公开(公告)号：US08742015B2

公开(公告)日：2014-06-03

申请号：US12376127

申请日：2007-07-11

申请人： Keigo Higaki ,  Yasuhiko Itou

发明人： Keigo Higaki ,  Yasuhiko Itou

IPC分类号： C08L51/04

CPC分类号： C08L25/12 ,  B60R13/02 ,  C08L25/16 ,  C08L27/18 ,  C08L35/06 ,  C08L51/04 ,  C08L55/02 ,  C08L65/00 ,  C08L73/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2666/02

摘要： The objective of the present invention is to provide a thermoplastic resin composition having an excellent balance of chemical resistance, heat resistance and impact resistance and a molded article comprising this thermoplastic resin composition. The present thermoplastic resin composition comprises a rubber-reinforced resin, an ethylene•(meth)acrylic acid ester•carbon monoxide copolymer, and polytetrafluoroethylene, and contents of ethylene•(meth)acrylic acid ester•carbon monoxide copolymer and polytetrafluoroethylene are respectively from 0.5 to 20 parts by weight and from 0.01 to 5 parts by weight, with respect to 100 parts by weight of the rubber-reinforced resin. A modified polyolefin resin may be contained.

摘要翻译： 本发明的目的是提供具有优异的耐化学性，耐热性和耐冲击性的平衡的热塑性树脂组合物和包含该热塑性树脂组合物的模塑制品。 本发明的热塑性树脂组合物包括橡胶增强树脂，乙烯·（甲基）丙烯酸酯·一氧化碳共聚物和聚四氟乙烯，乙烯·（甲基）丙烯酸酯·一氧化碳共聚物和聚四氟乙烯的含量分别为0.5 至20重量份和0.01至5重量份，相对于100重量份的橡胶增强树脂。 可以含有改性聚烯烃树脂。

公开(公告)号：US20090226727A1

公开(公告)日：2009-09-10

申请号：US12093468

申请日：2006-11-20

申请人： Keigo Higaki

发明人： Keigo Higaki

IPC分类号： B32B15/08 ,  B32B27/36 ,  B32B27/32 ,  B32B27/30 ,  C25D9/02

CPC分类号： C08L55/02 ,  C08F279/02 ,  C08F279/04 ,  C08F291/02 ,  C08L9/00 ,  C08L23/0815 ,  C08L23/16 ,  C08L23/18 ,  C08L25/12 ,  C08L51/04 ,  C08L53/02 ,  C08L69/00 ,  C08L2205/02 ,  C08L2205/03 ,  C23C18/1653 ,  C23C18/30 ,  C25D5/56 ,  Y10T428/31507 ,  Y10T428/31692 ,  C08L2666/04 ,  C08L2666/02 ,  C08L2666/24

摘要： The objective of the present invention is to provide a resin composition for direct plating whose plating performance such as depositibility and appearance after forming a metal film including copper film and the like by electroplating in direct plating method is excellent, a molded article comprising this composition, and a plated article having a metal film or an alloy film, formed by direct plating. The present composition is a thermoplastic resin composition containing a rubber-reinforced vinyl-based resin and the rubber-reinforced vinyl-based resin comprises a diene-based rubbery polymer [a1] and an ethylene•α-olefin-based rubbery polymer [a2], the total amount of the diene-based rubbery polymer [a1] and the ethylene•α-olefin-based rubbery polymer [a2] is from 3 to 30% by mass based on the thermoplastic resin composition, and the ratio of the ethylene•α-olefin-based rubbery polymer [a2] to the total amount is from 0.01 to 0.4.

摘要翻译： 本发明的目的是提供一种用于直接电镀的用于直接电镀方法的通过电镀形成包括铜膜等的金属膜之后的电镀性能，例如电镀性能的电镀性能优异的包含该组合物的成型品， 以及具有通过直接电镀形成的金属膜或合金膜的电镀制品。 本发明的组合物是含有橡胶强化乙烯基类树脂的热塑性树脂组合物，橡胶强化乙烯基系树脂含有二烯系橡胶质聚合物[a1]和乙烯-α-烯烃系橡胶质聚合物[a2] 二烯类橡胶质聚合物[a1]和乙烯-α-烯烃系橡胶质聚合物[a2]的总量相对于热塑性树脂组合物为3〜30质量％，乙烯的比例为3〜30质量％。 α-烯烃系橡胶质聚合物[a2]总量为0.01〜0.4。

公开(公告)号：US20060111514A1

公开(公告)日：2006-05-25

申请号：US10534984

申请日：2003-11-20

申请人： Keigo Higaki ,  Tadashi Nagahara ,  Hiroki Kashiwagi

发明人： Keigo Higaki ,  Tadashi Nagahara ,  Hiroki Kashiwagi

IPC分类号： C08F8/00

CPC分类号： C09D155/02 ,  C08F265/04 ,  C08F279/02 ,  C08F279/04 ,  C08L51/003 ,  C08L51/04 ,  C08L55/02 ,  C09D151/04 ,  C08L2666/24 ,  C08L2666/02 ,  C08L51/00

摘要： The invention provides a thermoplastic resin composition whereby a molded article is obtained having excellent flexibility, coating properties, weather resistance, peel properties, dimensional precision, and the like. The thermoplastic resin composition of the present invention comprises 70 mass% of an acrylic rubber reinforced resin obtained by polymerizing a vinyl monomer (a2) in the presence of an acrylic rubber polymer (a1); 10 mass% of a diene rubber reinforced resin obtained by polymerizing a vinyl monomer (b2) in the presence of a diene rubber polymer (b1); and 20 mass% of a vinyl monomer (d2) comprising an aromatic vinyl compound and a vinyl cyanide compound in which the bonded vinyl cyanide content is 33 mass%; the total content of the acrylic rubber polymers (a1) and (b1) therein is 27 mass%; the coefficient of linear expansion thereof is 10×10−5/°C. or less; and the flexural modulus thereof according to ISO 178 is 1000 to 2200 MPa.

摘要翻译： 本发明提供一种热塑性树脂组合物，由此得到具有优异的柔软性，涂层性能，耐候性，剥离性能，尺寸精度等的模塑制品。 本发明的热塑性树脂组合物含有70质量％的在丙烯酸橡胶聚合物（a1）的存在下聚合乙烯基单体（a2）而获得的丙烯酸橡胶增强树脂; 通过在二烯橡胶聚合物（b1）的存在下聚合乙烯基单体（b2）得到的二烯橡胶增强树脂10质量％; 和20质量％的包含芳族乙烯基化合物和乙烯基氰化合物的乙烯基单体（d2），其中所述键合的乙烯基氰含量为33质量％; 丙烯酸类橡胶聚合物（a1）和（b1）的总含量为27质量％。 其线性膨胀系数为10×10 -5 /℃。 或更少; 其根据ISO 178的挠曲模量为1000〜2200MPa。

公开(公告)号：US20100004394A1

公开(公告)日：2010-01-07

申请号：US12376127

申请日：2007-07-11

申请人： Keigo Higaki ,  Yasuhiko Itou

发明人： Keigo Higaki ,  Yasuhiko Itou

IPC分类号： C08L51/04 ,  C08L19/00

CPC分类号： C08L25/12 ,  B60R13/02 ,  C08L25/16 ,  C08L27/18 ,  C08L35/06 ,  C08L51/04 ,  C08L55/02 ,  C08L65/00 ,  C08L73/00 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2666/02

摘要： The objective of the present invention is to provide a thermoplastic resin composition having an excellent balance of chemical resistance, heat resistance and impact resistance and a molded article comprising this thermoplastic resin composition. The present thermoplastic resin composition comprises a rubber-reinforced resin, an ethylene.(meth)acrylic acid ester-carbon monoxide copolymer, and polytetrafluoroethylene, and contents of ethylene.(meth)acrylic acid ester.carbon monoxide copolymer and polytetrafluoroethylene are respectively from 0.5 to 20 parts by weight and from 0.01 to 5 parts by weight, with respect to 100 parts by weight of the rubber-reinforced resin. A modified polyolefin resin may be contained.

摘要翻译： 本发明的目的是提供具有优异的耐化学性，耐热性和耐冲击性的平衡的热塑性树脂组合物和包含该热塑性树脂组合物的模塑制品。 本发明的热塑性树脂组合物包括橡胶增强树脂，乙烯，（甲基）丙烯酸酯 - 一氧化碳共聚物和聚四氟乙烯以及乙烯含量，（甲基）丙烯酸酯，一氧化碳共聚物和聚四氟乙烯分别为0.5 至20重量份和0.01至5重量份，相对于100重量份的橡胶增强树脂。 可以含有改性聚烯烃树脂。

公开(公告)号：US5457167A

公开(公告)日：1995-10-10

申请号：US340391

申请日：1994-11-15

申请人： Keigo Higaki ,  Kouichi Sakurai ,  Nobuo Kawahashi ,  Yoichi Kamoshida ,  Makoto Matsumoto ,  Kazuto Shinohara ,  Kouji Kanuma

发明人： Keigo Higaki ,  Kouichi Sakurai ,  Nobuo Kawahashi ,  Yoichi Kamoshida ,  Makoto Matsumoto ,  Kazuto Shinohara ,  Kouji Kanuma

IPC分类号： C08F283/12 ,  C08F285/00 ,  C08F290/14 ,  C08G77/50 ,  C08G77/52

CPC分类号： C08G77/50 ,  C08F283/122 ,  C08F283/124 ,  C08G77/52

摘要： A polyorganosiloxane-type thermoplastic resin having excellent slidability, abrasion resistance, weatherability, impact strength, fatigue resistance and chemical resistance is disclosed. The thermoplastic resin comprises a graft copolymer (IV) obtained by graft-polymerizing at least one vinyl monomer (v) onto a modified polyorganosiloxane obtained by polymerizing 80 to 99.8% by weight of an organosiloxane (I) having the structural unit described thereinabove, 0.1 to 10% by weight of at least one graft crosslinking agent (II) containing an alkoxysilyl group, selected from the group consisting of a vinyl-type graft crosslinking agent, a mercapto-type graft crosslinking agent, an acryloyl-type crosslinking agent and a vinylphenyl-type crosslinking agent, and 0.1 to 10% by weight of a compound (III) having two alkoxysilyl groups, provided that (I)+(II)+(III)=100% by weight.

摘要翻译： 公开了具有优异的滑动性，耐磨性，耐候性，冲击强度，耐疲劳性和耐化学性的聚有机硅氧烷型热塑性树脂。 热塑性树脂包括通过将至少一种乙烯基单体（v）接枝聚合到通过使80至99.8重量％的具有上述结构单元的有机硅氧烷（I）聚合而获得的改性聚有机硅氧烷上获得的接枝共聚物（IV），0.1 至10重量％的至少一种含有烷氧基甲硅烷基的接枝交联剂（II），其选自乙烯基型接枝交联剂，巯基型接枝交联剂，丙烯酰基型交联剂和 乙烯基苯基型交联剂和0.1〜10重量％的具有两个烷氧基甲硅烷基的化合物（III），条件是（I）+（II）+（III）= 100重量％。

公开(公告)号：US09315662B2

公开(公告)日：2016-04-19

申请号：US12093468

申请日：2006-11-20

申请人： Keigo Higaki

发明人： Keigo Higaki

IPC分类号： C08L55/02 ,  C08L69/00 ,  C25D5/56 ,  C08L23/08 ,  C08L23/16 ,  C08L23/18 ,  C08L25/12 ,  C08L51/04

CPC分类号： C08L55/02 ,  C08F279/02 ,  C08F279/04 ,  C08F291/02 ,  C08L9/00 ,  C08L23/0815 ,  C08L23/16 ,  C08L23/18 ,  C08L25/12 ,  C08L51/04 ,  C08L53/02 ,  C08L69/00 ,  C08L2205/02 ,  C08L2205/03 ,  C23C18/1653 ,  C23C18/30 ,  C25D5/56 ,  Y10T428/31507 ,  Y10T428/31692 ,  C08L2666/04 ,  C08L2666/02 ,  C08L2666/24

摘要： The objective of the present invention is to provide a resin composition for direct plating whose plating performance such as depositibility and appearance after forming a metal film including copper film and the like by electroplating in direct plating method is excellent, a molded article comprising this composition, and a plated article having a metal film or an alloy film, formed by direct plating. The present composition is a thermoplastic resin composition containing a rubber-reinforced vinyl-based resin and the rubber-reinforced vinyl-based resin comprises a diene-based rubbery polymer [a1] and an ethylene•α-olefin-based rubbery polymer [a2], the total amount of the diene-based rubbery polymer [a1] and the ethylene•α-olefin-based rubbery polymer [a2] is from 3 to 30% by mass based on the thermoplastic resin composition, and the ratio of the ethylene•α-olefin-based rubbery polymer [a2] to the total amount is from 0.01 to 0.4.

摘要翻译： 本发明的目的是提供一种用于直接电镀的用于直接电镀方法的通过电镀形成包括铜膜等的金属膜之后的电镀性能，例如电镀性能的电镀性能优异的包含该组合物的成型品， 以及具有通过直接电镀形成的金属膜或合金膜的电镀制品。 本发明的组合物是含有橡胶强化乙烯基类树脂的热塑性树脂组合物，橡胶强化乙烯基系树脂含有二烯系橡胶质聚合物[a1]和乙烯·α-烯烃系橡胶质聚合物[a2] 二烯系橡胶质聚合物[a1]和乙烯·α-烯烃系橡胶质聚合物[a2]的合计量相对于热塑性树脂组合物为3〜30质量％，乙烯· α-烯烃系橡胶质聚合物[a2]总量为0.01〜0.4。

公开(公告)号：US06590016B2

公开(公告)日：2003-07-08

申请号：US09789533

申请日：2001-02-22

申请人： Masahiko Noro ,  Hiroyuki Itoh ,  Keigo Higaki ,  Hiroaki Miyazaki

发明人： Masahiko Noro ,  Hiroyuki Itoh ,  Keigo Higaki ,  Hiroaki Miyazaki

IPC分类号： C08L6900

CPC分类号： C08K5/523 ,  C08L27/18 ,  C08L69/00 ,  C08L51/00

摘要： Flame retardant thermoplastic resin compositions containing (A) a rubber-reinforced resin produced by graft-polymerizing a monomer component containing an aromatic vinyl compound and a vinyl cyanide compound as main ingredients in the presence of a rubber polymer particles and (B) 90 to 60 parts by weight of an aromatic polycarbonate. Optionally (C) a phosphate compound and (D) a component containing poly-tetrafluoroethylene and a lubricant may be present.

摘要翻译： 阻燃热塑性树脂组合物，其含有（A）在橡胶聚合物粒子的存在下，将含有芳香族乙烯基化合物和乙烯基氰化合物的单体成分接枝聚合而得到的橡胶强化树脂，（B）90〜60 重量份的芳族聚碳酸酯。 任选地（C）磷酸盐化合物和（D）含有聚四氟乙烯和润滑剂的组分。