公开(公告)号：US6034023A

公开(公告)日：2000-03-07

申请号：US943025

申请日：1992-09-10

申请人： Meinolf Kersting ,  Juergen Kerth ,  Klaus-Dieter Hungenberg ,  Peter Koelle

发明人： Meinolf Kersting ,  Juergen Kerth ,  Klaus-Dieter Hungenberg ,  Peter Koelle

IPC分类号： C08F4/654 ,  C08F4/60 ,  C08F4/642 ,  C08F4/646 ,  C08F4/648 ,  C08F4/651 ,  C08F4/657 ,  C08F10/00 ,  C08F4/64

CPC分类号： C08F10/00

摘要： A novel process for the preparation of Ziegler-Natta catalyst systems containing, as active components,a) a titanium-containing solid component which contains titanium, magnesium, halogen and a carboxylic ester and, as a cocatalyst,b) an aluminum compound andc) if required, a further electron donor is described. Ziegler-Natta catalyst systems which are obtainable by this process, the preparation of polymers of propylene with the aid of these catalyst systems, the polymers obtainable thereby and films and moldings of these polymers are also described.

摘要翻译： 一种用于制备齐格勒 - 纳塔催化剂体系的新方法，其包含作为活性组分的a）含钛，镁，卤素和羧酸酯的含钛固体组分，并且作为助催化剂，b）铝化合物和c ）如果需要，描述另一电子给体。 也可以通过该方法获得的齐格勒 - 纳塔催化剂体系，借助于这些催化剂体系制备丙烯的聚合物，由此得到的聚合物以及这些聚合物的膜和模制品。

公开(公告)号：US5773537A

公开(公告)日：1998-06-30

申请号：US579890

申请日：1995-12-28

申请人： Patrik Mueller ,  Klaus-Dieter Hungenberg ,  Juergen Kerth ,  Ralf Zolk

发明人： Patrik Mueller ,  Klaus-Dieter Hungenberg ,  Juergen Kerth ,  Ralf Zolk

IPC分类号： C08F4/646 ,  C08F10/00 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

CPC分类号： C08F10/00

摘要： Catalyst systems of the Ziegler-Natta type contain, as active components a) a titanium-containing solid component in whose preparation a titanium compound, a compound of magnesium, a halogenating agent and an electron donor component are used, b) an aluminum compound and c) as a further electron donor component, an organosilicon compound of the formula (I) R.sup.1 R.sup.2 Si(OR.sup.3).sub.2 (I) where R.sup.1 is C.sup.1 -C.sub.10 -alkyl or C.sub.3 -C.sub.8 -cycloalkyl, excluding sec-butyl, R.sup.2 is sec-butyl and R.sup.3 is C.sub.1 -C.sub.8 -alkyl. The catalyst systems are particularly suitable for the preparation of polymers of C.sub.2 -C.sub.10 -alk-1-enes.

摘要翻译： 齐格勒 - 纳塔型催化剂体系包含作为活性组分的a）其中使用钛化合物，镁化合物，卤化剂和电子给体组分的含钛固体组分，b）铝化合物和 c）作为另外的电子给体组分，式（I）的有机硅化合物R1R2Si（OR3）2（Ⅰ）其中R1是C1-C10-烷基或C3-C8-环烷基，不包括仲丁基，R2是仲 - 丁基，R 3为C 1 -C 8 - 烷基。 催化剂体系特别适用于制备C 2 -C 10 - 烷-1-烯的聚合物。

公开(公告)号：US5476905A

公开(公告)日：1995-12-19

申请号：US725870

申请日：1991-07-10

申请人： Harald Schwager ,  Thomas Muehlenbernd ,  Bernd L. Marczinke ,  Juergen Kerth ,  Hans-Joachim Mueller

发明人： Harald Schwager ,  Thomas Muehlenbernd ,  Bernd L. Marczinke ,  Juergen Kerth ,  Hans-Joachim Mueller

IPC分类号： C08F8/42 ,  C08F255/02 ,  C08F265/02 ,  C08F265/04

CPC分类号： C08F255/02 ,  C08F8/42

摘要： Propylene copolymers grafted with .alpha.,.beta.-ethylenically unsaturated carboxylic acids or derivatives and containing up to 35% by weight of other C.sub.2 - to C.sub.10 -alk-1-enes are obtainable by reacting the monomer to be grafted with a propylene copolymer at from 1 to 500 bar, where, in the absence of a free-radical initiator, from 0.01 to 1.0% by weight, based on the propylene copolymer, of the monomer to be grafted are admixed with the molten propylene copolymer, and the grafting reaction is carried out at from 210.degree. to 350.degree. C.The propylene copolymers according to the invention can be converted into crosslinked or crosslinkable propylene copolymers by admixing organic crosslinking agents.

摘要翻译： 用α，β-烯键式不饱和羧酸或衍生物接枝并含有至多35重量％的其它C 2 -C 10 - 烷-1-烯的丙烯共聚物可通过将待接枝的单体与丙烯共聚物在1 至500巴，其中在不存在自由基引发剂的情况下，基于丙烯共聚物，待接枝的单体的0.01至1.0重量％与熔融丙烯共聚物混合，并进行接枝反应 在210℃至350℃下进行。根据本发明的丙烯共聚物可以通过混合有机交联剂转化成交联或交联的丙烯共聚物。

公开(公告)号：US5077322A

公开(公告)日：1991-12-31

申请号：US684277

申请日：1991-04-12

申请人： Isidoor De Grave ,  Joachim Fischer ,  Wolfram Koegel ,  Hermann Tatzel ,  Onno Graalmann ,  Juergen Kerth ,  Rainer A. Werner

发明人： Isidoor De Grave ,  Joachim Fischer ,  Wolfram Koegel ,  Hermann Tatzel ,  Onno Graalmann ,  Juergen Kerth ,  Rainer A. Werner

IPC分类号： C08J9/14 ,  C08J9/16 ,  C08J9/18

CPC分类号： C08J9/18 ,  C08J9/141 ,  C08J2323/16

摘要： Novel foams having a density of from 0.01 to 0.1 g/cm.sup.3, based on a copolymer comprising ethylene, propylene and a C.sub.4 - to C.sub.8 -.alpha.-olefin, and having a torsion modulus of from 100 to 800 N/mm.sup.2 have high tensile, compressive and flexural strengths and at the same time high elongation at break.

摘要翻译： 基于包含乙烯，丙烯和C 4 -C 8α-烯烃的共聚物，并且具有100至800N / mm 2的扭转模量的密度为0.01至0.1g / cm 3的新型泡沫具有高拉伸强度， 压缩和弯曲强度，同时高断裂伸长率。

公开(公告)号：US5166113A

公开(公告)日：1992-11-24

申请号：US759980

申请日：1991-09-17

申请人： Harald Schwager ,  Peter Koelle ,  Juergen Kerth ,  Ralf Zolk

发明人： Harald Schwager ,  Peter Koelle ,  Juergen Kerth ,  Ralf Zolk

IPC分类号： C08F10/00

CPC分类号： C08F10/00

摘要： Ziegler-Natta-type catalyst systems containing, as active constituents,a) a titanium-containing solid component which also contains magnesium, halogen and a carboxylic acid ester, and, as cocatalyst,b) an aluminum compound,wherein the carboxylic acid ester in the solid component is a diester of a carboxylic acid of the formula Ia or Ib ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are hydrogen, C.sub.1 - to C.sub.15 -alkyl, C.sub.7 - to C.sub.15 -alkylaryl, or 5- to 7-membered cycloalkyl, which may itself carry C.sub.1 - to C.sub.10 -alkyl groups, are particularly suitable for the preparation of polypropylene and copolymers of propylene containing minor amounts of other .alpha.,.beta.-unsaturated olefinic compounds having from 2 to 12 carbon atoms.

摘要翻译： 含有作为活性成分的齐格勒 - 纳塔型催化剂体系a）含镁，卤素和羧酸酯的含钛固体组分，和作为助催化剂的b）铝化合物，其中羧酸酯在 固体组分是式Ia或Ib的羧酸的二酯（Ia）其中R 1，R 2，R 3和R 4相同或不同，为氢，C 1至C 15 - 烷基 可以自身携带C1-至C10烷基的C 7 -C 15烷基芳基或5-至7-元环烷基特别适用于制备聚丙烯和含有少量其它α，β- 具有2至12个碳原子的不饱和烯烃化合物。

公开(公告)号：US5147928A

公开(公告)日：1992-09-15

申请号：US660252

申请日：1991-02-25

申请人： Juergen Kerth ,  Harald Schwager ,  Ralf Zolk

发明人： Juergen Kerth ,  Harald Schwager ,  Ralf Zolk

IPC分类号： C08F2/34 ,  C08F10/00 ,  C08F210/06 ,  C08F297/08

CPC分类号： C08F297/083

摘要： Propylene-ethylene copolymers are prepared in an agitated bed of solids by first polymerizing propylene from the gas phase in a first polymerization zone at 20-40 bar and 60.degree.-90.degree. C. by addition of a Ziegler-Natta catalyst system, and copolymerizing in a second polymerization zone at 7-35 bar and 40.degree.-70.degree. C. the finely divided polymer from the first polymerization zone with a mixture of olefins a process which comprises copolymerizing in the second polymerization zone with a mixture of propylene, ethylene and a further .alpha.-olefin of from 4 to 10 carbon atoms, setting the ratio of the partial pressures between propylene and ethylene within the range from 100:20 to 100:120 and that of the partial pressures between propylene and the further .alpha.-olefin within the range from 100:1 to 100:20, setting the pressure in the second polymerization zone at at least 5 bar below the pressure in the first polymerization zone, and determining the weight ratio between the monomers reacted in the first polymerization zone and those reacted in the second polymerization zone in such a way that said weight ratio is within the range from 100:10 to 100:50.

摘要翻译： 丙烯 - 乙烯共聚物在搅拌的固体床中通过首先在20-40巴和60-90℃的第一聚合区中通过加入齐格勒 - 纳塔催化剂体系在气相中聚合丙烯来制备，并共聚合 在7-35巴和40-70℃的第二聚合区中，来自第一聚合区的细分聚合物与烯烃混合物的方法，该方法包括在第二聚合区中与丙烯，乙烯和 另外的4-10个碳原子的α-烯烃使丙烯和乙烯之间的分压比在100:20至100:120的范围内，丙烯与其它α-烯烃之间的分压比 范围为100:1至100:20，将第二聚合区中的压力设定在第一聚合区内的压力以下至少5巴，并测定单体之间的重量比 在第一聚合区和第二聚合区中反应的那些，使得所述重量比在100:10至100:50的范围内。

公开(公告)号：US4857613A

公开(公告)日：1989-08-15

申请号：US236213

申请日：1988-08-25

申请人： Ralf Zolk ,  Juergen Kerth ,  Rainer Hemmerich

发明人： Ralf Zolk ,  Juergen Kerth ,  Rainer Hemmerich

IPC分类号： C08F4/58 ,  C08F4/60 ,  C08F4/64 ,  C08F10/06

CPC分类号： C08F10/06

摘要： Polymers of propene are prepared using a Ziegler-Natta catalyst system consisting of (1) a titanium component which is based on a finely divided, shape-imparting silica gel and contains titanium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component. In the process, a titanium component (1) is employed which is obtained by (1.1) first preparing (I) a carrier from (Ia) a silica gel which has a relatively high moisture content, (Ib) an organomagnesium compound and (Ic) a gaseous chlorinating agent by a method in which (1.1.1) first (Ia) is reacted with (Ib), (1.1.2) then (Ic) is passed into the mixture obtained in (1.1.1), and (I) is isolated, (1.2) thereafter a solid-phase intermediate is prepared from (I), (II) an alkanol, (III) titanium tetrachloride and (IV) a phthalic acid derivative by a procedure in which (1.2.1) first (I) is reacted with (II), (1.2.2) then (III) is introduced into the mixture resulting from (1.2.1), with the proviso that (IV) is also introduced during (1.2.1) and/or (1.2.2), (1.3) then the solid-phase product resulting from (1.2) is extracted with titanium tetrachloride or a titanium tetrachloride/hydrocarbon mixture, and (1.4) finally the solid-phase product resulting from (1.3) is washed with a liquid hydrocarbon.

摘要翻译： 丙烯聚合物使用齐格勒 - 纳塔催化剂体系制备，该催化剂体系由（1）基于精细分散的形状赋予硅胶并含有钛，镁，氯和苯甲酸衍生物的钛组分组成，（2） 铝成分和（3）硅烷成分。 在该方法中，使用钛成分（1），其通过（1.1）首先制备（I）来自（Ia）具有较高水分含量的硅胶的载体（Ib）有机镁化合物和（Ic） ）气态氯化剂，其中（1.1.1）第一（Ia）与（Ib），（1.1.2）反应，然后将（Ic）转化为（1.1.1）中获得的混合物和（ I）分离，（1.2）之后，通过（I），（II）烷醇，（III）四氯化钛和（Ⅳ）邻苯二甲酸衍生物，通过步骤（1.2.1）制备固相中间体， 第一（I）与（II），（1.2.2）反应，然后将（III）引入由（1.2.1）得到的混合物中，条件是在（1.2.1）期间引入（IV）和 /或（1.2.2），（1.3），然后用四氯化钛或四氯化碳/烃混合物萃取由（1.2）得到的固相产物，（1.4）最后由（1.3）得到的固相产物 用液体水溶液洗涤 碳。

公开(公告)号：US4713430A

公开(公告)日：1987-12-15

申请号：US945085

申请日：1986-12-22

申请人： Juergen Kerth ,  Heinz Vogt

发明人： Juergen Kerth ,  Heinz Vogt

IPC分类号： C08F4/46 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F10/02

CPC分类号： C08F10/02 ,  Y10S526/904

摘要： Finely divided ethene polymers are prepared by means of a Ziegler catalyst system composed of (1) a titanium-containing catalyst component obtained by precipitation in an organic liquid from (1.1) a solution of titanium tetrachloride in a hydrocarbon, (1.2) a solution of a certain organoaluminum compound in a hydrocarbon, and a catalyst component which contains (1.3) an alpha-monoalkene and (2) aluminum, wherein the (1) used has been precipitated at relatively low temperatures in an organic liquid which, at the precipitation temperature has a relatively high viscosity and comprises (a) a liquid hydrocarbon and (b), dissolved therein, relatively small amounts of polymer of an alpha-monoalkene, with the provisos that (i) for every gram-mole of the total amount of titanium tetrachloride used specific amounts of the organic liquid, of the organoaluminum compound and of the alpha-monoalkene are used and (ii) for every mole unit of the total amount of titanium tetrachloride used specific amounts are precipitated per minute and specific amounts of the alpha-monoalkene are introduced per minute.

摘要翻译： 精细分离的乙烯聚合物通过齐格勒催化剂体系制备，该系统由以下组成：（1）通过在（1.1）四氢化碳溶液中的（1.1）有机液体中沉淀得到的含钛催化剂组分，（1.2） 烃中的某些有机铝化合物和含有（1.3）α-单链烯烃和（2）铝的催化剂组分，其中所用的（1）在相对低的温度下在有机液体中沉淀，在有机液体中，在沉淀温度 具有相对较高的粘度，并且包含（a）液体烃和（b）溶解在其中的相对少量的α-单链烯烃的聚合物，条件是（i）对于每克克数的钛的总量 使用四氯化碳使用特定量的有机液体，有机铝化合物和α-单链烯烃，和（ii）使用特定的amo的四氯化钛的总量的每摩尔单位 每分钟沉淀出单体，每分钟引入特定量的α-单链烯烃。

公开(公告)号：US5618895A

公开(公告)日：1997-04-08

申请号：US121465

申请日：1993-09-16

申请人： Juergen Kerth ,  Peter Koelle ,  Ralf Zolk ,  Harald Schwager

发明人： Juergen Kerth ,  Peter Koelle ,  Ralf Zolk ,  Harald Schwager

IPC分类号： C08F2/34 ,  C08F4/642 ,  C08F4/648 ,  C08F210/06

CPC分类号： C08F210/06 ,  Y10S526/901 ,  Y10S526/916

摘要： Copolymers of propylene with other 1-alkenes, obtainable by gas-phase polymerization of a mixture of propylene and another 1-alkene in the absence of a liquid reaction medium under a pressure of from 15 to 30 bar, at from 60.degree. to 90.degree. C. and with an average holdup time of the polymer of from 1 to 5 hours, with the aid of a Ziegler-Natta catalyst system which, besides a titanium-containing solid component, contains an aluminum component and an electron donor, with the temperature being chosen so that, under the preset pressure, no condensation of the monomer mixture takes place in the gas space and, moreover, the ratio of the partial pressures of propylene and the other 1-alkene is adjusted to from 5:1 to 100:1, are particularly suitable for producing sheets and shaped articles.

摘要翻译： 丙烯与其它1-烯烃的共聚物，可通过在不存在液体反应介质的情况下，在15至30巴，60至90度的压力下，将丙烯与另一种1-烯烃的混合物气相聚合而得到。 并且借助于齐格勒 - 纳塔催化剂体系，聚合物的平均保持时间为1至5小时，除了含钛固体组分外，还含有铝组分和电子给体，温度 使得在预设压力下，在气体空间中不发生单体混合物的冷凝，此外，将丙烯和其它1-烯烃的分压比例调节至5:1至100:1。 1，特别适用于生产片材和成形制品。

公开(公告)号：US5536789A

公开(公告)日：1996-07-16

申请号：US427273

申请日：1995-04-24

申请人： Harald Schwager ,  Peter Koelle ,  Rueger Schlund ,  Ralf Zolk ,  Juergen Kerth ,  Guenther Schweter ,  Klaus-Dieter Hungenberg ,  Werner Schoene

发明人： Harald Schwager ,  Peter Koelle ,  Rueger Schlund ,  Ralf Zolk ,  Juergen Kerth ,  Guenther Schweter ,  Klaus-Dieter Hungenberg ,  Werner Schoene

IPC分类号： C08F4/654 ,  C08F2/34 ,  C08F2/38 ,  C08F4/60 ,  C08F4/649 ,  C08F10/06 ,  C08F110/00 ,  C08F110/06 ,  C08L23/10 ,  C08L23/12 ,  C08F255/02 ,  C08F297/08

CPC分类号： C08F110/06 ,  C08F10/06 ,  C08L23/12 ,  C08L2205/02 ,  C08L23/10

摘要： Propylene polymers have a molecular weight ratio Q (M.sub.w /M.sub.n) of from 6 to 30 and are obtainable by Ziegler-Natta polymerization in the presence of hydrogen as molecular weight regulator and are particularly suitable for the production of films and moldings.

摘要翻译： 丙烯聚合物的分子量比Q（＆upbar＆Mw /＆Upbar＆Mn）为6至30，可通过齐格勒 - 纳塔聚合在氢气存在下作为分子量调节剂获得，特别适用于制备薄膜和模制品。