewandowski ,  Joseph D. Rule ,  Pradnya V. Nagarkar

IPC: C09K19/02 ,  B05D3/02 ,  B32B17/10 ,  B32B27/30 ,  B32B3/02 ,  C08F120/18 ,  C08F2/46 ,  C08L33/04

CPC classification number: B32B17/06 ,  C08F220/28 ,  C08F265/00 ,  C08L51/003 ,  G02B5/3033 ,  G02F1/133528 ,  G02F2202/28 ,  Y10T428/1041 ,  Y10T428/239 ,  Y10T428/26 ,  Y10T428/31649 ,  Y10T428/31935 ,  C08L2666/02

Abstract: An optical element with a polarizer and a support layer is disclosed herein. The polarizer comprises an intrinsic polarizer and the support layer comprises the reaction product of: (a) from 50 to 99 parts by weight of a (meth)acryloyl oligomer having a plurality of pendant, free radically polymerizable functional groups and a Tg of greater than or equal to 20° C., (b) from 1 to 50 parts by weight of a free-radically polymerizable crosslinking agent and/or diluent monomer, and (c) from 0.001 to 5 parts by weight of an initiator. A method of forming the optical element is also disclosed herein. The optical element may be used in optical devices such as projector systems.

Abstract translation: 本文公开了具有偏振器和支撑层的光学元件。 偏振器包括本征偏振器，并且支撑层包含以下反应产物：（a）50至99重量份具有多个侧基，可自由基可自由基聚合的官能团和Tg大于（重量）的（甲基）丙烯酰基低聚物 或等于20℃，（b）1至50重量份的可自由基聚合的交联剂和/或稀释剂单体，和（c）0.001至5重量份的引发剂。 本文还公开了形成光学元件的方法。 光学元件可以用于诸如投影仪系统的光学装置中。

公开(公告)号：US20110129644A1

公开(公告)日：2011-06-02

申请号：US12999026

申请日：2009-04-09

Applicant: Joseph D. Rule ,  Kevin M. Lewandowski

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski

IPC: B32B3/30

CPC classification number: B29C35/02 ,  B24D3/20 ,  B24D11/001 ,  B24D18/0009 ,  B29C37/0053 ,  B29C2059/023 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  Y10T428/24355 ,  Y10T428/24479

Abstract: Disclosed herein are microstructured articles that can be made by molding. The microstructured articles comprise crosslinked unsaturated polymers formed by ring opening metathesis polymerization (ROMP) of a monomer composition, the monomer composition comprising a cyclic monomer having at least one reactive double bond. The microstructured articles may be structured in that they comprise at least one microstructured feature having a dimension of less than about 2 mm, or less than about 500 um. The microstructured articles may also comprise a plurality of such microstructured features. Also disclosed herein are methods of making the microstructured articles.

Abstract translation: 本文公开了可以通过模制制造的微结构制品。 微结构化制品包含通过单体组合物的开环易位聚合（ROMP）形成的交联的不饱和聚合物，所述单体组合物包含具有至少一个反应性双键的环状单体。 微结构制品可以构造成它们包括至少一个具有小于约2mm或小于约500μm的尺寸的微结构特征。 微结构制品还可以包括多个这样的微结构特征。 本文还公开了制备微结构物品的方法。

公开(公告)号：US20100155998A1

公开(公告)日：2010-06-24

申请号：US12608313

申请日：2009-10-29

Applicant: Joseph D. Rule ,  Kevin M. Lewandowski

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski

IPC: C08J5/00 ,  C08F4/80

CPC classification number: C08L65/00 ,  C08G2261/3322 ,  C08G2261/418 ,  C08G2261/76

Abstract: A shape memory polymer composition is described comprising greater that 90 wt. % cyclooctene, less than 10 wt. % of a multicyclic diene, comprising at least two cyclo olefinic rings with at least two reactive double bonds, and less than 2 wt. % of a metathesis catalyst.

Abstract translation: 描述形状记忆聚合物组合物，其包含大于90wt。 ％环辛烯，小于10wt。 ％的多环二烯，包含至少两个具有至少两个反应性双键的环烯烃环，并且小于2wt。 复分解催化剂的百分比。

公开(公告)号：US09821529B2

公开(公告)日：2017-11-21

申请号：US14233398

申请日：2012-07-19

Applicant: Joseph D. Rule ,  Ross E. Behling ,  Nicholas A. Lee ,  Leslie M. LeBow

Inventor： Joseph D. Rule ,  Ross E. Behling ,  Nicholas A. Lee ,  Leslie M. LeBow

IPC: B32B7/12 ,  B32B3/18 ,  C09J5/06 ,  C09J7/02 ,  B32B5/18 ,  B32B38/10 ,  G09F7/18

CPC classification number: B32B3/18 ,  B32B5/18 ,  B32B7/12 ,  B32B38/10 ,  C09J5/06 ,  C09J7/22 ,  C09J7/38 ,  C09J2201/128 ,  C09J2201/20 ,  C09J2201/606 ,  C09J2205/302 ,  C09J2423/046 ,  C09J2465/006 ,  C09J2475/006 ,  G09F2007/1895 ,  Y10T156/1062 ,  Y10T156/1142 ,  Y10T428/24802

Abstract: A heat-debondable adhesive article having two opposing sides is provided that includes a shape-memory polymer sheet in its temporary strained shape that includes a plurality of slits therein and a first adhesive on one opposing side of the polymer sheet and a second adhesive on the other opposing side of the polymer sheet. The provided article, optionally, includes a first substrate in contact with the first adhesive and a second substrate in contact with the second adhesive. The article can be debonded by heating the article to a temperature equal to or greater than a transition temperature for the shape-memory polymer sheet.

公开(公告)号：US09370876B2

公开(公告)日：2016-06-21

申请号：US12999026

申请日：2009-04-09

Applicant: Joseph D. Rule ,  Kevin M. Lewandowski

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski

IPC: B32B3/30 ,  B29C35/02 ,  B24D3/20 ,  B24D11/00 ,  B24D18/00 ,  B29C37/00 ,  C08G61/08 ,  B29C59/02

CPC classification number: B29C35/02 ,  B24D3/20 ,  B24D11/001 ,  B24D18/0009 ,  B29C37/0053 ,  B29C2059/023 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  Y10T428/24355 ,  Y10T428/24479

Abstract: Disclosed herein are microstructured articles that can be made by molding. The microstructured articles comprise crosslinked unsaturated polymers formed by ring opening metathesis polymerization (ROMP) of a monomer composition, the monomer composition comprising a cyclic monomer having at least one reactive double bond. The microstructured articles may be structured in that they comprise at least one microstructured feature having a dimension of less than about 2 mm, or less than about 500 um. The microstructured articles may also comprise a plurality of such microstructured features. Also disclosed herein are methods of making the microstructured articles.

Abstract translation: 本文公开了可以通过模制制造的微结构制品。 微结构化制品包括通过单体组合物的开环易位聚合（ROMP）形成的交联的不饱和聚合物，所述单体组合物包含具有至少一个反应性双键的环状单体。 微结构制品可以构造成它们包括至少一个具有小于约2mm或小于约500μm的尺寸的微结构特征。 微结构制品还可以包括多个这样的微结构特征。 本文还公开了制备微结构物品的方法。

公开(公告)号：US09102868B2

公开(公告)日：2015-08-11

申请号：US13813000

申请日：2011-07-27

Applicant: Joseph D. Rule ,  Mohit Malik ,  Randy S. Frank

Inventor： Joseph D. Rule ,  Mohit Malik ,  Randy S. Frank

IPC: C09K8/80 ,  C09K8/62 ,  E21B43/267

CPC classification number: C09K8/80 ,  C09K8/62 ,  E21B43/267

Abstract: A plurality of particles comprising an elastomer-modified crosslinked aromatic epoxy vinyl ester polymer, wherein a particle from the plurality of particles maintains at least 50 percent of its height under a pressure of 1.7×107 Pascals at a temperature of at least 150° C. is disclosed. Mixtures of the plurality of particles and other particles, fluids containing the plurality of particles, methods of making the plurality of particles, and methods of fracturing a subterranean geological formation are also disclosed.

Abstract translation: 包含弹性体改性的交联芳族环氧乙烯基酯聚合物的多个颗粒，其中来自多个颗粒的颗粒在至少150℃的温度下在1.7×107帕斯卡的压力下保持其高度的至少50％。 被披露。 还公开了多个颗粒和其它颗粒的混合物，含有多个颗粒的流体，制备多个颗粒的方法以及压裂地下地质层的方法。