公开(公告)号：US20090221748A1

公开(公告)日：2009-09-03

申请号：US12040380

申请日：2008-02-29

申请人： Simion Coca ,  Deborah E. Hayes ,  Jonathan T. Martz ,  Karen A. Morow ,  Calum H. Munro ,  Kurt G. Olson ,  Dennis A. Simpson ,  Jane N. Valenta ,  Richard J. Winters ,  Stephen J. Thomas

发明人： Simion Coca ,  Deborah E. Hayes ,  Jonathan T. Martz ,  Karen A. Morow ,  Calum H. Munro ,  Kurt G. Olson ,  Dennis A. Simpson ,  Jane N. Valenta ,  Richard J. Winters ,  Stephen J. Thomas

IPC分类号： C08L33/08

CPC分类号： C08F290/046 ,  C08L33/08 ,  C08L61/28 ,  C09D133/066 ,  C09D133/068 ,  C08L2666/02

摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is

摘要翻译： 本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心 是聚合物总重量的10重量％。

公开(公告)号：US06592999B1

公开(公告)日：2003-07-15

申请号：US09919200

申请日：2001-07-31

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B904

CPC分类号： B05D7/57 ,  B05D7/574 ,  C08J5/12 ,  C08K3/38 ,  C08K5/55 ,  C09D7/60 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

公开(公告)号：US07737223B2

公开(公告)日：2010-06-15

申请号：US11612513

申请日：2006-12-19

申请人： Jane N. Valenta ,  Edward R. Coleridge ,  Steven J. Valasak ,  Karen A. Morow ,  Paul H. Lamers

发明人： Jane N. Valenta ,  Edward R. Coleridge ,  Steven J. Valasak ,  Karen A. Morow ,  Paul H. Lamers

IPC分类号： C08F8/30

CPC分类号： C09D133/14 ,  C08K5/34922 ,  C08L33/14 ,  C09D161/00 ,  C09D179/00 ,  C08L2666/04 ,  C08L2666/02

摘要： The present invention is directed to a substantially pigment-free coating composition with good cure response and improved appearance. In particular, the substantially pigment-free coating composition may comprise (a) at least one functional polymer containing amine groups and groups selected from hydroxyl and carbamate; and (b) a crosslinking agent.

摘要翻译： 本发明涉及具有良好固化反应和改进外观的基本上无色素的涂料组合物。 特别地，基本上不含颜料的涂料组合物可以包含（a）至少一种含有胺基团和选自羟基和氨基甲酸酯基团的官能聚合物; 和（b）交联剂。

公开(公告)号：US07329468B2

公开(公告)日：2008-02-12

申请号：US10935643

申请日：2004-09-07

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B9/04

CPC分类号： B05D7/57 ,  B05D7/574 ,  C08J5/12 ,  C08K3/38 ,  C08K5/55 ,  C09D7/60 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

摘要翻译： 本发明提供了两种或更多种聚合物层的改进的多层复合材料，其中至少一种由热固性组合物形成。 所述复合材料包括形成在基材上的至少第一聚合物层和在所述第一聚合物层上的第二聚合物层，其中在不存在含硼化合物的情况下，所述第一和第二聚合物层具有差的层间粘合性。 改进在于在足以改善第一和第二聚合物层之间的层间粘合力的量中将至少一种含硼化合物包含在第一和第二聚合物层的一个或两个中。 还提供了一种改进的可固化涂料组合物，其用于形成两层或多层固化涂层的多层复合涂层，其中至少一层由热固性组合物形成。 还提供了相关方法和涂覆的基底。

公开(公告)号：US08071679B2

公开(公告)日：2011-12-06

申请号：US12040380

申请日：2008-02-29

申请人： Simion Coca ,  Deborah E. Hayes ,  Jonathan T. Martz ,  Karen A. Morow ,  Calum H. Munro ,  Kurt G. Olson ,  Dennis A. Simpson ,  Jane N. Valenta ,  Richard J. Winters ,  Stephen J. Thomas

发明人： Simion Coca ,  Deborah E. Hayes ,  Jonathan T. Martz ,  Karen A. Morow ,  Calum H. Munro ,  Kurt G. Olson ,  Dennis A. Simpson ,  Jane N. Valenta ,  Richard J. Winters ,  Stephen J. Thomas

IPC分类号： C08F8/00 ,  C08G63/91

CPC分类号： C08F290/046 ,  C08L33/08 ,  C08L61/28 ,  C09D133/066 ,  C09D133/068 ,  C08L2666/02

摘要： The present invention is directed to a coating composition comprising a polymer that comprises an oligomeric macromonomer and a core from which the oligomeric macromonomer extends, wherein the oligomeric macromonomer comprises reactive functional groups and has an average functionality ranging from 1.0 to 30, and wherein the core is

摘要翻译： 本发明涉及包含聚合物的涂料组合物，所述聚合物包含低聚物大分子单体和低聚物大分子单体从其延伸的核心，其中所述低聚物大分子单体包含反应性官能团并且平均官能度为1.0至30，并且其中所述核心 是聚合物总重量的10重量％。

公开(公告)号：US07897261B2

公开(公告)日：2011-03-01

申请号：US11178548

申请日：2005-07-11

申请人： John W. Burgman ,  Simion Coca ,  Edward R. Coleridge ,  Heather L. Lim ,  Karen A. Morow ,  Jane N. Valenta

发明人： John W. Burgman ,  Simion Coca ,  Edward R. Coleridge ,  Heather L. Lim ,  Karen A. Morow ,  Jane N. Valenta

IPC分类号： B32B27/32 ,  C08F2/00

CPC分类号： C09D143/00 ,  C08L33/068 ,  C08L2312/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  Y10T428/31938 ,  C08L2666/04

摘要： A coating composition is provided comprising (a) a polymer containing reactive functional groups; (b) a curing agent having reactive functional groups that are reactive with the functional groups in the polymer in (a); and (c) a polymeric material different from (a) and (b) having functional groups. The functional groups in components (a) and (b) are more reactive with each other than with the functional groups in component (c) such that upon curing, at least a portion of the functional groups on component (c) remain unreacted. A coating layer formed from the composition upon application to a substrate has surface regions and a bulk region, and the concentration of component (c) at one or more surface regions is greater than the concentration of component (c) in the bulk region of the coating layer. The composition can be used in multi-layer composites containing two or more coating layers.

摘要翻译： 提供涂料组合物，其包含（a）含有反应性官能团的聚合物; （b）具有与（a）中的聚合物中的官能团反应的反应性官能团的固化剂; 和（c）不同于具有官能团的（a）和（b）的聚合物材料。 组分（a）和（b）中的官能团与组分（c）中的官能团相比更具反应性，使得在固化后，组分（c）上至少一部分官能团保持未反应。 由涂布到基材上的组合物形成的涂层具有表面区域和体积区域，并且在一个或多个表面区域的组分（c）的浓度大于组分（c）在本体区域中的浓度 涂层。 该组合物可用于含有两层或多层涂层的多层复合材料。

公开(公告)号：US06592998B2

公开(公告)日：2003-07-15

申请号：US09919095

申请日：2001-07-31

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Roger L. Scriven ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Roger L. Scriven ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B904

CPC分类号： C09D183/06 ,  B05D7/57 ,  B05D7/576 ,  C08L33/08 ,  C08L83/00 ,  C08L83/04 ,  C08L2666/52 ,  C09D133/08 ,  C09J133/08 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31667

摘要： Improved multi-layer composites are provided. The multi-layer composites include at least a first polymeric layer and a second polymeric layer formed over the first polymeric layer thereby forming an interface region there between. At least one of the polymeric layers is formed from a thermosetting composition which contains an adhesion promoter composition. The adhesion promoter composition is formed from (1) at least one adhesion promoting component, and (2) at least one surface active component. The improvement is represented by the presence of the adhesion promoting component (1) at the interface region.

公开(公告)号：US08029894B2

公开(公告)日：2011-10-04

申请号：US11465624

申请日：2006-08-18

申请人： Karen A. Morow ,  Jane N. Valenta ,  Shanti Swarup ,  Lawrence G. Anderson

发明人： Karen A. Morow ,  Jane N. Valenta ,  Shanti Swarup ,  Lawrence G. Anderson

IPC分类号： B32B7/04 ,  B32B27/08 ,  B32B27/18 ,  B32B27/26 ,  B32B27/36

CPC分类号： C09D7/65 ,  C08K3/38 ,  C08K5/0025 ,  C08K5/103 ,  Y10T428/28 ,  Y10T428/2848 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909

摘要： Thermosetting compositions comprising an adhesion-promoting agent are disclosed. The adhesion-promoting agent is derived from boric acid or an equivalent and an ester having two or more functional groups that are derived at least in part from a 1,3-polyol.

摘要翻译： 公开了包含粘合促进剂的热固组合物。 粘合促进剂衍生自硼酸或等同物和具有至少部分由1,3-多元醇衍生的两个或更多个官能团的酯。

公开(公告)号：US20110165418A1

公开(公告)日：2011-07-07

申请号：US11465624

申请日：2006-08-18

申请人： Karen A. Morow ,  Jane N. Valenta ,  Shanti Swarup ,  Lawrence G. Anderson

发明人： Karen A. Morow ,  Jane N. Valenta ,  Shanti Swarup ,  Lawrence G. Anderson

IPC分类号： B32B9/04 ,  B32B27/36 ,  B32B27/08 ,  C08L85/04

CPC分类号： C09D7/65 ,  C08K3/38 ,  C08K5/0025 ,  C08K5/103 ,  Y10T428/28 ,  Y10T428/2848 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909

摘要： Thermosetting compositions comprising an adhesion-promoting agent are disclosed. The adhesion-promoting agent is derived from boric acid or an equivalent and an ester having two or more functional groups that are derived at least in part from a 1,3-polyol.

摘要翻译： 公开了包含粘合促进剂的热固组合物。 粘合促进剂衍生自硼酸或等同物和具有至少部分由1,3-多元醇衍生的两个或更多个官能团的酯。

公开(公告)号：US20080141902A1

公开(公告)日：2008-06-19

申请号：US11612513

申请日：2006-12-19

申请人： Jane N. Valenta ,  Edward R. Coleridge ,  Steven J. Valasek ,  Karen A. Morow

发明人： Jane N. Valenta ,  Edward R. Coleridge ,  Steven J. Valasek ,  Karen A. Morow

IPC分类号： C09D135/02

CPC分类号： C09D133/14 ,  C08K5/34922 ,  C08L33/14 ,  C09D161/00 ,  C09D179/00 ,  C08L2666/04 ,  C08L2666/02

摘要： The present invention is directed to a substantially pigment-free coating composition with good cure response and improved appearance. In particular, the substantially pigment-free coating composition may comprise (a) at least one functional polymer containing amine groups and groups selected from hydroxyl and carbamate; and (b) a crosslinking agent.

摘要翻译： 本发明涉及具有良好固化反应和改进外观的基本上无色素的涂料组合物。 特别地，基本上不含颜料的涂料组合物可以包含（a）至少一种含有胺基团和选自羟基和氨基甲酸酯基团的官能聚合物; 和（b）交联剂。