公开(公告)号：US06911563B2

公开(公告)日：2005-06-28

申请号：US10451624

申请日：2001-12-27

申请人： Fujio Mizukami ,  Shuichi Niwa ,  Makoto Toba ,  Naotsugu Itoh ,  Tomonari Saito ,  Takemi Nanba ,  Hiroshi Shoji ,  Kazuhiko Haba

发明人： Fujio Mizukami ,  Shuichi Niwa ,  Makoto Toba ,  Naotsugu Itoh ,  Tomonari Saito ,  Takemi Nanba ,  Hiroshi Shoji ,  Kazuhiko Haba

IPC分类号： B01J8/00 ,  B01J10/00 ,  B01J12/00 ,  B01J14/00 ,  B01J19/24 ,  B01J23/44 ,  B01J35/06 ,  C07C29/50 ,  C07C37/58 ,  C07C37/60 ,  C07C39/04 ,  C07C39/07 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C45/40 ,  C07D213/63 ,  C07L37/00

CPC分类号： C07D213/63 ,  B01J8/009 ,  B01J10/007 ,  B01J12/007 ,  B01J14/005 ,  B01J19/2475 ,  B01J23/44 ,  B01J35/065 ,  B01J2219/00063 ,  B01J2219/00094 ,  B01J2219/00099 ,  C07C29/50 ,  C07C37/58 ,  C07C37/60 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/36 ,  C07C45/40 ,  C07C2601/14 ,  Y02P20/52 ,  C07C49/08 ,  C07C47/22 ,  C07C35/08 ,  C07C39/04 ,  C07C39/07 ,  C07C39/14 ,  C07C35/36

摘要： A method for carrying out a reaction of one substance capable of being activated by a catalyst with another substance capable of reacting with said one substance activated, characterized in that the substance capable of being activated is activated by passing the substance through a diaphragm type catalyst and the reaction is thus performed in one reaction step; a method for producing an aromatic alcohol utilizing the above method; and a reaction apparatus suitable for these reactions. In the method, one substance is activated by passing through a diaphragm type catalyst and an objective reaction is carried out by using the activated substance, and the reaction can be performed in one reaction step and with safety. Moreover, the contact of the above activated substance with a compound to be reacted therewith can be freely controlled, and therefore, over-reaction can be prevented and an objective product can be produced in high yield. The method is thus markedly advantageous from an economical view point as a commercial process for producing oxygen-containing organic compounds such as an aromatic alcohol, a ketone, an aldehyde, a carboxylic acid and an epoxide.

摘要翻译： 一种能够使一种能够被催化剂活化的物质与能够与所述一种活化物质反应的物质进行反应的方法，其特征在于，通过使该物质通过隔膜型催化剂而活化， 因此在一个反应​​步骤中进行反应; 利用上述方法制备芳族醇的方法; 和适用于这些反应的反应装置。 在该方法中，通过隔膜型催化剂活化一种物质，并通过使用活性物质进行目标反应，反应可以在一个反应​​步骤和安全性下进行。 此外，可以自由地控制上述活性物质与其反应的化合物的接触，因此可以防止过度反应，并且可以高产率制备目标产物。 因此，作为用于生产含氧有机化合物如芳族醇，酮，醛，羧酸和环氧化物的商业方法，从经济角度看，该方法显着是有利的。

公开(公告)号：US06605733B2

公开(公告)日：2003-08-12

申请号：US10028785

申请日：2001-12-28

申请人： Hideki Omori ,  Hiroko Ahara ,  Kazuhiko Haba ,  Yoshiaki Takaya ,  Shin Irie

发明人： Hideki Omori ,  Hiroko Ahara ,  Kazuhiko Haba ,  Yoshiaki Takaya ,  Shin Irie

IPC分类号： C07D30112

CPC分类号： C07D301/19 ,  B01J21/063 ,  B01J37/086 ,  C07D303/04

摘要： Provided are a titanium-containing solid catalyst useful for producing an epoxy compound from an olefin compound and a peroxide, and a process for producing an epoxy compound using said catalyst. The titanium-containing solid catalyst is obtainable by calcination of a titanium alkynyl alkoxide supported on a silica gel.

摘要翻译： 提供一种可用于从烯烃化合物和过氧化物制备环氧化合物的含钛固体催化剂，以及使用所述催化剂制备环氧化合物的方法。含钛固体催化剂可通过将钛炔基醇盐负载 在硅胶上。

公开(公告)号：US20100286351A1

公开(公告)日：2010-11-11

申请号：US12667785

申请日：2008-06-19

申请人： Norihiro Yoshida ,  Hijiri Aoki ,  Takahito Mita ,  Ami Yamaguchi ,  Kazuhiko Haba ,  Goro Sawada

发明人： Norihiro Yoshida ,  Hijiri Aoki ,  Takahito Mita ,  Ami Yamaguchi ,  Kazuhiko Haba ,  Goro Sawada

IPC分类号： C08F4/32 ,  C08F12/24

CPC分类号： C08F297/00 ,  C08F212/14 ,  C08F216/14

摘要： To provide a novel ABA-type triblock copolymer of vinyl ether series, comprising polyvinyl ether and an oxystyrene-series unit, and a process of producing the ABA-type copolymer at a series of steps. The invention relates to a novel ABA-type triblock copolymer comprising Segment A comprising an oxystyrene-series repeat unit (a) and Segment B comprising a vinyl ether-series repeat unit (b), in which the Segment A and the Segment B are bonded together with a single bond, and to a simple process of producing the same. The triblock copolymer can be produced at a series of steps in a simple manner, comprising living cationic polymerization of a vinyl ether-series monomer such as ethyl vinyl ether in the presence of a bifunctional initiator and a Lewis acid, and subsequently adding an oxystyrene-series monomer such as p-hydroxystyrene for living cationic polymerization.

摘要翻译： 提供一种乙烯基醚系列的新型ABA型三嵌段共聚物，包括聚乙烯基醚和氧苯乙烯系单体，以及一系列步骤制备该ABA型共聚物的方法。 本发明涉及一种新型的ABA型三嵌段共聚物，其包括含有氧化苯乙烯系列重复单元（a）的段A和包含乙烯基醚系列重复单元（b）的段B，其中段A和段B键合 连同一个单一的债券，以及一个简单的生产过程。 三嵌段共聚物可以以简单的方式在一系列步骤中制备，包括在双功能引发剂和路易斯酸的存在下乙烯基醚系单体如乙基乙烯基醚的阳离子聚合，随后加入氧苯乙烯 - 用于活性阳离子聚合的对羟基苯乙烯等系列单体。

公开(公告)号：US08492483B2

公开(公告)日：2013-07-23

申请号：US12667785

申请日：2008-06-19

申请人： Norihiro Yoshida ,  Hijiri Aoki ,  Takahito Mita ,  Ami Yamaguchi ,  Kazuhiko Haba ,  Goro Sawada

发明人： Norihiro Yoshida ,  Hijiri Aoki ,  Takahito Mita ,  Ami Yamaguchi ,  Kazuhiko Haba ,  Goro Sawada

IPC分类号： C08F4/32 ,  C08F12/24

CPC分类号： C08F297/00 ,  C08F212/14 ,  C08F216/14

摘要： To provide a novel ABA-type triblock copolymer of vinyl ether series, comprising polyvinyl ether and an oxystyrene-series unit, and a process of producing the ABA-type copolymer at a series of steps. The invention relates to a novel ABA-type triblock copolymer comprising Segment A comprising an oxystyrene-series repeat unit (a) and Segment B comprising a vinyl ether-series repeat unit (b), in which the Segment A and the Segment B are bonded together with a single bond, and to a simple process of producing the same. The triblock copolymer can be produced at a series of steps in a simple manner, comprising living cationic polymerization of a vinyl ether-series monomer such as ethyl vinyl ether in the presence of a bifunctional initiator and a Lewis acid, and subsequently adding an oxystyrene-series monomer such as p-hydroxystyrene for living cationic polymerization.

摘要翻译： 提供一种乙烯基醚系列的新型ABA型三嵌段共聚物，包括聚乙烯基醚和氧苯乙烯系单体，以及一系列步骤制备该ABA型共聚物的方法。 本发明涉及一种新型的ABA型三嵌段共聚物，其包括含有氧化苯乙烯系列重复单元（a）的段A和包含乙烯基醚系列重复单元（b）的段B，其中段A和段B键合 连同一个单一的债券，以及一个简单的生产过程。 三嵌段共聚物可以以简单的方式在一系列步骤中制备，包括在双功能引发剂和路易斯酸的存在下乙烯基醚系单体如乙基乙烯基醚的阳离子聚合，随后加入氧苯乙烯 - 用于活性阳离子聚合的对羟基苯乙烯等系列单体。

公开(公告)号：US06479707B2

公开(公告)日：2002-11-12

申请号：US10012318

申请日：2001-12-12

申请人： Hideki Omori ,  Kazuhiko Haba

发明人： Hideki Omori ,  Kazuhiko Haba

IPC分类号： C07B4104

CPC分类号： C07C29/50 ,  C07C45/33 ,  C07C49/10 ,  C07C31/12

摘要： The present invention provides a process for producing 2-butanone and 2-butanol under comparatively mild conditions with a decreased number of steps by direct oxidization of a hydrocarbon, which is cheaper than butenes, as a raw material using molecular oxygen such as air. The process for producing 2-butanone and 2-butanol comprises directly oxidizing n-butane using molecular oxygen in the presence of aluminum phosphate containing transition metal atoms and a selectivity-improving agent, as required.