公开(公告)号：US20120237706A1

公开(公告)日：2012-09-20

申请号：US13486511

申请日：2012-06-01

Applicant: Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

Inventor： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC: C08L33/02 ,  B32B1/02

CPC classification number: C08L33/02 ,  B32B17/10045 ,  B32B17/10743 ,  B32B17/10761 ,  B32B17/10853 ,  B32B17/10981 ,  B32B2367/00 ,  C08L23/0876 ,  C08L2205/02 ,  C08L2205/025 ,  C09J123/0876 ,  F41H5/0407 ,  Y10T428/1352 ,  Y10T428/269 ,  Y10T428/31645 ,  Y10T428/31855 ,  C08L2666/04

Abstract: An ionomer blend composition comprises a blend of a first ionomer and a second ionomer that is different from the first ionomer. The first ionomer is derived from a first precursor acid copolymer that has a melt flow rate of about 10 to about 4000 g/10 min and that comprises copolymerized units of an α-olefin and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid. Moreover, the first precursor acid can be neutralized to a level of about 40% to about 90% to form a sodium ionomer that has a MFR of about 0.7 to about 25 g/10 min and a freeze enthalpy that is less than about 3.0 j/g or that is not detectable, when determined by differential scanning calorimetry (DSC). A variety of articles may comprise or be produced from the ionomer blend composition, for example by injection molding.

Abstract translation: 离聚物共混物组合物包含与第一离聚物不同的第一离聚物和第二离聚物的共混物。 第一离聚物衍生自具有约10至约4000g / 10min的熔体流动速率的第一前体酸共聚物，其包含α-烯烃的共聚单元和约20至约30wt％的共聚单元 α，β-烯属不饱和羧酸。 此外，第一前体酸可被中和至约40％至约90％的水平以形成具有约0.7至约25g / 10min的MFR和小于约3.0j的冷冻焓的钠离聚物 / g，或通过差示扫描量热法（DSC）测定时不可检测。 各种制品可以包括或由离聚物共混组合物制备，例如通过注塑成型。

公开(公告)号：US07825191B2

公开(公告)日：2010-11-02

申请号：US11642072

申请日：2006-12-20

Applicant: Barry Alan Morris ,  Karlheinz Hausmann ,  Matthew Scott Hall ,  John Chu Chen

Inventor： Barry Alan Morris ,  Karlheinz Hausmann ,  Matthew Scott Hall ,  John Chu Chen

IPC: C08L33/02

CPC classification number: C08K3/08 ,  C08K2201/017 ,  C08L23/08 ,  C08L23/0876 ,  C08L2205/02 ,  C08L2666/06

Abstract: A composition and an article comprising or produced from the composition are disclosed. The composition comprises an ionomer and a reducing static charge-buildup amount of potassium ion wherein the ionomer is neutralized with sodium, zinc, or magnesium ions. The article can be a film including a multilayer film.

Abstract translation: 公开了一种组合物和包含该组合物或由该组合物制备的制品。 该组合物包含离子交联聚合物和减少的静电荷积聚量的钾离子，其中离聚物用钠，锌或镁离子中和。 该物品可以是包括多层膜的膜。

公开(公告)号：US20100166992A1

公开(公告)日：2010-07-01

申请号：US12610881

申请日：2009-11-02

Applicant: KARLHEINZ HAUSMANN ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

Inventor： KARLHEINZ HAUSMANN ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC: B32B1/02 ,  C08F8/00 ,  B32B5/00

CPC classification number: B32B17/10036 ,  B32B17/10743 ,  C08F8/44 ,  C08F210/02 ,  C08F2800/20 ,  C08L23/0876 ,  C08L2205/02 ,  Y10T428/1352 ,  Y10T428/265 ,  Y10T428/269 ,  Y10T428/31645 ,  Y10T428/31855 ,  C08L2666/06 ,  C08F220/06

Abstract: A sodium/zinc mixed ionomer comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 10 to about 4000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry. Further provided are articles comprising or prepared from the sodium/zinc mixed ionomer.

Abstract translation: 钠/锌混合离聚​​物包括羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约10至约4000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。 还提供了包含或由钠/锌混合离聚​​物制备的制品。

公开(公告)号：US20090192266A1

公开(公告)日：2009-07-30

申请号：US12358944

申请日：2009-01-23

Applicant: Charles John Talkowski ,  Karlheinz Hausmann ,  David J. Walsh

Inventor： Charles John Talkowski ,  Karlheinz Hausmann ,  David J. Walsh

IPC: C08L67/06

CPC classification number: C08L67/02 ,  C08L23/0876 ,  C08L2666/06

Abstract: A composition is disclosed which comprises a mixture of a poly(trimethylene terephthalate) polymer composition, a nucleating agent, and an ethylene copolymer. Also disclosed in a method for reducing the melt viscosity of nucleated poly(trimethylene terephthalate) polymer composition.

Abstract translation: 公开了包含聚（对苯二甲酸丙二醇酯）聚合物组合物，成核剂和乙烯共聚物的混合物的组合物。 还公开了一种降低有形聚（对苯二甲酸丙二醇酯）聚合物组合物的熔体粘度的方法。

公开(公告)号：US20060160952A1

公开(公告)日：2006-07-20

申请号：US11315988

申请日：2005-12-21

Applicant: Richard Chou ,  Karlheinz Hausmann ,  Han Lee

Inventor： Richard Chou ,  Karlheinz Hausmann ,  Han Lee

IPC: C08F8/00

CPC classification number: C08L23/0853 ,  C08L23/0869 ,  Y10T428/249993 ,  Y10T428/269 ,  Y10T428/31692 ,  Y10T428/31699 ,  Y10T428/31725 ,  Y10T428/31855 ,  Y10T428/3188 ,  Y10T428/31895 ,  Y10T428/31906 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T442/30 ,  Y10T442/60 ,  C08L2666/06

Abstract: Disclosed are high frequency-active blends comprising (a) copolymers of ethylene and maleic anhydride or its functional equivalents and (b) ethylene copolymers with polar comonomers such as ethylene/vinyl acetate copolymers, ethylene/alkyl (meth)acrylate copolymers and ethylene/(meth)acrylate/carbon monoxide terpolymers; and films, powders, multilayer structures, and articles prepared therefrom.

Abstract translation: 公开了包含（a）乙烯和马来酸酐的共聚物或其功能等同物的高频 - 活性共混物，和（b）与极性共聚单体如乙烯/乙酸乙烯酯共聚物，乙烯/（甲基）丙烯酸烷基酯共聚物和乙烯/（ 甲基）丙烯酸酯/一氧化碳三元共聚物; 以及由其制备的薄膜，粉末，多层结构和制品。

公开(公告)号：US07074494B2

公开(公告)日：2006-07-11

申请号：US10782211

申请日：2004-02-19

Applicant: Karlheinz Hausmann ,  Robert V. Kasowski

Inventor： Karlheinz Hausmann ,  Robert V. Kasowski

IPC: B32B27/08 ,  B32B27/30

CPC classification number: B32B27/08 ,  B32B27/30 ,  B32B2307/3065 ,  B32B2307/412 ,  B32B2419/00 ,  B32B2605/003 ,  Y10T428/31909 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31938

Abstract: Flame retardant polymer compositions, especially ionomer polymer compositions, are prepared using ethylene diamine phosphate and used as surface coverings and building materials.

Abstract translation: 使用乙二胺磷酸盐制备阻燃聚合物组合物，特别是离聚物聚合物组合物，并用作表面覆盖物和建筑材料。

公开(公告)号：US06964988B2

公开(公告)日：2005-11-15

申请号：US10266423

申请日：2002-10-08

Applicant: Karlheinz Hausmann

Inventor： Karlheinz Hausmann

IPC: C08K5/00 ,  C08L23/08 ,  C09K3/16 ,  C08K5/15

CPC classification number: C09K3/16 ,  C08K5/0075 ,  C08L23/0876 ,  Y10S524/91 ,  C08L23/08

Abstract: The invention relates to a thermoplastic composition comprising at least a copolymer of ethylene and an α,β-unsaturated C3-C8 carboxylic acid, from about 10 to 99.9% neutralized with Lithium, and at least from about 0.01 wt % to about 2 wt % of a migrating antistatic agent. The invention also relates to films, sheet and molded articles comprising the above composition. The composition, film, sheet or molded article of the invention show good antistatic properties and preferably have a surface resistivity equal or less than 10E11. The composition, film, sheet or molded article of the invention can in particular be used as a protective transparent coating or layer on abrasion and scratch-exposed objects.

Abstract translation: 本发明涉及一种热塑性组合物，其包含至少一种乙烯与α，β-不饱和C 3 -C 8羧酸的共聚物，约10至99.9％的中和 和至少约0.01重量％至约2重量％的迁移性抗静电剂。 本发明还涉及包含上述组合物的薄膜，片材和模制品。 本发明的组合物，薄膜，片材或模塑制品具有良好的抗静电性能，优选具有等于或小于10E 11的表面电阻率。 本发明的组合物，薄膜，片材或模塑制品可特别用作磨损和划伤物体上的保护性透明涂层或层。

公开(公告)号：US06696524B2

公开(公告)日：2004-02-24

申请号：US10071029

申请日：2002-02-08

Applicant: Karlheinz Hausmann

Inventor： Karlheinz Hausmann

IPC: C08L3302

CPC classification number: C08L23/04 ,  C08L23/08 ,  C08L23/0823 ,  C08L23/0876 ,  C08L2666/04

Abstract: Blends comprising an ethylene based polymer having a glass transition temperature lower than or equal to 20° C. and cycloolefin polymer are prepared. The ethylene based polymer preferably comprises at least 60 weight % of ethylene, relative to the weight of the polymer and polar monomers selected from the group of carboxylic acids, alkyl acrylates and vinyl acetates. It is preferably 0.01 to about 99.5% neutralized with metal ions selected from sodium, potassium, zinc, calcium, magnesium, lithium, aluminum, nickel, and chromium. The cycloolefin polymer is preferably an ethylene-norbornene copolymer. The invention also relates to the applications of such blends to improved impact resistant molded articles.

Abstract translation: 制备包含玻璃化转变温度低于或等于20℃的乙烯基聚合物和环烯烃聚合物的共混物。 基于乙烯的聚合物优选包含至少60重量％的乙烯，相对于聚合物的重量和选自羧酸，丙烯酸烷基酯和乙酸乙烯酯的极性单体。 优选使用选自钠，钾，锌，钙，镁，锂，铝，镍和铬的金属离子中和0.01至约99.5％。 环烯烃聚合物优选为乙烯 - 降冰片烯共聚物。 本发明还涉及这种共混物在改进的耐冲击成型制品上的应用。

公开(公告)号：US06630528B2

公开(公告)日：2003-10-07

申请号：US09923653

申请日：2001-08-07

Applicant: Karlheinz Hausmann ,  Bernard Rioux ,  Jean-Marie Francois

Inventor： Karlheinz Hausmann ,  Bernard Rioux ,  Jean-Marie Francois

IPC: C08K509

CPC classification number: C08J5/18 ,  C08J2323/08 ,  C08K5/0075 ,  C08K5/103 ,  C08L23/08 ,  C08L71/00 ,  C09K3/16 ,  Y10S524/91 ,  Y10S524/912 ,  Y10S525/919 ,  Y10T428/1334 ,  Y10T428/1345 ,  Y10T428/1352 ,  Y10T428/31855 ,  Y10T428/31935 ,  C08L2666/22

Abstract: A blend capable of being melt fabricated into an antistatic film which has improved antistatic action practically immediately after production comprises ethylene &agr;,&bgr;-ethylenically unsaturated C3-8 carboxylic acid copolymers having 0-90% of the carboxylic acid groups neutralized by metal ions, particularly sodium ions, and an antistatic effective amount of a polyoxyethylene sorbitan fatty acid, particularly Polyoxyethylene Sorbitan Monolaureate.

Abstract translation: 特别是能够熔融制成防静电膜的共混物，其生产后几乎立即具有改进的抗静电作用，包括具有0-90％的被金属离子中和的羧酸基团的乙烯α，β-烯属不饱和C 3-8羧酸共聚物，特别是 钠离子和抗静电有效量的聚氧乙烯山梨糖醇酐脂肪酸，特别是聚氧乙烯脱水山梨糖醇单油酸酯。

公开(公告)号：US06407172B1

公开(公告)日：2002-06-18

申请号：US09581955

申请日：2000-06-16

Applicant: Karlheinz Hausmann

Inventor： Karlheinz Hausmann

IPC: C08L2310

CPC classification number: C08L23/0815 ,  C08L23/08 ,  C08L23/0876 ,  C08L23/0884 ,  C08L23/10 ,  C08L23/16 ,  C08L2666/04

Abstract: A composition suitable for thermoforming which demonstrates good grain retention at thin gauges, low gloss and whose cost is competitive for many applications, particularly in the automotive industry, is described. This composition contains (a) 10-35 wt. % of polypropylene or an ethylene/propylene copolymer, (b) 0-30 wt. % uncrosslinked ethylene propylene copolymer rubber having an ethylene content 60-80 wt. %, (c) 10-25 wt. % of an ionomeric copolymer of ethylene and an &agr;, &bgr;-unsaturated C3-C8 carboxylic acid, (d) 2-6 wt. % of a copolymer of ethylene and glycidyl acrylate or glycidyl methacrylate, (e) 5-20 wt. % polyethylene, and (f) 0-25 wt. % of an ethylene alpha-olefin copolymer elastomer.

Abstract translation: 描述了适用于热成型的组合物，其在薄的压力表处具有良​​好的颗粒保持性，低光泽度，并且其成本在许多应用中特别是在汽车工业中具有竞争力。 该组合物含有（a）10-35wt。 ％的聚丙烯或乙烯/丙烯共聚物，（b）0-30wt。 ％未交联的乙烯丙烯共聚物橡胶，其乙烯含量为60-80wt。 ％，（c）10-25wt。 ％的乙烯和α，β-不饱和C3-C8羧酸的离聚物共聚物，（d）2-6重量％ 乙烯和丙烯酸缩水甘油酯或甲基丙烯酸缩水甘油酯的共聚物的％，（e）5-20重量％ ％聚乙烯，和（f）0-25wt。 ％的乙烯α-烯烃共聚物弹性体。