摘要:
A process for preparing random propylene copolymers containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes by polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C.sub.2 -C.sub.10 -alk-1-enes are polymerized with one another at from 50 to 100.degree. C. at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
摘要:
Propylene polymers containA) a semicrystalline propylene homopolymer having a melting point of 125 to 165.degree. C. and a glass transition temperature which is greater than -10.degree. C. andB) a semicrystalline propylene homopolymer having a melting point below 130.degree. C. and a glass transition temperature which is less than or equal to -10.degree. C. or a non-crystallizing propylene homopolymer having a glass transition temperature which is less than or equal to -10.degree. C.
摘要:
In catalyst systems of the Ziegler-Natta type modified during their preparation and comprising as active constituentsa) a titanium-containing solid component which is obtained by reacting a compound of titanium with a compound of magnesium, a halogen, an inorganic oxide as support, a C.sub.1 -C.sub.8 -alkanol and a carboxylic ester as electron donor compound,and also as cocatalystb) an aluminum compound andc) if desired, a further electron donor compound,the titanium-containing solid component a) is prepared by first, in a first stage, admixing an inorganic oxide as support with a solution of a chlorine-free compound of magnesium in an inert solvent, stirring this mixture for from 0.5 to 5 hours at from 10 to 120.degree. C. and subsequently reacting it while stirring continually in an inert solvent with a C.sub.1 -C.sub.8 -alkanol in an at least 1.3-fold excess, based on the compound of magnesium, to give a chlorine-free intermediate, then, without purification or extraction of the intermediate, adding a compound of trivalent or tetravalent titanium and a carboxylic ester as electron donor compound to this intermediate, stirring the resulting mixture for at least 30 minutes at from 20 to 130.degree. C., subsequently filtering off and washing the solid thus obtained and subsequently, in a second stage, extracting the solid obtained from the first stage in an inert solvent comprising at least 5% by weight of titanium tetrachloride and washing it with a liquid alkane.
摘要:
Supported catalyst systems are obtainable bya) application of a mixture ofA) at least one metallocene complex andB) at elast one metal compoundto a carrier which, if required, may have been pretreated, andb) subsequent activation by reaction with a solution or suspension of a compound forming metallocenium ions.
摘要:
In a process for converting the achiral meso form or the racemate of an ansa-metallocene complex or a mixture thereof into one of its enantiomers, the conversion is carried out photochemically in the presence of an enantiomerically pure auxiliary reagent.
摘要:
A process for preparing oligomers and polymers, obtained from A) from 0.001 to 100 mol % of at least one aminoalkene of the formula I ##STR1## where X is an integer from 0 to 25 and R.sup.1 to R.sup.6 are hydrogen, C.sub.1 - to C.sub.10 -alkyl, 5- to 7-membered cycloalkyl which, in turn, can carry C.sub.1 - to C.sub.6 -alkyl groups as substituents or C.sub.6 - to C.sub.15 -aryl and B) from 0 to 99.999 mol % of at least one alkene, for x=1 in formula I propene being excluded as component B).
摘要:
Catalyst systems of the type comprising the Ziegler-Natta catalysts contain, as active components,a) a titanium-containing solid component which contains titanium, magnesium, halogen and a carboxylic ester as an electron donor, and, as a cocatalyst,b) an aluminum compound andc) if required, a further electron donor, a compound of the following formula IR.sub.m.sbsb.1 Al--(OCOR.sup.1).sub.m.sbsb.2 (I)whereR and R.sup.1 are identical or different and are each hydrogen or C.sub.1 -C.sub.8 -alkyl andm.sub.1 and m.sub.2 are each 1 or 2 and sum to give 3, being used as aluminum compound b) in the preactivation of the titanium-containing soild compound a) with the cocatalyst.
摘要:
Propylene polymers which comprise from 25 to 97% by weight of a propylene polymer (I) containing from 0 to 15% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes and also comprise from 3 to 75% by weight of a further propylene polymer (II) containing from 15 to 80% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes, are obtainable by two-stage polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system which comprises a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also as cocatalysts an aluminum compound b) and a further electron donor compound c), where, in a first polymerization stage, propylene is polymerized in the presence or absence of further C.sub.2 -C.sub.10 -alk-1-enes at from 50.degree. to 100.degree. C., pressures in the range from 15 to 40 bar and a mean residence time of from 0.5 to 5 hours and subsequently, in a second polymerization stage, a mixture of propylene and further C.sub.2 -C.sub.10 -alk-1-enes is polymerized at from 30.degree. to 100.degree. C., pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours onto the propylene polymer obtained from the first polymerization stage, and the silica gel used as support for the titanium-containing solid component has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic volume as a proportion of the total particle in the range from 5 to 20%.
摘要:
Random propylene copolymers containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes are obtainable by polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C.sub.2 -C.sub.10 -alk-1-enes are polymerized with one another at from 50.degree. to 100.degree. C. at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
摘要:
Cyclopentadineyl compounds of the formula II ##STR1## and formula III ##STR2## their preparation and their use as intermediates in the preparation of metallocene complexes of the formula I.